Characterization study of polyAMPS@BMA core-shell particles using two types of RAFT agents

• Autorzy: Shah Nasrullah , Khan Zubair Ullah , Hussain Manzoor , Rehan Touseef , Khan Abbas

Identyfikatory

DOI

10.2478/msp-2021-0015

• Języki publikacji: EN

Abstrakty

EN

The study and application of reversible addition-fragmentation chain transfer (RAFT) polymerization have been widely reported in the literature because of its high compatibility with numerous monomers, reaction conditions, and low polydispersity index. The effect of RAFT agents on the characteristics of the final product is greatly needed to be explored. Our present study aimed to compare the influence of two different types of RAFT agents on the characteristics of the water-soluble polymer (2-acrylamido-2-methylpropane sulfonic acid) (polyAMPS) and their polyAMPS@butyl methacrylate (BMA) core-shell particles. Different analytical techniques including scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD), and thermogravimetric analysis (TGA) were used to ascertain the final morphological, structural, and thermal properties of the resultant products. It was found that RAFT agents have shown a clear influence on the final properties of the resultant polyAMPS and their core-shell particles such as particle size, shape, size distribution, and thermal behavior. This study confirms that RAFT agents can control the final properties of the polymers and their core-shell particles.

Słowa kluczowe

EN

RAFT agents; effect of RAFT agents; polyAMPS; core-shell particles; characterization

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2021
• Tom: Vol. 39, No. 2
• Strony: 200--208
• Opis fizyczny: Bibliogr. 39 poz., rys., tab.

Twórcy

autor

Shah Nasrullah

• Department of Chemistry, Abdul Wali Khan University Mardan, Mardan, KP 23200, Pakistan

autor

Khan Zubair Ullah

• Department of Chemistry, Abdul Wali Khan University Mardan, Mardan, KP 23200, Pakistan

autor

Hussain Manzoor

• Department of Chemistry, Abdul Wali Khan University Mardan, Mardan, KP 23200, Pakistan

autor

Rehan Touseef

• Department of Biochemistry, Shaheed Benazir Bhutto Women University, Peshawar, KP 25000, Pakistan

autor

Khan Abbas

• Department of Chemistry, Abdul Wali Khan University Mardan, Mardan, KP 23200, Pakistan

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