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Strontium-based nanosized phosphates as anticorrosive fillers of epoxy and polyurethane coating compositions

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Anticorrosive epoxy and polyurethane coatings were compounded using zinc-free nanosized phosphates of strontium (SP) or strontium and aluminum (SAP). For comparison, a nanosized calcium aluminum ammonium phosphate (CAP) and a microsized zinc phosphate (ZP) were tested. Results of salts spray and cyclic corrosion tests revealed better anticorrosive properties of the SAP-based coatings in relation to the samples with the other Zn-free fillers or ZP. Electrochemical noise tests of uncoated steel in aqueous suspensions of the phosphates exhibited similar corrosion inhibition efficiency of the Sr-based phosphates and ZP, and worse anticorrosive features of CAP. Electrochemical impedance spectroscopy did not show better protective properties of ZP-based coatings than the samples with the Zn-free fillers.
Rocznik
Strony
52--58
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
  • West Pomeranian University of Technology, Faculty of Chemical Technology and Engineering, Polymer Institute, Piastów Ave 42, 71-065 Szczecin, Poland
  • West Pomeranian University and Technology, Faculty of Chemical Technology and Engineering, Polymer Institute, Piastów Ave 42, 71-065 Szczecin, Poland
  • West Pomeranian University and Technology, Faculty of Chemical Technology and Engineering, Polymer Institute, Piastów Ave 42, 71-065 Szczecin, Poland
  • West Pomeranian University and Technology, Faculty of Chemical Technology and Engineering, Institute of Inorganic Chemical Technology and Environmental Engineering, Piastów Ave 42, 71-065 Szczecin, Poland
Bibliografia
  • 1. Roselli, S., Romagnoli, R. & Deyá, C. (2017). The anti-corrosion performance of water-borne paints in long term tests. Prog. Org. Coat. 109, 172–178. DOI: 10.1016/j.porgcoat.2017.04.031.
  • 2. Heydarpour, M., Zarrabi, A., Attar, M. & Ramezanzadeh, B. (2014). Studying the corrosion protection properties of an epoxy coating containing different mixtures of strontium aluminum polyphosphate (SAPP) and zinc aluminum phosphate (ZPA) pigments. Prog. Org. Coat. 77, 160–167. DOI: 10.1016/j.porgcoat.2013.09.003.
  • 3. Kalendová, A. (2003). Comparison of the anticorrosion efficiencies of pigments based on condensed phosphates and polyphosphosilicates. Anti-corr. Meth. Mater. 50, 82–90. 10.1108/00035590310463957.
  • 4. del Amo, B., Romagnoli, R., Deyá, C. & González, J. (2002). High performance water-based paints with non-toxic anticorrosive pigments. Prog. Org. Coat. 45, 389–397. DOI: 10.1016/S0300-9440(02)00125-X.
  • 5. Ahmed, N., Mohamed, M., Mabrouk, M. & ElShami, A. (2015). Novel anticorrosive pigments based on waste material for corrosion protection of reinforced concrete steel. Constr. Build. Mater. 98, 388–396. DOI: 10.1016/j.conbuildmat.2015.08.111.
  • 6. Bethencourt, M., Botana, F., Marcos, M., Osuna, R. & Sánchez-Amaya, J. (2003). Inhibitor properties of “Green” pigments for paints. Prog. Org. Coat. 46, 280–287. DOI: 10.1016/S0300-9440(03)00013-4.
  • 7. Naderi, R., Arman, S. & Fouladvand, S. (2014). Investigation on the inhibition synergism of new generations of phosphate-based anticorrosion pigments. Dyes Pigm. 105, 23–33. DOI: 10.1016/j.dyepig.2014.01.015.
  • 8. de Lima-Neto, P., de Araújo, A., Araújo, W. & Correia, A. (2008). Study of the anticorrosive behaviour of epoxy binders containing non-toxic inorganic corrosion inhibitor pigments. Prog. Org. Coat. 62, 344–350. DOI: 10.1016/j.porg-coat.2008.01.012.
  • 9. Kowalczyk, K. Przywecka, K. & Grzmil, B. (2018). Influence of novel ammonium-modified zinc-free phosphate nanofillers on anticorrosive features of primer-less polyurethane top-coating compositions. J. Coat. Technol. Res. DOI: 10.1007/s11998-018-0119-7.
  • 10. Kowalczyk, K., Łuczka, K. & Grzmil, B. (2015). Preparation and characterization of anticorrosion polyurethane paints and coats based on novel Zn-free phosphates.” J. Coat. Technol. Res. 12, 153–165. DOI: 10.1007/s11998-018-0119-7.
  • 11. Kowalczyk, K., Łuczka, K., Grzmil, B. & Spychaj, T. (2013). Anticorrosive 2K polyurethane paints based on nanoand microphosphates with high dispersing additive content. Prog. Org. Coat. 76, 1088–1094. DOI: 10.1016/j.porgcoat.2013.03.003.
  • 12. Kowalczyk, K., Łuczka, K., Grzmil, B. & Spychaj, T. (2012). Anticorrosive polyurethane paints with nano- and microsized phosphates. Prog. Org. Coat. 74, 151–157. DOI: 10.1016/j.porgcoat.2011.12.003.
  • 13. Kalendová, A., Veselý, D. & Brodinová, J. (2004). Anticorrosive spinel-type pigments of the mixed metal oxides compared to metal polyphosphates. Anti-Corr. Meth. Mater. 51, 6–17. DOI: 10.1108/00035590410512681.
  • 14. Jašková, V. & Kalendová, A. (2012). Anticorrosive coatings containing modified phosphates. Prog. Org. Coat. 75, 328–334. DOI: 10.1016/j.porgcoat.2012.07.019.
  • 15. Gorodylová, N., Dohnalová, Ž., Šulcová, P., Bĕlina, P. & Vlček, M. (2016). Influence of synthesis conditions on physicochemical parameters and corrosion inhibiting activity of strontium pyrophosphates SrMIIP2O7 (MII=Mg and Zn). Prog. Org. Coat. 93, 77–86. DOI: 10.1016/j.porgcoat.2016.01.004.
  • 16. Abd El-Ghaffar, M., Youssef, E. & Ahmed, N. (2004). High performance anticorrosive paint formulations based on phosphate pigments. Pig. Res. Technol. 33, 226–237. DOI: 10.1108/03699420410546917.
  • 17. Kalenda, P., Kalendová, A. & Veselý, D. (2006). Properties of anticorrosion pigments depending on their chemical composition and PVC value. Pig. Res. Technol. 35/4, 188–199. DOI: 10.1108/03699420610677181.
  • 18. Kalendová, A. (2002). Comparison of the efficiencies of anticorrosive pigments based on chemically modified phosphates. Anti-Corr. Meth. Mater. 49, 364–372. DOI: 10.1108/00035590210440746.
  • 19. Naderi, R., Mahdavian, M. & Darvish, A. (2013). Electrochemical examining behavior of epoxy coating incorporating zinc-free phosphate-based anticorrosion pigment. Prog. Org. Coat., 76, 302–306. DOI: 10.1016/j.porgcoat.2012.09.026.
  • 20. Gawri, S. & Balakrishnan, K. (1994). The effect of the PVC/CPVC ratio on the corrosion resistance properties of organic coatings. Prog. Org. Coat. 23, 363–377. DOI: 10.1016/0033-0655(94)87005-5.
  • 21. Przywecka, K., Grzmil, B.& Kowalczyk, K. (2018). Modyfikacja powierzchniowa i badanie właściwości fizykochemicznych antykorozyjnych pigmentów fosforanowych. In Z. Lendzion-Bieluń & D. Moszyński (Eds.), Postępy w technologii i inżynierii chemicznej 2018 (pp. 192–200). Szczecin: WU ZUT w Szczecinie.
  • 22. Przywecka, K., Grzmil, B. & Kowalczyk, K. (2019). Anticorrosive and physicochemical properties of modified phosphate pigments. Polish J. Chem. Tech. 21, 20–23. DOI: 10.2478/pjct-2019-0004.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1b091202-26df-4d49-98cb-fb2fb88639ac
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