PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Evaluation of the thermo-mechanical and explosive properties of bimodal and hybrid polymer bonded explosive (PBX) compositions based on HNS and HMX

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In the present paper, a series of bimodal PBX compositions containing coarse (90 μm) and fine (<1 μm) HNS (2,2’4,4’6,6’-hexanitrostilbene) and hybrid PBX compositions based on HNS and HMX (1,3,5,7-tetranitro-1,3,5,7- tetraazacyclooctane) in varying mass ratios, along with the fluoropolymer Viton-A, a vinylidene fluoride and hexafluoropropylene copolymer, as a binder (5%), have been prepared on the lab scale. In order to observe any effect of incorporating fine HNS particles with coarse ones and the effect of replacing HNS with HMX in all types of bimodal and hybrid PBX compositions, the samples were characterized for composition analysis, thermal behavior and morphological analysis as well as evaluated for their mechanical and explosive properties including sensitiveness tests and detonic properties. The data showed that incorporation of fine HNS into coarse particles of HNS in the bimodal PBX resulted in an increase in mechanical strength and a decrease in friction and impact sensitivity, as well as an enhanced performance compared to PBXs based on coarse HNS alone. Viton-A based hybrid PBX compositions provided better mechanical and sensitivity properties as compared to conventional explosive compositions based exclusively on HMX or HNS and the performance of the PBX compositions increased with increasing HMX content.
Słowa kluczowe
Rocznik
Strony
371--391
Opis fizyczny
Bibliogr. 17 poz., rys., tab.
Twórcy
autor
  • Department of Quality Assurance, Terminal Ballistics Research Laboratory, Sector-30, Chandigarh-160030, India
autor
  • Department of Quality Assurance, Terminal Ballistics Research Laboratory, Sector-30, Chandigarh-160030, India
autor
  • Department of Quality Assurance, Terminal Ballistics Research Laboratory, Sector-30, Chandigarh-160030, India
autor
  • Department of Applied Sciences, PEC University of Technology, Sector-12, Chandigarh-160012, India
Bibliografia
  • [1] Cumming A.S., New Directions in Energetic Materials, J. Def. Sci., 1996, 1(3), 319.
  • [2] Urbanski T., Vasudeva S. K., Heat Resistant Explosives, J. Sci. Ind. Res., 1978, 37(5), 250-255.
  • [3] Schmid H., Coating of Explosives, J. Hazard. Mater., 1986, 13(1), 89-101.
  • [4] Mattos E.C., Moreira E.D., Diniz M.F., Dutra R.C.L., Silva G., Iha K., Teipel U., Characterization of Polymer-coated RDX and HMX Particles, Propellants Explos. Pyrotech., 2008, 33(1), 44-50.
  • [5] Daniel M.A., Polyurethane Binder Systems for Polymer Bonded Explosives, Report DSTO-GD-0492, Weapons Systems Division, Edinburgh, Australia, Dec, 2006.
  • [6] Talawar M.B., Agarwal A.P., Anniyappan M., Gore G.M., Asthana S.N., Venugopalan S., Method for Preparation of Fine TATB (2-5 μm) and Its Evaluation in Plastic Bonded Explosive (PBX) Formulations, J. Hazard. Mater., 2006, 137(3), 1848-1852.
  • [7] Agrawal J.P., Some New High Energy Materials and Their Formulations for Specialized Applications, Propellants Explos. Pyrotech., 2005, 30(5), 316-328.
  • [8] Kilmer E.E., HNS/Teflon Explosive Charges for the Apollo 17 Seismic Experiments, Report NOLTR 73-44, LSPE, Naval Ordnance Laboratory, White Oak, Silver Spring, Maryland, USA, May 10, 1973.
  • [9] Boddu V.M., Viswanath D.S., Ghosh T.K., Damavarapu R., 2,4,6-Triamino-1,3,5- trinitrobenzene (TATB) and TATB-based Formulations − A Review, J. Hazard. Mater., 2010, 181(1), 1-8.
  • [10] Kaur J., Arya V.P., Kaur G., Gupta Y.P., Verma M.M., Lata P., Determination of Solvent Contamination and Characterization of Ultrafine HNS Particles after Solvent Recrystallization, Propellants Explos. Pyrotech., 2010, 35(5), 487-493.
  • [11] Schaffer C.L., Compositional Analysis of PBX 9503- A TATB/HMX/Kel-F800 Formulation, Report MHSMP-81-55, DE 82006183, Department of Energy, USA, November, 1981.
  • [12] UN Recommendation on the Transport of Dangerous Goods, Manual of Tests and Criteria, United Nations, 13.4.2 Test 3(a) (ii) BAM Fall Hammer, New York, USA, 2003.
  • [13] UN Recommendation on the Transport of Dangerous Goods, Manual of Tests and Criteria, United Nations, 13.5.1 Test 3(b) (i) BAM Friction Apparatus, New York, USA, 2003.
  • [14] Provatas A., Formulation and Performance Studies of Polymer Bonded Explosives (PBX) Containing Energetic Binder Systems. Part 1, Report DSTO-TR-1397, Weapons Systems Division, Systems Sciences Laboratory, Edinburgh, Australia, March, 2003.
  • [15] Gautam P.C, Goel G., Khurana R., Sharma A.C., Singh M., Electrical Techniques for Measurement of Detonics Parameters of High Explosives, 8th International High Energy Materials Conference & Exhibit, HEMCE-11, TBRL, Chandigarh, India, Nov 10-12, 2011.
  • [16] Urbanski J., Handbook of Analysis of Synthetic Polymers and Plastics, John Wiley & Sons, New York, USA, 1977, p. 494.
  • [17] Ameduri B., Boutevin B., Kostov G., Fluoroelastomers: Synthesis, Properties and Application, Prog. Polym. Sci., 2005, 26, 105-187.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1bac9239-1376-44f1-8b52-de63488f103c
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.