Bio Oil Production by Thermal and Catalytic Pyrolysis of Waste Tires

• Autorzy: Khalaf Dunya Ahmed , Abudi Zaidun Naji , Dhaher Saadi Muhammed

Identyfikatory

DOI

10.12911/22998993/140258

• Języki publikacji: EN

Abstrakty

EN

In this study, pyrolysis of shredded waste tire was carried out thermally and catalytically in a fixed bed reactor. Thermal pyrolysis was performed at temperatures of 330 °C, 430 °C, 530 °C, and 630 °C under Ar. flow rate of 0.5 L/min as a carrier gas and retention time of 15 min catalytic pyrolysis was carried out at temperature of 530 °C. The effects of temperature and two types of catalysts (CaCO₃ and SiO₂/Al₂O₃) were studied on the yield of pyrolysis products. Fourier transform infrared spectroscopy (FTIR) and Gas chromatography mass spectrometry (GC-MS) analysis for the oil products that were obtained by thermal and catalytic pyrolysis at 530 °C for chemical characterization. Oil, solid, and gas products yield by thermal pyrolysis at 530 °C were 50 wt. %, 35.6 wt. %, and 14.4 wt. % respectively, when the CaCO₃ catalyst was used, the products distribution was 52 wt. %, 38.5 wt. %, and 9.5 wt. % respectively. While using SiO₂ /Al₂O₃ the pyro oil, and char, and gas were decreased to 47 wt. %, 38 wt. %, and 15 wt. % respectively. The chemical composition of pyrolysis oil mainly included hydrocarbons compounds, predominantly Limonene which was represented by Cyclohexene, 1-methyl-4-(1-methylethenyl).

Słowa kluczowe

EN

waste tires; pyrolysis; catalyst; limonene

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2021
• Tom: Vol. 22, nr 8
• Strony: 189--199
• Opis fizyczny: Bibliogr. 34 poz., rys., tab.

Twórcy

autor

Khalaf Dunya Ahmed

• Environmental Engineering Department, College of Engineering, Mustansiriayah University, Baghdad, Iraq

autor

Abudi Zaidun Naji

• Environmental Engineering Department, College of Engineering, Mustansiriayah University, Baghdad, Iraq
• [e-mail]

• https://orcid.org/0000-0001-5630-6373

autor

Dhaher Saadi Muhammed

• Environmental Research, University of Technology, Baghdad, Iraq

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