The impact of phase state of guest histidine on properties and practical applications of nanohybrids on InSe and GaSe basis

• Autorzy: Ivashchyshyn F. O. , Grygorchak I. I. , Balaban O. V. , Seredyuk B. O.

Identyfikatory

DOI

10.1515/msp-2017-0019

• Języki publikacji: EN

Abstrakty

EN

A new technological approach to the synthesis of multilayer nanostructures which allows their use in high-performance storage of electrical energy at the nanoscale level is discussed in this paper. In particular, the effect of co-intercalation of histidine (his), water and a solution of KOH into layered semiconductors of GaSe and InSe on the charge accumulation are studied. Based on the data of the cyclic current-voltage characteristics (CVC) a power storage mechanism (capacitive/pseudocapacitive) in each of these structures is described. This mechanism is in a good accord with the results of galvanostatic studies. The simulation of the parameters of the impedance equivalent circuit has been carried out, proving the possibility of using the described structures for nanoelectronics and nanoenergy devices. The observed values of tangent of electrical losses tgδ (<1) in coherence with a high dielectric constant ε are promising for the creation of quantum batteries and capacitors.

Słowa kluczowe

EN

histidine intercalation; impedance spectroscopy; negative capacitance; quantum batteries

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2017
• Tom: Vol. 35, No. 1
• Strony: 239--245
• Opis fizyczny: Bibliogr. 13 poz., rys., tab.

Twórcy

autor

Ivashchyshyn F. O.

• Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine

autor

Grygorchak I. I.

• Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine

autor

Balaban O. V.

• Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine

autor

Seredyuk B. O.

• National Academy of Land Forces, 32 Geroiv Majdanu St., Lviv 79012, Ukraine

Bibliografia

• [1] CHOY J.H., KWONS.J., PARK G.S., Science, 280 (1998), 1589.
• [2] CHOY J.H., KWAK S.Y., PARK J.S., JEONG Y.J., J. Am. Chem. Soc., 121 (1999), 1399.
• [3] GRYGORCHAK I.I., SEREDYUK B.O., TOVSTYUK K.D., BAKHMATYUK B.P., High-Frequency Capacitor Nanostructure Formation by Intercalation, in: JULIEN C., PEREIRA-RAMOS J.P., MOMCHILOV A. (Eds.), New Trends in Intercalation Compounds for Energy Storage. Nato Science Series II, Springer, Netherlands, 2002, p. 543.
• [4] VOITOVYCH S.A., GRYGORCHAK I.I., AKSIMENTYEVA O.I., Mol. Cryst. Liq. Cryst., 497 (2008), 55.
• [5] IVASHCHYSHYN F.O., GRYGORCHAK I.I., Phys. Status Solidi A, 52 (2010), 1891.
• [6] IVASHCHYSHYN F.O., GRYGORCHAK I.I., MIKITYUK Z.M., FECHAN A.V., KULIK Y.O., Russ. Phys. J.+, 53 (2010), 155.
• [7] KUHN A., CHEVY A., CHEVALIER R., Phys. Status Solidi A, 31 (1975), 469.
• [8] STOJNOV Z.B., GRAFOV B.M., SAVVOVA-STOJNOVA B.S., YELKIN V.V., Electrochemical impedance, Nauka Publishers, Moscow, 1991.
• [9] MACDONALD J.R., Impedance Spectroscopy, J. Wiley & Sons, New York, 1987.
• [10] IVASHCHYSHYN F.O., GRYGORCHAK I.I., KLAPCHUK M.I., SPQEO, 18 (2015), 362.
• [11] BISHCHANIUK T.M., BALABAN O.V., SHVETS R.Y., GRYGORCHAK I.I., FECHAN A.V., LUKIYANETS B.A., IVASHCHYSHYN F.O., Mol. Cryst. Liq. Cryst., 589 (2014), 132.
• [12] GRYGORCHAK I.I., LUKIYANETS B.A., BALABAN O.V., BISHCHANIUK T.M., SHVETS R.Y., Mat. Sci. Semicon. Proc., 26 (2014), 690.
• [13] BISQUERT J., RANDRIAMAHAZAKA H., GARCIABELMONTE G., Electrochim. Acta, 51 (2005), 627.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).