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The results of laboratory scale research have been presented on the effects of ozonation of carrier gas containing NOx and SO2 on by-products trapped in Dreschel washers with solution of sodium hydroxide. The controlling parameter in this process was the ozonation intensity determined by the molar ratio O3/NOx. The measured by-products in a scrubber were SO32- , SO42- , NO2- and NO3- ions. It has been shown that ozonation of flue gas favours oidation of nitrites to nitrates and sulfites to sulfates in alkaline solution. Some of these results were confirmed in a pilot scale studies. Pilot plant was located in Wroclaw CHP (Combined Heat and Power), which provided flue gas for testing at a rate of 200 m3/h from the OP-430 boiler. Exhaust gases were ozonized and captured simultaneously with SO2. Sodium hydroxide was used in a pilot scale as an absorbent.
Czasopismo
Rocznik
Tom
Strony
125--136
Opis fizyczny
Bibliogr. 20 poz., tab., rys.
Twórcy
autor
- Wroclaw University of Science and Technology, Faculty of Environmental Engineering, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland.
autor
- Wrocław University of Science and Technology, Faculty of Chemistry, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
autor
- Wrocław University of Science and Technology, Faculty of Mechanical and Power Engineering, Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland
autor
- Wrocław University of Science and Technology, Faculty of Mechanical and Power Engineering, Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland
Bibliografia
- [1] Directive 2010/75/EU of the European Parliament and the Council, 2010.
- [2] KUCOWSKI J., LAUDYN D., PRZEKWAS M., Energetics and the environmental protection, WNT, War-saw 1997 (in Polish).
- [3] ELLISON W., Chemical process design alternatives to gain simultaneous removal in scrubbers, POWER-GEN International, Las Vegas, USA, 9–11 December 2003.
- [4] CARPENTER A.M., Advances in multi-pollutant control, IEA Clean Coal Centre, 11.2013.
- [5] HUTSON N.D., KRZYŻYŃSKA R., SRIVASTAVA R.K., Simultaneous removal of SO2, NOx, and Hg from coal flue gas using NaClO2-enhanced wet scrubber, Ind. Eng. Chem., 2008, 479 (16), 5825.
- [6] KORDYLEWSKI W., ŁUSZKIEWICZ D., Nitrogen oxides removal from flue gas by ozonation method, Energetyka, 2015, 7, 480 (in Polish).
- [7] SANDER R., Compilation of Henry’s law constants for inorganic and organic species of potential importance in environmental chemistry, Air Chemistry Department, Max-Planck Institute of Chemistry, PO Box 3060, 55020 Mainz, Germany, 1999.
- [8] Treatment technologies for removal of methyl tertiary butyl ether (MTBE) from drinking water. Chapter 3. Advanced oxidation processes, National Water Research Institute, Fountain Valley, CA (U.S.A.), 2000.
- [9] SKALSKA K., MILLER J.S. , LEDAKOWICZ S., Kinetic model of NOx ozonation and its experimental verification, Chem. Engn. Sci., 2011, 66, 3386.
- [10] SUN C., ZHAO N., ZHUANG Z., WANG H., LIU Y., WENG X., WU Z., Mechanisms and reaction pathways for simultaneous oxidation of NOx and SO2 by ozone determined by in situ IR measurements, J. Hazard. Mater., 2014, 274, 376.
- [11] JOSHI J.B., MAHAJANI V.V., JUVEKAR V.A., Absorption of NOx gases, Chem. Eng. Com., 1985, 33, 1.
- [12] JAKUBIAK M., KORDYLEWSKI W., Pilot-scale studies on NOx removal from flue gas via NO ozonation and absorption into NaOH solution, Chem. Proc. Eng., 2012, 33 (3), 345.
- [13] PRATHER M.J., LOGAN J.A., Combustion’s impact on the global atmosphere, Proc. 25th Int. Symp. Combust., Pittsburgh, USA, 31 July–5 August 1994, 1513.
- [14] DRAGO R.S., Infrared spectra of the salts of the dinitrososulfite ion (nitrosohydroxylaminesulfonates), J. Am. Chem. Soc., 1957, 79, 2049.
- [15] ACKERMANN M.N., POWELL R.E., Air oxidation of hydroxylamine-N-sulfonate, Inorg. Chem., 1967, 6 (9), 1718.
- [16] LITTLEJOHN D., WANG Y., CHANG S.G., Oxidation of aqueous sulfite ion by nitrogen dioxide, Environ. Sci. Technol., 1993, 27, 2162.
- [17] Regulation of the Minister of Environment on conditions to be met when introducing sewage into the water or soil and on substances particularly harmful to the aquatic environment, Dz.U. 2009, nr 27, poz. 169) (in Polish).
- [18] DORA J., GOSTOMCZYK M.A., JAKUBIAK M., KORDYLEWSKI W., MISTA W., TKACZUK M., Parametric studies of effectiveness of oxidation of NO by ozone, Chem. Proc. Eng., 2009, 30, 621.
- [19] MOK S.Y., LEE H.-J., Removal of sulfur dioxide and nitrogen oxides by using ozone injection and absorption-reduction technique, Fuel. Proc. Technol., 2006, 87, 591.
- [20] GŁOMBA M., KORDYLEWSKI W., Simultaneous removal of NOx, SO2, CO and Hg from flue gas by ozonation. Pilot plant studies, Environ. Prot. Eng., 2014, 40 (3), 113.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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