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Żużel hutniczy : niebezpieczny odpad, wartościowy surowiec czy źródło cennych informacji?

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Warianty tytułu
EN
Metallurgical slag : hazardous waste, valuable raw material or a source of useful information?
Języki publikacji
PL
Abstrakty
EN
Metallurgical slags are a byproduct of metal ore smelting and are classified as waste from thermal processes. The production of one tonne of copper or lead generates approximately two tonnes of slag. During thousands of years of metallurgy, vast amounts of slags have been produced and deposited in slag heaps. Although slags contain significantly less metal than the corresponding ores, their metal concentrations are still higher than those found in barren rocks. Slags have gained increasing significance in the search for alternative metal sources and with growing environmental awareness. Due to their similarity to igneous rocks, they can be studied using classical methods of Earth sciences. Results of those studies support the development of metal recovery technologies and enhance our understanding of element cycles in environments affected by human activity. Moreover, research on historical slags provides valuable insights into the development of ancient civilizations. Studying slags not only contributes to better management of metallurgical waste but also offers important knowledge about both the past and future use of mineral resources.
Rocznik
Strony
829--836
Opis fizyczny
Bibliogr. 54 poz., fot., wykr.
Twórcy
  • Instytut Nauk Geologicznych, Uniwersytet Wrocławski, pl. M. Borna 9, 50-204 Wrocław
autor
  • Instytut Nauk Geologicznych, Uniwersytet Wrocławski, pl. M. Borna 9, 50-204 Wrocław
  • Instytut Nauk Geologicznych, Uniwersytet Wrocławski, pl. M. Borna 9, 50-204 Wrocław
Bibliografia
  • 1. ÁLVAREZ-VALERO A.M., PÉREZ-LÓPEZ R., MATOS J., CAPITÁN M.A., NIETO J.M., SÁEZ R., DELGADO J., CARABALLO M. 2008 - Potential environmental impact at Säo Domingos mining district (Iberian Pyrite Belt, SW Iberian Peninsula): evidence from a chemical and mineralogical characterization. Environmental Geology, 55 (8): 1797-1809.
  • 2. BARON S., TÂMAŞ C.G., LE CARLIER C. 2014 - The significance of Pb isotopes in metal provenance studies. Archaeometry, 56: 665-680.
  • 3. BAYLESS E.R., SCHULZ M.S. 2003 - Mineral precipitation and dissolution at two slag-disposal sites in northwestern Indiana, USA. Environmental Geology, 45: 252-261.
  • 4. BRIL H., ZAINOUN K., PUZIEWICZ J., COURTIN-NOMADE A., VANAECKER M., BOLLINGER J-C. 2008 - Secondary phases from the alteration of a pile of zinc-smelting slag as indicators of environmental conditions: An example from Świętochłowice, Upper Silesia, Poland. Canadian Mineralogist, 46: 1235-1248.
  • 5. DECYZJA KOMISJI, 2020 - Decyzja Komisji z dnia 3 maja 2000 r. zastępująca decyzję 94/3/WE ustanawiającą wykaz odpadów zgodnie z art. 1 lit. a) dyrektywy Rady 75/442/EWG w sprawie odpadów oraz decyzję Rady 94/904/WE ustanawiającą wykaz odpadów niebezpiecznych zgodnie z art. 1 ust. 4 dyrektywy Rady 91/689/EWG w sprawie odpadów niebezpiecznych; http://data.europa.eu/eli/dec/2000/532/2015-06-01
  • 6. DERKOWSKA K., ŚWIERK M., NOWAK K. 2021 - Reconstruction of Copper Smelting Technology Based on 18-20th-Century Slag Remains from the Old Copper Basin, Poland. Minerals, 11 (9), 926.
  • 7. DERKOWSKA K., KIERCZAK J., POTYSZ A., PIETRANIK A., PĘDZIWIATR A., ETTLER V., MIHALJEVIČ M. 2023 - Combined approach for assessing metal(loid)s leaching, mobility and accumulation in a specific near-neutral (pH) environment of a former Cu-smelting area in the Old Copper Basin, Poland. Applied Geochemistry, 154, 105670.
  • 8. ETTLER V., JOHAN Z., TOURAY J.C., JELINEK E. 2000 - Zinc partitioning between glass and silicate phases in historical and modern lead-zinc metallurgical slag from the Pribram district, Czech Republic. Comptes Rendus de l Académie des Sciences - Series IIA - Earth and Planetary Science, 331 (4):245-250.
  • 9. ETTLER V., JOHAN Z., KŘÍBEK B., ŠEBEK O., MIHALJEVIČ M. 2009 - Mineralogy and environmental stability of slags from the Tsumeb smelter, Namibia. Applied Geochemistry, 24: 1-15.
  • 10. ETTLER V., VITKOVA M. 2021 - Slag Leaching Properties and Release of Contaminants. [W:] Piatak N., Ettler V. (red.), Metallurgical slags: environmental geochemistry and resource potential. Royal Society of Chemistry, London: 151-173.
  • 11. GEE C., RAMSEY M.H., MASKALL J. THORNTON I. 1997 - Mineralogy and weathering processes in historical smelting slags and their effect on the mobilisation of lead. Journal of Geochemical Exploration, 58: 249-257.
  • 12. HOBSON A.J., STEWART D.I., BRAY A.W., MORTIMER J.G., MAYES W.M., ROGERSON M., BURKE I.T. 2017 - Mechanism of Vanadium Leaching during Surface Weathering of Basic Oxygen Furnace Steel Slag Blocks: A Microfocus X-ray Absorption Spectroscopy and Electron Microscopy. Environmental Science and Technology, 51,7823.
  • 13. KĄDZIOŁKA K., PIETRANIK A., KIERCZAK J., POTYSZ A., STOLARCZYK T. 2020 - Towards better reconstruction of smelting temperatures: Methodological review and the case of historical K-rich Cu-slags from the Old Copper Basin, Poland. Journal of Archaeological Science, 118, 105142.
  • 14. KIERCZAK J., PIETRANIK A. 2011 - Mineralogy and composition of historical Cu slags from the Rudawy Janowickie Mountains, southwestern Poland. Canadian Mineralogist, 49: 1281-1296.
  • 15. KIERCZAK J., NEEL C., PUZIEWICZ J., BRIL H. 2009 - The mineralogy and weathering of slag produced by the smelting of lateritic Ni ores, Szklary, southwestern Poland. Canadian Mineralogist, 47: 557-572.
  • 16. KIERCZAK J., POTYSZ A., PIETRANIK A., TYSZKA R., MODELSKA M., NÉEL C., ETTLER V., MIHALJEVIE M. 2013-Environmental impact of the historical Cu smelting in the Rudawy Janowickie Mountains (south-western Poland). Journal of Geochemical Exploration, 124: 183-194.
  • 17. KUCHA H. JĘDRZEJCZYK B. 1995 - Primary minerals of mining and metallurgical Zn-Pb dumps at Bukowno, Poland, and their stability during weathering. Mineralogia Polonica, 26: 75-99.
  • 18. KUCHA H., MARTENS A., OTTENBURGS R., DE VOS W. VIAENE W. 1996 - Primary minerals of Zn-Pb mining and metallurgical dumps and their environmental behavior at Plombieres, Belgium. Environmental Geology, 27: 1-15.
  • 19. KUPCZAK K, WARCHULSKI R. 2024 - SLAG-software for reconstruction of historical smelting processes based on slag properties. Archaeometry, 66 (4): 803-823.
  • 20. KUPCZAK K., WARCHULSKI R., GAWĘDA A., JANIEC J. 2024 - Bloomery iron production in the Holy Cross Mountains (Poland) area during the Roman period: conditions during the metallurgical process and their uniformity between locations. Heritage Science,12, 147.
  • 21. LASTRA R., CARSON D. 1996 - Mineralogical characterization of deleterious elements in ten slags from Canadian non-ferrous sulfide smelters II. Canada Centre for Mineral and Energy Technology, Mining and Mineral Sciences Laboratories, Report: 96-135.
  • 22. LOTTERMOSER B.G. 2005 - Evaporative mineral precipitates from a historical smelting slag dump, Rio Tinto, Spain. Neues Jahrbuch für Mineralogie - Abhandlungen Journal of Mineralogy and Geochemistry 181 (2): 183-190.
  • 23. MANZ M., CASTRO L.J. 1997 - The environmental hazard caused by smelter slags from the Sta. Maria de la Paz mining district in Mexico. Environmental Pollution, 98 (1): 7-13.
  • 24. MAZUREK S., DERKOWSKA K., JANUSZEWSKA A., SROGA C. 2025 - Towards sustainable resource management: Anational assessment ofhistorical mining waste in Poland. Resources Policy, 102, 105482.
  • 25. MIKODA B., POTYSZ A., KMIECIK E., 2019 - Bacterial leaching of critical metal values from Polish copper metallurgical slags using Acidithiobacillus thiooxidans. Journal of Environmental Management, 236: 436-445.
  • 26. MIKODA B., POTYSZ A., KUCHA H., KMIECIK E. 2020 - Vanadium removal from spent sulfuric acid plant catalyst using citric acid and Acidithiobacillus thiooxidans. Archives of Civil and Mechanical Engineering, 20, 132.
  • 27. MUSZER A. 1996 - Charakterystyka petrograficzno-mineralogiczna żużli metalurgicznych z huty Miedzi Głogów. Fizykochemiczne Problemy Mineralurgii, 30: 193-205.
  • 28. MUSZER A. 2006 - Petrographical and mineralogical characteristics of the metallurgical slag from the dörschl furnace (Głogów foundry, Poland). Fizykochemiczne Problemy Mineralurgii, 40: 89-98.
  • 29. MUSZER A., CIOSKA T. 2018 - Przeróbka odpadów górniczo-hutniczych przy pomocy techniki mikrofalowej. Górnictwo Odkrywkowe, 3: 63-68.
  • 30. NOWAK K., STOLARCZYK T., STOS-GALE Z., BARON J., DERKOWSKA K., DERKOWSKI P., MIAZGA B., WOODHEAD J., KARASIŃSKI J., MAAS R. 2023 - Question of local exploitation of copper ore deposits in the Urnfield time in Poland. Frontiers in Earth Science, 11, 1184949.
  • 31. NOWIŃSKA K. 2022 - Formy występowania metali w żużlach z hutnictwa cynku i ołowiu w aspekcie środowiskowym i możliwości ich odzysku. Wydawnictwo Politechniki Śląskiej.
  • 32. PETERSEN J. 2016 - Heap leaching as a key technology for recovery of values from low-grade ores-A brief overview. Hydrometallurgy, 165: 206-212.
  • 33. PIATAK N.M., ETTLER V. 2021 - Introduction: metallurgical slags-environmental liability or valuable resource? [W:] Piatak N., Ettler V. (red.), Metallurgical slags: environmental geochemistry and resource potential. Royal Society of Chemistry, London: 1-13.
  • 34. PIATAK N.M., ETTLER V., HOPPE D. 2021 - Geochemistry and mineralogy of slags. [W:] Piatak N., Ettler V. (red.), Metallurgical slags: environmental geochemistry and resource potential. Royal Society of Chemistry, London: 59-124.
  • 35. PIETRANIK A., KIERCZAK J., TYSZKA R., SCHULZ B. 2018 - Understanding Heterogeneity of a Slag-Derived Weathered Material: The Role of Automated SEM-EDS Analyses. Minerals, 8, 513.
  • 36. PN-EN 12457-1-4:2006 Charakteryzowanie odpadów - Wymywanie - Badanie zgodności w odniesieniu do wymywania ziarnistych materiałów odpadowych i osadów, Części 1-4.
  • 37. POTYSZ A., KIERCZAK J. 2019 - Prospective (Bio)leaching of Historical Copper Slags as an Alternative to Their Disposal. Minerals, 9 (9), 542.
  • 38. POTYSZ A., KIERCZAK J., FUCHS Y., GRYBOS M., GUIBAUD G., LENS P.N.L., VAN HULLEBUSCH E.D. 2016a - Characterization and pH-dependent leaching behaviour of historical and modern copper slags. Journal of Geochemical Exploration, 160: 1-15.
  • 39. POTYSZ A., GRYBOS M., KIERCZAK J., GUIBAUD G., LENS P.N.L., VAN HULLEBUSCH E.D. 2016b - Bacterially-mediated weathering of crystalline and amorphous Cu-slags. Applied Geochemistry, 64: 92-106.
  • 40. POTYSZ A., LENS P.N.L., VAN DE VOSSENBERG J., RENE E.R., GRYBOS M., KIERCZAK J., GUIBAUD G., VAN HULLEBUSCH E.D. 2016c - Comparison of Cu, Zn and Fe bioleaching from Cu-metallurgical slags in the presence of Pseudomonas fluorescens and Acidithiobacillus thiooxidans. Applied Geochemistry, 68: 39-52.
  • 41. POTYSZ A., KIERCZAK J., PIETRANIKA., KĄDZIOŁKA K. 2018a - Mineralogical, geochemical, and leaching study of historical Cu-slags issued from processing of the Zechstein formation (Old Copper Basin, southwestern Poland). Applied Geochemistry, 98: 22-35.
  • 42. POTYSZ A., KIERCZAK J., GRYBOS M., PĘDZIWIATR A., VAN HULLEBUSCH E.D. 2018b - Weathering of historical copper slags in dynamic experimental system with rhizosphere-like organic acids. Journal of Environmental Management, 222: 325-337.
  • 43. POTYSZ A., VAN HULLEBUSCH E.D. 2021 - Secondary metal recovery from slags. [W:] Piatak N., Ettler V. (red.), Metallurgical slags: environmental geochemistry and resource potential. Royal Society of Chemistry, London: 268-301.
  • 44. POTYSZ A., VAN HULLEBUSCH E.D., KIERCZAK J. 2018c - Perspectives Regarding the Use of Metallurgical Slags as Secondary Metal Resources - A Review of Bioleaching Approaches. Journal of Environmental Management, 219: 138-152.
  • 45. POTYSZ A., PĘDZIWIATR A., HEDWIG S., LENZ M. 2020 - Bioleaching and toxicity of metallurgical wastes. Journal of Environmental Chemical Engineering, 8 (6), 104450.
  • 46. SHEN H., FORSSBERG E. 2003 - An overview of recovery of metals from slags. Waste Manage, 23: 933-949.
  • 47. STOLARCZYK T., KOBYLAŃSKA M., KIERCZAK J., MADZIARZ M., GARBACZ-KLEMPKA A. 2017 - Leszczyna. Monografia ośrodka górnictwa i metalurgii rud miedzi. Radziechów. Fundacja Archeologiczna Archeo.
  • 48. TYSZKA R., KIERCZAK J., PIETRANIK A., ETTLER V., MIHALJEVIČ M.2014 - Extensive weathering of zinc smelting slag in a heap in Upper Silesia (Poland): Potential environmental risks posed by mechanical disturbance of slag deposits. Applied Geochemistry, 40: 70-81.
  • 49. TYSZKA R., PIETRANIK A., KIERCZAK J., ZIELIŃSKI G., DARLING J.2018 - Cadmium distribution in Pb-Zn slags from Upper Silesia, Poland: Implications for cadmium mobility from slag phases to the environment. Journal of Geochemical Exploration, 186: 215-224.
  • 50. USEPA Method 1311, Toxicity Characteristic Leaching Procedure (TCLP), USEPA, Washington, 1992.
  • 51. U.S. GEOLOGICAL SURVEY, 2022 - Mineral commodity summaries (2022).
  • 52. U.S. Geological Survey; https://doi.org/10.3133/mcs2022
  • 53. WARCHULSKI R., GAWĘDA A. JANECZEK J., KĄDZIOŁKA-GAWEŁ M. 2016 - Mineralogy and origin of coarse-grained segregations in the pyrometallurgical Zn-Pb slags from Katowice-Wełnowiec (Poland). Mineralogy and Petrology, 110: 681-692.
  • 54. WARCHULSKI R., GAWĘDAA., KUPCZAK K., BANASIK K., KRZYKAWSKI T. 2020 - Slags from Ruda Śląska, Poland as a large-scale laboratory for the crystallization of rare natural rocks: melilitolites and paralavas. Lithos, 372-373, 105666.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-19a64a9e-bc96-42cb-baec-a81c29251311
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