Removal of fluoride ions by batch electrodialysis

• Autorzy: Majewska-Nowak K. , Grzegorzek M. , Kabsch-Korbutowicz M.

Identyfikatory

DOI

10.5277/epe150106

• Języki publikacji: EN

Abstrakty

EN

Suitability of conventional batch electrodialysis to fluoride removal from aqueous solutions has been investigated. The experiments were conducted with the use of laboratory installation PCCell BED-1 System at a constant current density (1.56 or 2.34 mA/cm2). The influence of initial fluoride and salt (NaCl) concentration, as well as the presence of organic matter on the process performance was studied. It was found that the separation efficiency increased upon decrease of initial fluoride content in model solutions. Permissible final concentration of fluorides in the product water (1.5 mg/dm3) was obtained for experiments with solutions of initial fluoride concentration equal to 5 mg F–/dm3 and 10 mg F–/dm3. The presence of humic acids in fluoride solutions subjected to electrodialysis treatment has no adverse effect on the defluorization and desalination efficiency. The calculated electrical energy demand depended on composition of fluoride solution and varied from 0.121 to 0.895 kWh/m3.

Słowa kluczowe

EN

fluorine compounds; biological materials; electrodialysis; fluoride concentrations; fluoride removal

PL

związki fluoru; materiały biologiczne; elektrodializa; stężenie fluorków; usuwanie fluorków

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2015
• Tom: Vol. 41, nr 1
• Strony: 67--81
• Opis fizyczny: Bibliogr. 26 poz., tab., rys.

Twórcy

autor

Majewska-Nowak K.

• Department of Environmental Engineering, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Grzegorzek M.

• Department of Environmental Engineering, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Kabsch-Korbutowicz M.

• Department of Environmental Engineering, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

Bibliografia

• [1] JHA S.K., MISHRA V.K., SHARMA D.K., DAMODARAN T., Fluoride in the environment and its metabolism in humans, Rev. Environ. Contam. Toxicol., 2011, 211, 121.
• [2] DOLBIER W.R., Fluorine chemistry at the millennium, J. Fluorine Chem., 2005, 126 (2), 157.
• [3] DOLAR D., KOŠUTIĆ K., VUČIĆ B., RO/NF treatment of wastewater from fertilizer factory – removal of fluoride and phosphate, Desalination, 2011, 265, 237.
• [4] SHEN F., CHEN X., GAO G., CHEN P., Electrochemical removal of fluoride ions from industrial wastewater, Chem. Eng. Sci., 2003, 58, 987.
• [5] OZSVATH D.L., Fluoride and environmental health. A review, Rev. Environ. Sci. Biotechnol., 2009, 8 (1), 59.
• [6] WHO, Guidelines for Drinking Water Quality, World Health Organization, 2006.
• [7] Regulation of the Minister of the Environment of 20.04.2010 changing the regulation on water quality for drinking purpose, Journal of Laws, 2010, No. 72, item. 466.
• [8] Regulation of the Minister of the Environment of 24.07.2006 on the conditions to be met with the introduction of sewage into the water or land, and on substances particularly harmful to the aquatic environment, Journal of Laws, 2006, No. 137, item. 984.
• [9] SUMANTA K., MUKHERJEE K., GHOSH K.S., SAHA B., Sources and toxicity of fluoride in the environment, Res. Chem. Intermed., 2013, 39 (7), 2881.
• [10] PANDEY J., PANDEY U., Fluoride contamination and fluorosis in rural community in the vicinity of a phosphate fertilizer factory in India, Bull. Environ. Contam. Toxicol., 2011, 87 (3), 245.
• [11] MOHAPATRA M., ANAND S., MISHRA B.K., GILES D.E., SINGH P., Review of fluoride removal from drinking water, J. Environ. Manage., 2009, 91, 67.
• [12] BHATNAGAR A., KUMAR E., SILLANPÄÄ M., Fluoride removal from water by adsorption. A review, Chem. Eng. J., 2011, 171, 811.
• [13] AMOR Z., BARIOU B., MAMERI N., TAKY M., NICOLAS S., ELMIDAOUI A., Fluoride removal Corn brackish water by electrodialysis, Desalination, 2001, 133, 215.
• [14] EMAMJOMEH M.M., SIVAKUMAR M., Fluoride removal by a continuous flow electrocoagulation reactor, J. Environ. Manage., 2009, 90, 1204.
• [15] DROBNIK M., LATOUR T., SZIWA D., The elements of specific biological activity in therapeutic waters in polish health resorts, J. Elem., 2011, 16, 525.
• [16] ADAMOWICZ-KLEPALSKA B., KRZYŻAGÓRSKA J., EMERICH-POPLATEK K., Fluoride in the environment and oral health in children, Fluoride, 2000, 33 (1) 2000, S1.
• [17] STRATHMANN H., Ion-exchange membrane separation processes. Membrane Science and Technology, Series 9, Elsevier, 2004.
• [18] ERGUN E., TOR A., CENGELOGLU Y., KOCAK I., Electrodialytic removal of fluoride from water: Effects of process parameters and accompanying anions, Sep. Purif. Technol., 2008, 64, 147.
• [19] AMOR Z., BARIOU B., MAMERI N., TAKY M., NICOLAS S., ELMIDAOUI A., Fluoride removal from brackish water by electrodialysis, Desalination, 2001, 133, 215.
• [20] ZENI M., RIVEROS R., MELO K., PRIMERI R., LORENZINI S., Study on fluoride reduction in artesian well-water electrodialysis process, Desalination, 2005, 185, 241.
• [21] TAHAIKT M., ACHARY I., MENKOUCHI-SAHLI M.A., AMOR Z., TAKY M., ALAMI A., BOUGHRIBA A., HAFSI M., ELMIDAOUI A., Defluoridation of Moroccan groundwater by electrodialysis: continuous operation, Desalination, 2006, 189, 215.
• [22] KERI R.S., HOSAMANI K.M., SEETHARAMA REDDY H.R., NATARAJ S.K., AMINABHAVI T.M., Application of the electrodialytic pilot plant for fluoride removal, J. Water Chem. Tech., 2011, 33, 293.
• [23] LAHNID S., TAHAIKT M., ELAROUI K. IDRISSI I., HAFSI M., LAAZIZ I., AMOR Z., TIYAL F., ELMIDAOUI A., Economic evaluation of fluoride removal by electrodialysis, Desalination, 2008, 230, 213.
• [24] CHAKRABARTY T., RAJESH M.A, JASTI A., THAKUR A.K., SINGH A.K., PRAKASH S.,KULSHRESTHA V., SHAHI K.V., Stable ion-exchange membranes for water desalination by electrodialysis, Desalination, 2011, 282, 2.
• [25] BANASIAK J.J., SCHAFER A.I., Removal of boron, fluoride and nitrate by electrodialysis in the presence of organic matter, J. Membr. Sci., 2009, 334, 101.
• [26] KABAY N., ARAR O., SAMATYA S., YUKSEL U., YUKSEL M., Separation of fluoride from aqueous solution by electrodialysis: Effect of process parameters and other ionic species, J. Hazard. Mater., 2008, 153, 107