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Tytuł artykułu

Recognition of Environmentally Important Ions

Identyfikatory
Warianty tytułu
PL
Rozpoznawanie jonów o znaczeniu środowiskowym
Języki publikacji
EN
Abstrakty
EN
The synthesis and binding properties of N,N’-bis(2-naphthyl)pyridine-2,6-dicarboxyamide are described. The ion binding ability in solution has been tested by UV-Vis spectrophotometry and liquid-liquid extraction of metal picrates from water into dichloromethane. Among studies ions spectral changes of ligand solution in acetonitrile were observed in the presence of Pb2+, Cu2+, and F- ions. The stability constants (logβ) and the stoichiometry of formed complexes were determined.
PL
Artykuł przedstawia syntezę i właściwości kompleksujące receptora jonów, będącego amidową pochodną kwasu pirydyno-2,6-dikarboksylowego. Badania prowadzone były przy użyciu spektrofotometrii UV-Vis oraz metod ekstrakcyjnych.
Czasopismo
Rocznik
Tom
Opis fizyczny
Bibliogr. 17 poz., rys., wykr., pełen tekst na CD
Twórcy
autor
  • Gdansk University of Technology, Faculty of Chemistry
  • Gdansk University of Technology, Faculty of Chemistry
  • Université de Strasbourg, IPHC
autor
  • Université de Strasbourg, IPHC
  • Gdansk University of Technology, Faculty of Chemistry
Bibliografia
  • [1] Nordberg G.: Handbook on the Toxicology of Metals, Academic Press, New York, 2007, p. 529–600.
  • [2] Pomećko R., Asfari Z., Hubscher-Bruder V., Arnaud-Neu F., Bocheńska M.: Anion recognition by phosphonium calix[n]arenes: synthesis and physico-chemical studies, “Supramol. Chem.”, 22 (5), 2010 p. 275–288.
  • [3] Martinez-Manez R., Sancenon F.: Fluorogenic and chromogenic chemosensors and reagents for anions, “Chem. Rev.”, 103 (11), 2003, p. 4419–4476.
  • [4] Gloe K., Stephan H., Grotjahn M.: Where is anion extraction going?, “Chem. Eng. Technol.”, 26 (11), 2003, p. 1107–1117.
  • [5] Kang S.O., Begum R.A., Bowman-James K., Amide based ligands for anion coordination, “Angew. Chem.Int. Ed.”, 45 (47), 2006, p. 7882–7894.
  • [6] Renaud F., Piguet C., Brenardinelli G., Bünzli J.C.G, Hopfgartner G.: In search for monomolecular helical lanthanide building blocks with predetermined properties: triple-stranded helical complexes with N,N,N’,N’-tetraethylpyridine-2,6-dicarboxyamide, “Chem. Eur. J.”, 3 (10), 1997, p. 1646–1659.
  • [7] Picot A., Malvolti F., Guennic B.L., Baldeck P.L., Williams J.A.G., Andraud C., Maury O.: Two-photon antenna effect included in octupolar europium complexes, “Inorg. Chem.”, 46 (7), 2007, p. 2659–2665.
  • [8] Marlin D.S., Mascharak P.K, Coordination of carboxamido nitrogen to tervalent iron: insight into a new chapter of iron chemistry, “Chem. Soc. Rev.”, 29, 2011, p. 69–74.
  • [9] Huang D., Makhlynets O.V., Tan L.L., Lee S.C., Rybak-Akimova E.V., Holm R.H.: Fast carbon dioxide fixation by 2,6-pyridenedicarboxyamidatonickel(II)- hydroxide complexes: influence of changes in reactive site environment on reaction rates, “Inorg. Chem.”, 50, 2011, p. 10070–10081.
  • [10] Dutta S., Pal S., Bhattacharya P.K.: Synthesis and characterization of some Ru(II)complexes of 2-carbamoylpyridine derivatives, “Polyhedron”, 18, 1999, p. 2157–2162.
  • [11] Leung W.-H., Ma J.-X., Yam V.W.-W., Che C.-M.,Poon C.-K., Syntheses, electrochemistry and reactivities of pyridine amide complexes of chrmomium(III) and manganese(III), “J. Chem. Soc.”, Dalton Trans., 4, 1991, p. 1071–1076.
  • [12] Wagner-Wysiecka E., Chojnacki J., Chromogenic amides of pyridine-2,6-dicarboxylic acid as anion receptors, “Supramol. Chem.”, 24 (9), 2012, p. 684–695.
  • [13] Yamnitz, C. R., Negin, S., Carasel, I.A., Winterb, R.K., Gokel, G.W.: Dianilides of dipicolinic acid function as synthetic chloride channels, “Chem. Commun.” 46 (16), 2010, p. 2838–2840.
  • [14] Methodes d’analyses complexométriques par les Titriplex, 3rd ed, E. Merck AG, Darmstadt, 1992, 37, 51.
  • [15] Gampp H., Maeder M., Meyer C.J., Zueberbuhler A.D.: Calculation of Equilibrium Constants from Multiwavelenght Spectroscopic Data- I, “Mathematical Consideration”, Talanta 32, 1985, p. 95–101.
  • [16] Pedersen C.J.: Ionic complexes of macrocyclic polyethers, “Fed. Proc. Fed. Amer. Soc. Expl. Biol.”, 27, 1968, 1305.
  • [17] Hiratani K., Taguchi K.: 2,6-bis[N-(8-quinolyl)carbamoyl]pyridine as a highly selective extractant for Cu(II), “Bull. Chem. Soc. Jpn.”, 63, 1990, p. 3331–3333.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-17d858e0-554c-4606-b0ee-3d4715201e54
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