Removal of Azo Dye Acid Red 27 from Aqueous Solutions Using Classical and Modified Fenton Reagent with Zero-Valent Iron

• Autorzy: Kliś Simona , Thomas Maciej , Barbusiński Krzysztof , Gołombek Klaudiusz , Krzemiński Łukasz , Chyc Marek

Identyfikatory

DOI

10.5604/01.3001.0013.2908

Warianty tytułu

PL

Usuwanie barwnika azowego czerwień kwasowa 27 z roztworów wodnych przy zastosowaniu odczynnika Fentona modyfikowanego żelazem zero wartościowym

• Języki publikacji: EN

Abstrakty

EN

The article compares the classic Fenton reagent (Fe²⁺/H₂O₂) with its modification with zero-valent iron (ZVI/ H₂O₂) to remove azo dye Acid Red 27 from aqueous solutions at a concentration of 100 mg/L. For both methods, the most favorable parameter values were determined at which visual discoloration of the solutions tested was obtained (for Fe²⁺/ H₂O₂:pH 3.5, H₂O₂=60 mg/L, Fe²⁺/ H₂O₂=0.3, t=15 min, and for ZVI/ H₂O₂pH = 3, H₂O₂=40 mg/L, ZVI=80 mg/L, t=15 min). Under these conditions, the COD value was reduced by 71.5% and 69.2% for the classic Fenton and its modification, respectively. A reduction in toxicity was also obtained for Vibrio fischeri bacteria to below 25% by using the Microtox test. ZVI digestion at acidic pH for 10 minutes allowed to shorten the reaction time by about four times - from 15 to 4 minutes. BET analysis showed that the specific surface area increases with the digestion time, which significantly accelerates the reaction. The visual discoloration of aqueous solutions was obtained, and the final COD values were very small, ranging from 49-53 mg O₂/L. According to the Aliivibrio fischeri toxicity classification test for water samples, all solutions of dyes tested can be considered as non-toxic (toxicity value <25%). In the study presented, results of decreasing the COD value and concentration of the dye in the ZVI/ H₂O₂ method obtained are slightly worse compared to the Fe²⁺/ H₂O₂method. However, taking the decolorisation time as a criterion, a four times faster decolorisation time was obtained in the ZVI/ H₂O₂ method, compared to the Fe²⁺/ H₂O₂ method.

PL

W artykule porównano klasyczny odczynnik Fentona (Fe²⁺/H₂O₂) z jego modyfikacją żelazem o zerowej wartościowości (ZVI/ H₂O₂), w celu usunięcia barwnika azowego czerwień kwasowa 27 z wodnych roztworów, o stężeniu 100 mg/L. Dla obu metod wyznaczono najkorzystniejsze wartości parametrów, przy których uzyskano wizualne odbarwienie badanych roztworów (dla (Fe²⁺/H₂O₂): pH 3,5, H₂O₂=60 mg/L, Fe²⁺/ H₂O₂=0,3, t=15 min. i dla ZVI/H2O2: pH 3, H₂O₂=40 mg/L, ZVI=80 mg/L, t=15 min. W tych warunkach wartość ChZT spadła o 71,5% i 69,2% dla klasycznego Fentona i jego modyfikacji. Zmniejszenie toksyczności uzyskano również dla bakterii Aliivibrio fischeri (poniżej 25%) przy zastosowaniu testu Microtox. Trawienie ZVI w kwasowym pH przez 10 minut pozwoliło skrócić czas reakcji około cztery razy z 15 do 4 minut. Analiza BET wykazała, że powierzchnia właściwa wzrasta wraz z czasem trawienia, co znacznie przyspiesza reakcję. Uzyskano wizualne odbarwienie roztworów wodnych, a końcowe wartości ChZT były bardzo małe i mieściły się w zakresie 49-53 mg O₂/L. Zgodnie z testem klasyfikacji toksyczności wobec Vibrio fischeri dla próbek wodnych, wszystkie testowane roztwory barwników można uznać za nietoksyczne (wartość toksyczności <25%).

Słowa kluczowe

EN

Acid Red 27; Fenton's reagent; modified Fenton reagent; zero-valent iron; wastewater treatment

PL

czerwień kwasowa 27; odczynnik Fentona; zmodyfikowany odczynnik Fentona; żelazo o zerowej wartościowości; oczyszczanie ścieków

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2019
• Tom: Vol. 27, no. 5 (137)
• Strony: 100--106
• Opis fizyczny: Bibliogr. 30., rys., tab.

Twórcy

autor

Kliś Simona

• Central Mining Institute, Plac Gwarków 1, 40-166 Katowice, Poland

autor

Thomas Maciej

• Chemiqua Company, ul. Skawińska 25/1, 31-066 Kraków, Poland

autor

Barbusiński Krzysztof

• Silesian University of Technology, Institute of Water and Wastewater Engineering, ul. Konarskiego 18, 44-100 Gliwice, Poland

autor

Gołombek Klaudiusz

• Silesian University of Technology, Institute of Engineering Materials and Biomaterials, ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Krzemiński Łukasz

• Silesian University of Technology, Institute of Engineering Materials and Biomaterials, ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Chyc Marek

• State Higher Vocational School in Tarnów, Institute of Mathematical and Natural Sciences, ul. Mickiewicza 8, 33-100 Tarnów, Poland

Bibliografia

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