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Thermal and Flame Retardant Properties of Shaped Polypropylene Fibers Containing Modified-Thai Bentonite

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Tetraphenyl phosphonium-modified organoclay (TPP-Mt) was prepared by modifying montmorillonite-rich Thai bentonite via ion exchange. TGA results revealed that TPP-Mt possessed high thermal stability, where degradation occurred at a temperature range of 418-576°C. The obtained TPP-Mt/PP nanocomposites exhibited degradation at higher temperatures than PP (410-420°C vs. 403°C). Fibers of different cross-sectional shapes (circular, circular hollow, and cross) containing 1, 2 and 3%wt TPP-Mt were prepared and characterized. Nonwovens of 3%wt TPPMt/PP fibers were fabricated for flame retardant test. From results, nonwovens of TPP-Mt/PP fibers exhibited self-extinguishing characteristic and the areas of burning were less than that of PP nonwoven (14.5-31.6% vs. 95.6%). Nonwovens of cross-shaped fibers showed the best flame retardant property, followed by those of circular hollow and circular fibers. The flame retardant properties observed in nonwovens were explained due to the inter-fiber spaces between cross-shaped fibers and center hole in circular hollow fibers, which could trap initiating radicals inside, thus reducing flame propagation. In addition, large surface area in cross-shaped fibers could help in increasing the flame retardant effectiveness due to more exposure of TPP-Mt particles to the flame. Knowledge obtained in this study offered an approach to produce flame retardant nonwovens via a combination of modified organolcay and fiber shape.
Rocznik
Strony
13--19
Opis fizyczny
Bibliogr. 25 poz.
Twórcy
autor
  • National Metal and Materials Technology Center, 114 Pathoyothin Klong 1, Klong Luang, Pathumthani 12120, Thailand Phone 662 5646500 Fax 662 5646446
  • Department of Engineering, Ratchamangkala University of Technology, 39 Moo 1, Rangsit-Nakhonnayok Rd., Thanyaburi, Pathumthani 12110, Thailand
  • National Metal and Materials Technology Center, 114 Pathoyothin Klong 1, Klong Luang, Pathumthani 12120, Thailand Phone 662 5646500 Fax 662 5646446
  • National Metal and Materials Technology Center, 114 Pathoyothin Klong 1, Klong Luang, Pathumthani 12120, Thailand Phone 662 5646500 Fax 662 5646446
autor
  • National Metal and Materials Technology Center, 114 Pathoyothin Klong 1, Klong Luang, Pathumthani 12120, Thailand Phone 662 5646500 Fax 662 5646446
Bibliografia
  • [1] Kotal, M. & Bhowmick, A.K. (2015). Polymer nanocomposites from modified clays: Recent advances and challenges. Progress in Polymer Science, 51, 127-187.
  • [2] Shah, K.J., Shukla, A.D., Shah, D.O. & Imae T. (2016). Effect of organic modifiers on dispersion of organoclay in polymer nanocomposites to improve mechanical properties. Polymer, 97, 525-532.
  • [3] Garcia-Lopez, D., Fernandez, J.F., Merino, J.C. & Pastor, J.M. (2013). Influence of organic modifier characteristics on the mechanical properties of polyamide6/organo-sepiolite nanocomposites. Composites: Part B, 45, 459-465.
  • [4] Feng, J., Hao, J., Du, J. & Yang, R. (2012). Effects of organoclay modifiers on the flammability, thermal and mechanical properties of polycarbonate nanocomposites filled with a phosphate and organoclays. Polymer Degradation and Stability, 97, 108-117.
  • [5] Leszczynska, A., Njuguna, J., Pielichowski, K. & Banerjee, J.R. (2007). Polymer/montmorillonite nanocomposites with improved thermal properties II. Thermal stability of montmorillonite nanocomposites based on different polymeric matrixes. Thermochimica, 454, 1-22.
  • [6] Calderon, J.U., Lennox, B. & Kamal, M.R. (2008). Thermally stable phosphonium-montmorillonite organoclay. Applied Clay Science, 40, 90-98.
  • [7] Abdallah, W. & Yilmazer, U. (2011). Novel thermally stable organo-montmorillonites from phosphonium and imidazolium surfactants. Thermochimica Acta, 525, 129-140.
  • [8] Mittal, V. (2012). Modification of montmorillonites with thermally stable phosphonium cations and comparison with alkylammonium montmorillonites. Applied Clay Science, 56:103-109.
  • [9] Patel, H. A., Somani, R.S., Bajaj, H. C. & Jasra, R. V. (2007). Preparation and characterization of phosphonium montmorillonite with enhanced thermal stability. Applied Clay Science, 35, 194-200.
  • [10] Xie, W., Xie, R., Pan, W.P., Hunter, D., Koene, B., Tan, L.S. & Vaia, R. (2002). Thermal stability of quarternary phosphonium modified montmorillonites. Chemistry of Materials, 14, 4837-4845.
  • [11] Du, B., Guo, Z., Song, P., Liu, H., Fang, Z. & Wu, Y. (2009). Flame retardant mechanism of organo-bentonite in polypropylene. Applied Clay Science, 45, 178-184.
  • [12] Yourdkhani, M., Mousavand, T., Chapleau, N. & Hubert, P. (2013). Thermal, oxygen barrier and mechanical properties of polylactide-organoclay nanocomposites. Composites Science and Technology, 82,47-53.
  • [13] Hwang, S., Liu, S., Hsu, P.P, Yeh, J., Yang, J., Chang, K. & Chu, S. (2011). Effect of organoclay and preparation methods on the mechanical/thermal properties of microcellular injection molded polyamide 6-clay nanocomposites. International Communications in Heat and Mass Transfer, 38, 1219-1225.
  • [14] Laoutid, F., Persenaire, O., Bonnaud, L. & Dubois, P. (2013). Flame retardant polypropylene through the joint action of sepiolite and polyamide 6. Polymer Degradation and Stability. 98, 1972-1980.
  • [15] Onder, E., Sarier, N. & Ersoy, M. S. (2012). The manufacturing of polyamide-and polypropylene-organoclay nanocomposite filaments and their suitability for textile applications. Thermochimica Acta, 543, 37-58.
  • [16] Bueno, M. A., Aneja, A. P. & Renner, M. (2004). Influence of the shape of fiber cross section on fabric surface characteristics. Journal of Materials Science, 39, 557-564.
  • [17] Karaca, E., Ozcelik, F. (2007). Influence of the crosssectional shape on the structure and properties of polyester fibers. Journal of Applied Polymer Science, 103, 2615-2621.
  • [18] Oh, T. H. (2006). Studies on melt spining process of hollow polyethylene terephthalate fibers. Polymer Engineering and Science, 46, 609-616.
  • [19] Jung, I., Kim, S. & Oh, T. H. (2010). Effects of spinning conditions on shape changes of trilobal-shaped fibers. Textile Research Journal, 80, 12-18.
  • [20] Zhou, J., Li, J., Yu, W., Lin, X. & Zhou, C. (2010). Studies on the melt spinning process of noncircular fiber by numerical and experimental methods. Polymer Engineering and Science, 50, 1935-1944.
  • [21] Takarada, W., Ito, H., Kikutani, T. & Okui, N. (2001). Studies on high-speed melt spinning of noncircular cross-section fibers II. On-line measurement of the spin line, including change in cross-sectional shape. Journal of Applied Polymer Science, 80, 1582-1588.
  • [22] Yao, D. (2006). Fundamental study of the driving mechanisms for cross-section shape change in highly noncircular fiber spinning. The Fiber Society, Fall Annual Meeting and Technical Conference, 55-56.
  • [23] Thuc, C.N.H., Grillet, A.C., Reinert, L. & Ohashi, F. (2010). Separation and purification of montmorillonite and polyethylene oxide modified montmorillonite from Vietnamese bentonites. Applied Clay Science, 49, 229-238.
  • [24] Prahsarn, C., Roungpaisan, N., Suwannamek, N., Klinsukhon, W., Hayashi, H., Kawasaki, K. & Ebina, T. (2014). Influence of molecular structure of quarternary phosphonium salts on Thai bentonite intercalation. Clays and Clay Minerals, 62(1), 13-19.
  • [25] Zhang, S. & Horrocks, A.R. (2003). A review of flame retardant polypropylene fibres. Progress in Polymer Science, 28, 1517-1538.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-172272c2-275a-4324-b137-e230dbb1c258
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