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Emulsion matrix sensitization is typically performed by chemical reduction of the density using different sensitization agents. Mixing of the components takes place directly inside the loading hose, which is equipped with static mixing devices. Precise dosing of the components, due to the multi-ingredient nature of the mixture, has a significant impact on the detonation and operational parameters of the end product. However, the operation and maintenance of the mixing-charging units in underground mines is very difficult due to the local conditions. As a consequence, different values for the detonation parameters may be expected when charging the same explosive into blastholes using two different charging units. The present article presents the results of laboratory testing of the influence of the sensitizing agent content on the density of a bulk emulsion explosive. Analysis confirmed that increasing the concentration of the sensitizing agent by 30% and 50% led to density reductions by 4% and 7%, respectively. In turn, reducing the sensitizer content by the same percentages resulted in an increase in the final density by 7% and 8%, respectively.
Słowa kluczowe
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Tom
Strony
429--447
Opis fizyczny
Bibliogr. 18 poz., rys., tab.
Twórcy
autor
- NITROERG S.A., 1 Nobla square, 43-150 Bieruń, Poland
autor
- KGHM Cuprum Ltd. Research & Development Centre, 2-8 Sikorskiego Street, 53-659 Wrocław, Poland
Bibliografia
- [1] Egly, R.S.; Neckar, A.E. Ammonium Nitrate-containing Emulsion Sensitizers for Blasting Agents. Patent US 3161551, 1964.
- [2] Bluhm, H.F. Ammonium Nitrate Emulsion Blasting Agent and Method of Preparing Same. Patent US 3447978, 1969.
- [3] Bulk Emulsion Explosives Emerging as Replacement of Packaged Counterparts in Underground Mining Applications. Future Market Insights, Press release, 2020.
- [4] Sifferlinger, N.A.; Hartlieb, P.; Moser, P. The Importance of Research on Alternative and Hybrid Rock Extraction Methods. Berg Huettenmaenn Monatsh. 2017, 162(2): 58-66.
- [5] Pickering, R.G.B.; Young, C. Controlled Foam Injection: A New and Innovative non-Explosive Rockbreaking Technology. J. South. Afr. Inst. Min. Metall. 2017, 117(3): 237-243.
- [6] Da Silva, G.; Dlugogorski, B.; Kennedy, E. Water‐in‐Oil Emulsion Foaming by Thiourea Nitrosation: Reaction and Mass Transfer. AIChE J. 2006, 52(4): 1558- 1565.
- [7] Agrawal, H.; Mishra, A.K. A Study on Influence of Density and Viscosity of Emulsion Explosive on Its Detonation Velocity. Model. Meas. Control. C 2017, 78(3): 316-336.
- [8] Lee, J.; Persson, P.A. Detonation Behavior of Emulsion Explosives. Propellants Explos. Pyrotech. 1990, 15(5): 208-216.
- [9] Sitkiewicz-Wołodko, R.; Maranda, A. Analysis of Selected Parameters of Saletrols and Emulsion Explosives. CHEMIK 2016, 70(1): 11-18.
- [10] Pradhan, M. Sleep Time: Its Consequences on Performance of Bulk Emulsion Explosive. J. Sci. Ind. Res. 2010, 69(2): 125-128.
- [11] Mertuszka, P.; Kramarczyk, B. The Impact of Time on the Detonation Capacity of Bulk Emulsion Explosives Based on Emulinit 8L. Propellants Explos. Pyrotech. 2018, 43(8): 799-804.
- [12] Mertuszka, P.; Fuławka, K.; Pytlik, M.; Wincenciak, J.; Wawryszewicz, A. The Influence of Time on the Density and Detonation Velocity of Bulk Emulsion Explosives – A Case Study from Polish Copper Mines. Cent. Eur. J. Energ. Mater. 2019, 16(2): 245-258.
- [13] Mahadevan, E.G. Emulsion Explosives. In: Ammonium Nitrate Explosives for Civil Applications: Slurries, Emulsions and Ammonium Nitrate Fuel Oils. Wiley, Weinheim, 2013; ISBN 978-3-527-33028-7.
- [14] Kabamba, K.J. Development of Two-Component Gassing System to Sensitize Explosive Emulsions. MEng. disertation, Cape Peninsula University of Technology, 2019.
- [15] Field, J.E. Hot Spot Ignition Mechanism for Explosives. Acc. Chem. Res. 1992, 25: 489-496.
- [16] Negovanović, M.; Kričak, L.; Milanović, S.; Đokić, N.; Simić, N. Ammonium Nitrate Explosion Hazards. Undergr. Min. Eng. 2015, 27: 49-63.
- [17] Tao, T.J.; Zhang, J.H.; Chi, E.A.; Zhao, M.S.; Kang, Q. Study of Influence of Sensitization Process on Quality of Mixed Emulsion Explosive. Adv. Mat. Res. 2014, 1033-1034: 1305-1308.
- [18] Mishra, A.K.; Rout, M.; Singh, D.R.; Pada Jana, S. Influence of Gassing Agent and Density on Detonation Velocity of Bulk Emulsion Explosives. Geotech. Geol. Eng. 2018, 36(1): 89-94.
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Bibliografia
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bwmeta1.element.baztech-188224db-645c-4b6f-8e51-5fe5136e3d57