Sonically modified zeolites with MFI and USY type structure as catalysts for methane combustion. Preparation and physicochemical characterisation

• Autorzy: Kuterasiński Łukasz , Dymek Klaudia , Jodłowski Przemysław Jakub

Identyfikatory

DOI

10.5604/01.3001.0013.5388

• Języki publikacji: EN

Abstrakty

EN

The objectives of our study were to prepare of ZSM-5 and USY-based catalysts by hydrothermal method, containing metallic active phase, deposited by both conventional ionic-exchange or ultrasonic irradiation. Prepared materials were characterized by various physicochemical methods, such as XRD, BET, SEM, UV-VIS and the sorption of ammonia monitored by FT- -IR spectroscopy. The XRD data confirmed pure MFI or USY type structure zeolite. BET and ammonia sorption results have shown that the presented method leads to preparation of highly porous and acidic systems. Metallic active phase was found as cations and oxides with hexagonal and octahedral coordination.

Słowa kluczowe

EN

hydrothermal synthesis; zeolite; ultrasound; methane combustion

PL

synteza hydrotermalna; zeolit; ultradźwięk; spalanie metanu

• Wydawca: Państwowa Wyższa Szkoła Zawodowa w Tarnowie
• Czasopismo: Science, Technology and Innovation
• Rocznik: 2019
• Tom: Vol. 6, no. 3
• Strony: 11--18
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Kuterasiński Łukasz

• Jerzy Haber Institute of Catalysis and Surface Chemistry Polish Academy of Sciences, Niezapominajek 8, 30–239 Kraków, Poland

autor

Dymek Klaudia

• Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 30–155 Kraków, Poland

autor

Jodłowski Przemysław Jakub

• Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 30–155 Kraków, Poland

Bibliografia

• 1. Khirsariya P., Mewada R.K.: Single step oxidation of methane to methanol – towards better understanding. Procedia Eng. 2013; 51: 409–415.
• 2. Jones C., Taube D., Ziatdinov V.R., Periana R.A., Nielsen R.J., Oxgaard J., Goddard W.: Selective oxidation of methane to methanol catalyzed with C-H activation by homogeneous cationic gold. Angew. Chem. Int. Ed. Engl. 2004; 6: 4626–4629.
• 3. Xiao P., Wang Y., Nishitoba T., Kondo J.N., Yokoi T.: Selective oxidation of methane to methanol with H2O2 over Fe-MFi zeolites catalyst using sulfone solvent. Chem. Commun. 2019; 55: 2896–2899.
• 4. Kierys A., Goworek J.: Adsorbenty i Katalizatory. Wybrane technologie a środowisko, w Materiały krzemionkowe nowej generacji, Uniwersytet Rzeszowki, 2012. http://www.ztch.umcs.lublin.pl/materialy/praca_zbiorowa_wprowadzenie.pdf
• 5. Bonrath W.: Ultrasound supported catalysis. Ultrason. Sonochem. 2005; 12: 103–106.
• 6. Andac O., Tatlıer M., Sirkecioglu A., Ece I, Erdem-Senatalar A.: Effects of ultrasound on zeolite A synthesis. Microporous Mesoporous Mater. 2005; 79: 225–233.
• 7. Andac O., Murat Telli S., Tatlier M., Erdem-Senatalar A.: Effects of ultrasound on the preparation of zeolite A coatings. Microporous Mesoporous Mater. 2006; 88: 72–76.
• 8. Wang B., Wu J., Yuan Z.Y., Li N., Xiang S.: Synthesis of MCM-22 zeolite by an ultrasonic-assisted aging procedure. Ultrason. Sonochem. 2008; 15: 334–338.
• 9. Pal P., Das J.K., Das N., Bandyopadhyay S.: Synthesis of NaP zeolite at room temperature and short crystallization time by sonochemical method. Ultrason. Sonochem. 2013; 20: 314–321.
• 10. Hosseini M., Zanjanchi M.A., Ghalami-Choobar B., Golmojdeh H.: Ultrasound-assisted dealumination of zeolite Y. J. Chem. 2015; 127: 25–31.
• 11. Pereda-Ayo B., De La Torre U., JoséIllán-Gómez M., Bueno-López A., González-Velasco J.R.: Role of the different copper species on the activity of Cu/zeolite catalysts for SCR of NOx with NH3. Appl. Catal. B. 2014; 147: 420–428.
• 12. Yan J.Y., Lei G.D., Sachtler W.M.H., Kung H.H.: Deactivation of Cu/ZSM-5 catalysts for lean NOx reduction: Characterization of changes of Cu state and zeolite support. J. Catal. 1996; 161: 43–54.
• 13. Janas J., Machej T., Gurgul J., Socha R.P., Che M., Dzwigaj S.: Effect of Co content on the catalytic activity of CoSiBEA zeolite in the selective catalytic reduction of NO with ethanol: Nature of the cobalt species. Appl. Catal. B. 2007; 75: 239–248.
• 14. Li L.D., Shen Q., Yu J.J.; Hao Z.P., Xu Z.P., Lu G.Q.M.: Fe−USY zeolite catalyst for effective decomposition of nitrous oxide. Environ. Sci. Technol. 2007; 41: 7901–7906.
• 15. Lee K., Kosaka H., Sato S., Yokoi T., Choi B., Kim D.: Effects of Cu loading and zeolite topology on the selective catalytic reduction with C3H6 over Cu/zeolite catalysts. J. Industrial and Eng. Ch. 2019; 72: 73–86.
• 16. Datka J., Kawałek M.: Strength of Brønsted acid sites in boralites. J. Chem. Soc. Faraday Trans. 1993; 89: 1829–1831.
• 17. Yashmina T., Yamazaki K., Ahmad H., Katsuta M., Hara N.: Alkylation on synthetic zeolites: II. Selectivity of p-xylene formation. J. Catal. 1970; 17: 151–156.
• 18. Freude D., Frochlich T., Hunger M., Pfeifer H., Scheler G.: NMR studies concerning the dehydroxylation of zeolites HY. Chem. Phys. Lett. 1983; 98: 263–266.
• 19. Brylewska K., Tarach K.A., Mozgawa W., Olejniczak Z., Filek U., Góra-Marek K.: Modification of ferrierite through post-synthesis treatments. Acidic and catalytic properties. J. Mol. Struct. 2016; 1126: 147–153.
• 20. Chmielarz L., Kuśtrowski P., Zbroja M., Gil-Knap B., Datka J., Dziembaj R.: SCR of NO by NH3 on alumina or titania pillared montmorillonite modified with Cu or Co Part II. Temperature programmed studies. Appl. Catal. B. 2004; 53: 47–61.
• 21. Rutkowska M., Diaz U., Palomares A.E., Chmielarz L.: Cu and Fe modified derivatives of 2D MWW-type zeolites (MCM-
• 22, ITQ-2 and MCM-36) as new catalysts for DeNOx process. Appl. Catal. B. 2015; 168–169: 531–539.
• 22. Urquieta-Gonzales E.A., Pequin R.P.S., Batiste M.S.: Identification of extra-framework species on Fe/ZSM-5 and Cu/ZSM-5 catalysts typical microporous molecular sieves with zeolitic structure. Materials Research. 2002; 5: 321–327.
• 23. Shen Q., Li L., He C., Zhang X., Hao Z., Xu Z.: Cobalt zeolites: Preparation, characterization and catalytic properties for N2O decomposition. Asia-Pac. J. Chem. Eng. 2012; 7: 502–509.
• 24. Xie P., Luo Y., Ma Z., Wang L., Huang C., Yue Y., Hua W., Gao Z.: CoZSM-11 catalysts for N2O decomposition: Effect of preparation methods and nature of active sites. Appl. Catal. B. 2015; 170: 34–42.
• 25. Chlebda D.K., Stachurska P., Jędrzejczyk R.J., Kuterasiński Ł., Dziedzicka A., Górecka S., Chmielarz L., Łojewska J., Sitarz M., Jodłowski P.J.: DeNOx abatement over sonically prepared iron substituted Y, USY and MFI zeolite catalysts in lean exhaust gas conditions. Nanomaterials. 2018; 8: 21–39.
• 26. Zhao Z., Duan A., Xu C.: CrHZSM-5 zeolites- highly efficient catalysts for catalytic cracking of isobutane to produce light olefins. Catal. Lett. 2006; 109: 65–70.