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Removal of calcium from magnesite flotation concentrate by selective leaching and kinetics analysis

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Dolomite is the main impurity mineral in magnesite ore, affecting the quality of magnesite products. This study proposed a selective leaching process to reduce the calcium content from the magnesite flotation concentrate using hydrochloride acid (HCl). Laboratory scale tests were conducted to explore the influence of operation factors including HCl concentration, leaching temperature and time, stirring speed on the leaching recovery. The results showed that leaching recovery of CaO and MgO increased with increasing HCl concentration, temperature and time. The CaO leaching recovery is always significantly higher than that of MgO, indicating a good selectivity of HCl to leach dolomite from magnesite. The leaching kinetics of both dolomite and magnesite follow the Avrami model and are diffusion controlled, with an activation energy of 43±}1 kJ×mol-1 and 25±}4 kJ×mol-1, respectively.
Słowa kluczowe
Rocznik
Strony
939--948
Opis fizyczny
Bibliogr. 32 poz., rys., tab.
Twórcy
autor
  • State Key Laboratory of Mineral Processing, BGRIMM Technology Group, Beijing 100160, China
autor
  • State Key Laboratory of Mineral Processing, BGRIMM Technology Group, Beijing 100160, China
Bibliografia
  • AVRAMI, M., 1939. Kinetics of phase change. I. General Theory. J. Chem. Phys.7, 1103-1112.
  • ASHRAF, M., ZAFAR, Z.I., ANSARI, T.M., 2005. Selective leaching kinetics and upgrading of low-grade calcareous phosphate rock in succinic acid. Hydrometallurgy. 80, 286-292.
  • ABALI, Y., COPUR, M., YAVUZ, M., 2006. Determination of the optimum conditions for dissolution of magnesite with H2SO4 solutions. Indian J. Chem. Technol.13, 391-397.
  • BUSENBERG, E., PLUMMER, L.N., 1982. The kinetics of dissolution of dolomite in CO2-H2O systems at 1.5 to 65℃ and 0 to 1 atm PCO2. AM. J. Sci. 282, 45-79.
  • BAKAN, F., LACIN, O., BAYRAK, B., SARAC, H., 2006. Dissolution kinetics of natural magnesite in lactic acid solutions. Int. J. Miner. Process. 80, 27–34.
  • BAYRAK, B., LACIN, O., BAKAN, F., SARAC, H., 2006. Investigation of dissolution kinetics of natural magnesite in gluconic acid solutions. Chem. Eng. J. 117,109-115.
  • BAYRAK, B., LACIN, O., SARAC, H., 2010. Kinetic study on the leaching of calcined magnesite in gluconic acid solutions. J. Ind. Eng. Chem.16, 479-484.
  • BREZANI, I., SKVARLA, J., SISOL, M., 2017. Reverse froth flotation of magnesite ore by using (12-4-12) cationic gemini surfactant. Miner. Eng. 110, 65-68.
  • CHOU, L., GARRELS, R.M., WOLLAST, R., 1989. Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals. Chem. Geol. 78, 269-282.
  • CHEN, G.L., TAO, D., 2004. Effect of solution chemistry on flotability of magnesite and dolomite. Int. J. Miner. Process. 74, 343-357.
  • CAO, Z., ZHONG, H., JIANG, T., WANG, S., LIU, G.Y., XIA, L.Y., 2012. A novel hydrometallurgy of molybdenite concentrate and its kinetics. J. Chem. Technol. Biotechnol. 87, 938-942.
  • FOUDA, M.F.R., ABD-ELZAHER M.M., AMIN R.S., 1999. Exploitation of Egyptian dolomite and magnesite ores for the preparation of magnesium compounds I. Kinetics of the reaction with hydrochloric acid. S. Afr. J. Chem. 52, 84-89.
  • FOUDA, M.F.R., ABD-ELZAHER M.M., AMIN R.S., 1999. Exploitation of Egyptian dolomite and magnesite ores for the preparation of magnesium compounds Ⅱ. Kinetics of reaction with nitric and sulphuric acids. S. Afr. J. Chem. 52, 90-94.
  • GENCE, N., OZDAG, H., 1995. Surface properties of magnesite and surfactant adsorption mechanism. Int. J. Miner. Process. 43, 37-47.
  • GENCE, N., 2006. Wetting behavior of magnesite and dolomite surfaces. Appl. Surf. Sci. 252, 3744-3750.
  • GENCE, N., OZBAY, N., 2006.Ph dependence of electrokinetic behavior of dolomite and magnesite in aqueous electrolyte solutions. Appl. Surf. Sci. 252, 8057-8061.
  • GHARABAGHI, M., NOAPARAST, M., IRANNAJAD, M., 2009. Selective leaching kinetics of low-grade calcareous phosphate ore in acetic acid. Hydrometallurgy. 95, 341-345.
  • HEYDARPOUR, T., REZAI, B., GHARABAGHI, M., 2011. A kinetics study of the leaching of a calcareous phosphate rock by lactic acid. Chem. Eng. Res. Des. 89, 2153-2158.
  • KARAOGLU, H., YANMIS, D., GURKOK, S., 2016. Magnesite enrichment with pseudomonas oryzihabitans isolated from magnesite ore. Geomicrobiol. J. 33, 46–51.
  • LACIN, O., DONMEZ, B., DEMIR, F., 2005. Dissolution kinetics of natural magnesite in acetic acid solutions. Int. J. Miner. Process. 75, 91-99.
  • LI, Y., KAWASHIMA, N., LI, J., CHANDRA, A.P., GERSON, A.R., 2013. A review of the structure, and fundamental mechanisms and kinetics of the leaching of chalcopyrite. Adv. Colloid Interface Sci. 197-198, 1-32.
  • KAYA, M. ERDOGAN, N., 2004. Production of magnesium compounds from KUMAS (Turkey) electro-filter magnesite dust waste. Global Symposium on Recycling, Waste Treatment and Clean Technologies, Madrid, Spain, pp. 563-572.
  • ONCEK, S., KAYA, M., 1994. Concentration of magnesite by column flotation. 5th International Mineral Processing Symposium, Cappadocia, Turkey, pp. 211-218.
  • RAZA, N., Zafar, Z.I., NAJAM-UL-HAQ, M., 2014. Utilization of formic acid solutions in leaching reaction kinetics of natural magnesite ores. Hydrometallurgy 149,183-188.
  • RAZA, N., ZAFAR, Z.I., NAJAM-UL-HAQ, KUMAR, R.V., 2015. Leaching of natural magnesite ore in succinic acid solutions. Int. J. Miner. Process. 139, 25-30.
  • SANTANA, A.N., PERES, A.E.C., 2001. Reverse magnesite flotation. Miner. Eng. 14, 107-111.
  • SHEIBANI, S., ATAIE, A., HESHMATI-MANESH, S., 2008. Kinetics analysis of mechano-chemically and thermally synthesized Cu by Johnson–Mehl–Avrami model. J. Alloy. Compd. 455, 447-453.
  • SAFARI, V., ARZPEYMA, G., RASHCHI, F., MOSTOUFI, N., 2009. A shrinking particle-shrinking core model for leaching of a zinc ore containing silica. Int. J. Miner. Process. 93, 79-83.
  • SOKIC, M.D., MARKOVIC, B., ZIVKOVIC, D., 2009. Kinetics of chalcopyrite leaching by sodium nitrate in sulphuric acid. Hydrometallurgy. 95, 273-279.
  • SHABANI, M.A., IRANNAJAD, M., AZADMEHR, A.R., 2012. Investigation on leaching of malachite by citric acid. Int. J. Min. Met. Mater. 19, 782-786.
  • YAO, J., YIN, W., GONG, E., 2016. Depressing effect of fine hydrophilic particles on magnesite reverse flotation. Int. J. Miner. Process.149, 84-93.
  • ZHANG, H., LIU, W.G., HAN, C., HAO, H.Q., 2018. Effects of monohydric alcohols on the flotation of magnesite and dolomite by sodium oleate. J. Mol. Liq. 249, 1060–1067.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-19007dbd-0b87-4030-9a5c-88ca0cf57e7c
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