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Chemical transformation of leather waste into chromium free biomass has been investigated. The conversion was performed by extracting the toxic metal. The effects of several influential factors on the process have been studied using design of experiments. Optimal conditions of chromium extraction have been determined. The collagen fiber of the biomass obtained has been analyzed by the Fourier transform infrared spectroscopy (FTIR). The chemical mechanism allowing this transformation has been suggested. The infrared analysis showed that the collagen fiber of the obtained biomass presents chemical composition similar to that of native collagen fiber of non-chromed leather. These results demonstrated the almost complete extraction of chromium from leather waste and the conversion of these latter into an environmentally harmless biomass.
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Rocznik
Tom
Strony
179--192
Opis fizyczny
Bibliogr. 23 poz., tab., rys.
Twórcy
autor
- Research Unit of Materials – Processes and Environment (UR-MPE), Laboratory of Matter Chemistry and Environment, Faculty of Engineer Sciences, M’hamed Bougara University, Avenue of Independence, 35000 Boumerdes, Algeria.
autor
- Research Unit of Materials – Processes and Environment (UR-MPE), Laboratory of Matter Chemistry and Environment, Faculty of Engineer Sciences, M’hamed Bougara University, Avenue of Independence, 35000 Boumerdes, Algeria.
autor
- Research Unit of Materials – Processes and Environment (UR-MPE), Laboratory of Matter Chemistry and Environment, Faculty of Engineer Sciences, M’hamed Bougara University, Avenue of Independence, 35000 Boumerdes, Algeria.
autor
- Research Unit of Materials – Processes and Environment (UR-MPE), Laboratory of Matter Chemistry and Environment, Faculty of Engineer Sciences, M’hamed Bougara University, Avenue of Independence, 35000 Boumerdes, Algeria.
Bibliografia
- [1] EL BOUSHY A.R., VAN DER POEL A.F.B., KOENE J.I.A., DIELEMAN S.H., Tanning waste by-product from cattle hides, its suitability as a feedstuff, Biores. Technol., 1991, 35, 321.
- [2] ERDEM M., Chromium recovery from chrome shavings generated in tanning process, J. Hazard. Ma-ter., 2006, 129 (1–3), 143.
- [3] SARAVANABHAVAN S., THANIKAIVELAN P., RAGHAVA R. J., UNNINAIR B., RAMASAM I.T., Reversing the conventional leather processing sequence for cleaner leather production, Environ. Sci. Technol., 2006, 40, 1069.
- [4] BIENKIEWICZ E., Physical chemistry of leather making, Krieger Publishing, Malabar, Fl., 1983.
- [5] THORSTENSEN T.C., Practical Leather Technology, Krieger Publishing, Malabar, Fl., 1993.
- [6] SHUTTLEWORTH S.G., The Chemistry and Technology of Leather, Krieger Publishing, Malabar, Fl., 1978.
- [7] NAUMCZYK J., KUCHARSKA M., Tannery wastewater treatment by anodic electrooxidation coupled with electro-Fenton process, Environ. Prot. Eng., 2011, 37 (3), 47.
- [8] KOSIŃSKA K., MIŚKIEWICZ T., Precipitation of heavy metals from industrial wastewater by desulfovibrio desulfurican, Environ. Prot. Eng., 2012, 38 (2), 51.
- [9] TAHIRI S., BOUHRIA M., ALBIZANE A., MESSAOUDI A., AZZI M., ALAMI S.Y., MABROUR J., Extraction of proteins from chrome shavings with sodium hydroxide and reuse of chromium in the tanning process, J. Am. Leather Chem. Assoc., 2004, 99 (1), 16.
- [10] TAYLOR M.M., DIEFENDORF E.J., THOMPSON C.J., BROWN E.M., MARMER W.N., CABEZA L.F., Extraction of value added byproducts from the treatment of chromium containing collagenous leather industry waste, J. Soc. Leather Technol. Chem., 1997, 81 (1), 5.
- [11] RAO J.R., THANIKAIVELAN P., SREERAM K.J., NAIR B.U., Green route for the utilisation of chrome shavings (chromium-containing solid waste) in tanning industry, Environ. Sci. Technol., 2002, 36, 1372.
- [12] MU C.D., LIN W., ZHANG M.R., ZHU Q., Towards zero discharge of chromium-containing leather waste trough improved alkali hydrolysis, Waste Manage., 2003, 23, 835.
- [13] TAHIRI S., AZZI M., ALBIZANE A., MESSAOUDI A., BOUHRIA M., ALAMI Y.S., MOURID A., MABROUR J., Study of quality of a pigment prepared by complexation of chromates recovered from treated chrome shavings and tanned splits, J. Am. Leather Chem. Assoc., 2001, 96, 426.
- [14] CABEZA L.F., TAYLOR M.M., BROWN E.M., MARMER W.N., Isolation of protein products from chrome-containing leather waste using two consecutive enzymes and purification of final chromium product pilot plant studies, J. Soc. Leather Technol. Chem., 1999, 83 (1), 14.
- [15] WANG K.S., SUN C. J., LIU C., Effect of the type of sintering atmosphere on the chromium leachability of thermal-treated municipal solid waste incinerator fly ash, Waste Manage., 2001, 21, 85.
- [16] KIRK D.W., CHAN C.C.Y., MARSH H., Chromium behaviour during thermal treatment of MSW fly ash, J. Hazard. Mater., 2002, 90 (1), 39.
- [17] KOWALSKI Z., Treatment of chromic tannery wastes, J. Hazard. Mater., 1994, 37 (2), 137-.
- [18] US Department of Health and Human Services, Toxicological Profile for Chromium, Washington, DC., 1991.
- [19] ALVARES P., BLANCO C., GRANDA M., The adsorption of chromium(VI) from industrial wastewater by acid and base-activated lignocellulosic residues, J. Hazard. Mater., 2007, 144 (1–2), 400.
- [20] GIKAS P., ROMANOS P., Effect of trivalent (Cr(III)) and hexavalent (Cr(VI)) chromium on the growth of activated sludge, J. Hazard. Mater., 2006, 133, 212.
- [21] BENOIST D., Plan d’expériences, Lavoisier, Paris, 1994.
- [22] GOUPY J., Les plans d’expériences, Revue Modulad, 2006, 34.
- [23] MALEK A., HACHEMI H., DIDIER V., New approach of depollution of solid chromium leather waste by the use of organic chelates, J. Hazard. Mater., 2009, 170 (1), 156.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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