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Copper recovery from chalcopyrite concentrate acid leach solutions by Acorga M5397

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Chalcopyrite concentrate from Hajar Mine, Morocco, was leached with nitro-fluosilicic acid leach solution. The pregnant leach solution obtained contained 19.3 g/dm3 Cu, 18.1 g/dm3 Fe, 4.5 g/dm3 Zn and 0.03 g/dm3 Pb. Copper recovery from this pregnant leach liquor was performed by solvent extrac-tion using Acorga M5397 diluted in Escaid 110. McCabe–Thiele distribution isotherms showed that at pH 1.7 complete and selective copper extraction can be achieved with φo/φa =1.5/1 in 3 stages of extraction. Stripping of the loaded copper by treating the organic phases by a fresh sulphuric acid solution was easily realized.
Rocznik
Strony
329--339
Opis fizyczny
Bibliogr. 19 poz., wykr.
Twórcy
autor
  • Laboratoire Géoressources, Unité Associée au CNRST (URAC 42), Faculté des Sciences et Techniques Guéliz, B. P. 549, 40000 Marrakech, Maroc
autor
  • LEM UMR 7569, Nancy Université, ENSG-INPL-CNRS, 15 avenue du Charmois, B.P. 54 501, Vandoeuvre-Les-Nancy, France
autor
  • ENSG-INPL, Rue du Doyen Marcel Roubault, B. P. 40, 54501 Vandoeuvre, France
Bibliografia
  • 1. ARBITER N., FLETCHER A.W., 1994, Copper hydrometallurgy-evolution and milstone, Mining Engi-neering. 118–124.
  • 2. BLAZY P. JDID E.A., 2002, Hydrométallurgie du cuivre. Techniques de l’Ingénieur, M2242, 1–10.
  • 3. DALTON R. F., DIAZ G., PRICE R. ZUKEL A.D., 1991, The cuprex metal extraction process: recover-ing copper from sulfide ores. JOM, 51–56.
  • 4. DREISINGER D., 2004, New developments in hydrometallurgical treatment of copper concentrates. Engineering and Mining Journal, 205, 32–35.
  • 5. EL AMARI K.. JDID E.A., BLAZY P., BOUHAFID A., EL MERAY M., AKALAY I., 2000, Acid and Oxidizing Leaching of Chalcopyrite Concentrate by Ferric Sulphate and Fluorosilicic-Nitric Media. Separation Science and Technology, 35 (13), 2143–2158.
  • 6. EL AMARI K., JDID E.A., BLAZY P., 2006, Copper solvent extraction from chalcopyrite concentrate acid leach solutions by Lix 984. Journal of Mining and Metallurgy, 42 B (1), 1–11.
  • 7. HABASHI F., 2007, Copper metallurgy at the crossroads. Journal of Mining and Metallurgy, 43 B, 1–19.
  • 8. HELLE S., JEREZ O., KELM U., PINCHEIRA M., VARELA B., 2010, The influence of rock character-istics on acid leach extraction and re-extraction of Cu-oxide and sulphide minerals. Minerals engi-neering, 23, 45–50.
  • 9. HENKEL CORPORATION, Private communication.
  • 10. INTERNATIONAL COPPER STUDY GROUP, 2010, The World Copper Factbook, 1–54.
  • 11. KITOBO W., GAYDARDZHIEV S., FRENAY J., BASTIN D., IIUNGA N., 2010, Separation of copper and zinc by solvent extraction during reprocessing of flotation tailings. Separation science and Tech-nology, 45, 535–540.
  • 12. KOLEINI S.M.; JAVAD; AGHAZADEH VALEH, SANDSTRÖM A., 2011, Acidic Sulphate Leaching of Chalcopyrite Concentrates in Presence of Pyrite. Minerals Engineering, 24, 381–386.
  • 13. PADILLA R., RODRIGUEZ G., RUIZ M.C., 2010, Copper and arsenic dissolution from chalcopyrite-enargite concentrate by sulfidation and pressure leaching in H2SO4-O2. Hydrometallurgy, 100, 152–156.
  • 14. PANIGRAHI S., PARHI P.K. NATHSARMA K.C., 2009, A study on extraction of copper using LIX 84-I and LIX 622N, Separation and Purification Technology. 70(1), 58–62.
  • 15. PRADHAM N., NATHSARMA K.C., SRINIVASA R., 2008, Heap bioleaching of chalcopyrite: A re-view. Minerals Engineering 21 (5), 355–365.
  • 16. SRINIVASA RAO K., DEVI N.B., REDDY B.R., 2000, Solvent extraction of copper from sulphate medium using MOC 45 as extractant. Hydrometallurgy, 57, 269–275.
  • 17. SUTTILL R. K., 1989, Solvent extraction: a key in maintaining copper production. EEMJ, 24–27.
  • 18. WATLING H.R., 2006, The bioleaching of sulphide minerals with emphasis on copper sulphides – A review. Hydrometallurgy, 84, 81–108.
  • 19. YOSHINARI B., KATSUTOSHI I., 1988, Solvent extraction equilibria of copper (II) by carboxylic acids with high acid dissociation constants. Hydrometallurgy, 21, 203–212.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-188c5c13-a114-4a62-9e8c-9d404b46be20
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