PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Effects of Ca2+ and SO42- ions on fluorite flotation

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The effects of Ca2+ and SO42- on the flotation behaviour of fluorite with sodium oleate as a collector and the underlying mechanism by which these effects were investigated via micro-flotation experiments, solution chemistry calculations, and X-ray photoelectron spectroscopy. The results indicated that the addition of SO42- and Ca2+ inhibited fluorite flotation and the inhibition effect was increased by the addition of pH. This was mainly due to the increase of the sulphate-containing components in the solution and the adsorption of SO42- on the surface of fluorite. With the increase of pH, the alkalinity of the solution increases, OH- and more SO42- are further adsorbed on the fluorite surface, thereby reducing the recovery of fluorite flotation.
Słowa kluczowe
Rocznik
Strony
95--104
Opis fizyczny
Bibliogr. 44 poz., rys., tab., wykr.
Twórcy
autor
  • School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
Bibliografia
  • ALROUDHAN, A., VINOGRADOV, J. and JACKSON, M.D., 2016. Zeta potential of intact natural limestone: Impact of potential-determining ions Ca, Mg and SO4. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 493, 83-98.
  • AZIMI, G., PAPANGELAKIS, V.G. and DUTRIZAC, J.E., 2008. Development of an MSE-based chemical model for the solubility of calcium sulphate in mixed chloride–sulphate solutions. Fluid Phase Equilibria. 266, 172-186.
  • CHEN, W., FENG, Q., ZHANG, G., LIU, D. and LI, L., 2018. Selective flotation of scheelite from calcite using calcium lignosulphonate as depressant. Minerals Engineering. 119, 73-75.
  • CHEN, W., FENG, Q., ZHANG, G., YANG, Q. and ZHANG, C., 2017. The effect of sodium alginate on the flotation separation of scheelite from calcite and fluorite. Minerals Engineering. 113, 1-7.
  • CHEN, W., FENG, Q., ZHANG, G., YANG, Q., ZHANG, C. and XU, F., 2017. The flotation separation of scheelite from calcite and fluorite using dextran sulfate sodium as depressant. International Journal of Mineral Processing. 169, 53- 59.
  • CHEN, Z., REN, Z., GAO, H., ZHENG, R., JIN, Y. and NIU, C., 2019. Flotation studies of fluorite and barite with sodium petroleum sulfonate and sodium hexametaphosphate. Journal of Materials Research and Technology. 8, 1267-1273.
  • CHENNAKESAVULU, K., RAJU, G.B., PRABHAKAR, S., NAIR, C.M. and MURTHY, K.V.G.K., 2008. Adsorption of oleate species at the fluorite-aqueous solution interface. Int. J. Miner. Process. 90, 101–104.
  • CUI, Y., JIAO, F., WEI, Q., WANG, X. and DONG, L., 2020. Flotation separation of fluorite from calcite using sulfonated lignite as depressant. Separation and Purification Technology. 242,
  • ELIZONDO-ÁLVAREZ, M.A., FLORES-ÁLVAREZ, J.M., DáVILA-PULIDO, G.I. and URIBE-SALAS, A., 2017. Interaction mechanism between galena and calcium and sulfate ions. Minerals Engineering. 111, 116-123.
  • FA, K., NGUYEN, A.V. and MILLER, J.D., 2006. Interaction of calcium dioleate collector colloids with calcite and fluorite surfaces as revealed by AFM force measurements and molecular dynamics simulation. International Journal of Mineral Processing. 81, 166-177.
  • FENG, B., LUO, X., WANG, J. and WANG, P., 2015. The flotation separation of scheelite from calcite using acidified sodium silicate as depressant. Minerals Engineering. 80, 45-49.
  • FENG, Q., WEN, S., ZHAO, W. and CHEN, Y., 2018. Effect of calcium ions on adsorption of sodium oleate onto cassiterite and quartz surfaces and implications for their flotation separation. Separation and Purification Technology. 200, 300-306.
  • FILIPPOV, L.O., FILIPPOVA, I.V., LAFHAJ, Z. and FORNASIERO, D., 2019. The role of a fatty alcohol in improving calcium minerals flotation with oleate. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 560, 410-417.
  • FILIPPOVA, I.V., FILIPPOV, L.O., DUVERGER, A. and SEVEROV, V.V., 2014. Synergetic effect of a mixture of anionic and nonionic reagents: Ca mineral contrast separation by flotation at neutral pH. Minerals Engineering. 66-68, 135-144.
  • FILIPPOVA, I.V., FILIPPOV, L.O., LAFHAJ, Z., BARRES, O. and FORNASIERO, D., 2018. Effect of calcium minerals reactivity on fatty acids adsorption and flotation. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 545, 157-166.
  • FLORES-ÁLVAREZ, J.M., ELIZONDO-ÁLVAREZ, M.A., DáVILA-PULIDO, G.I., GUERRERO-FLORES, A.D. and URIBE-SALAS, A., 2017. Electrochemical behavior of galena in the presence of calcium and sulfate ions. Minerals Engineering. 111, 158-166.
  • FOUCAUD, Y., BADAWI, M., FILIPPOV, L.O., FILIPPOVA, I.V. and LEBEGUE, S., 2018. Surface properties of fluorite in presence of water: An atomistic investigation. J. Phys. Chem. B. 122, 6829-6836.
  • FOUCAUD, Y., FILIPPOVA, I.V. and FILIPPOV, L.O., 2019. Investigation of the depressants involved in the selective flotation of scheelite from apatite, fluorite, and calcium silicates: Focus on the sodium silicate/sodium carbonate system. Powder Technology. 352, 501-512.
  • FREE, M.L. and MILLER, J.D., 1996. The significance of collector colloid adsorption phenomena in the fluorite/oleate flotation system as revealed by FTIR/IRS and solution chemistry analysis. Int. J. Miner. Process. 48, 197-216.
  • GAO, J., SUN, W., HU, Y., WANG, L., LIU, R., GAO, Z., CHEN, P., TANG, H., JIANG, W. and LYU, F., 2019. Propyl gallate: A novel collector for flotation separation of fluorite from calcite. Chemical Engineering Science. 193, 255-263.
  • HU, Y. and XU, Z., 2003. Interactions of amphoteric amino phosphoric acids with calcium-containing minerals and selective flotation. International Journal of Mineral Processing. 72, 87-94.
  • JONG, K., PAEK, I., KIM, Y., LI, I. and JANG, D., 2020. Flotation mechanism of a novel synthesized collector from Evodiaefructus onto fluorite surfaces. Minerals Engineering. 146,
  • LEWANDOWSKI, B., SAID, B.B., ULBRICHT, M. and KREKEL, G., 2019. Application of Raman spectroscopy to the flotation process of fluorite. Minerals Engineering. 135, 129-138.
  • LI, L., HAO, H., YUAN, Z. and LIU, J., 2017. Molecular dynamics simulation of siderite-hematite-quartz flotation with sodium oleate. Applied Surface Science. 419, 557-563.
  • LIU, C., SONG, S. and LI, H., 2019. Selective flotation of fluorite from barite using trisodium phosphate as a depressant. Minerals Engineering. 134, 390-393.
  • LIU, C., ZHOU, M., XIA, L., FU, W., ZHOU, W. and YANG, S., 2020. The utilization of citric acid as a depressant for the flotation separation of barite from fluorite. Minerals Engineering. 156,
  • LIU, H., KHOSO, S. A., SUN, W., ZHU, Y., HAN, H., HU, Y., KANG, J., MENG, X. and ZHANG, Q., 2019. A novel method for desulfurization and purification of fluorite concentrate using acid leaching and reverse flotation of sulfide. Journal of Cleaner Production. 209, 1006-1015.
  • MARINAKIS, K.I. and SHERGOLD, H.L., 1985. The mechanism of fatty acid adsorption in the presence of fluorite, calcite and barite. International Journal of Mineral Processing. 14, 161-176.
  • MIELCZARSKI, E., MIELCZARSKI, J.A., CASES, J.M., RAI, B. and PRADIP, 20020. Influence of solution conditions and mineral surface structure on the formation of oleate adsorption layers on fluorite. Colloids and Surfaces A: Physicochemical and Engineering. 205, 73–84.
  • SAYILGAN, A. and AROL, A I., 2004. Effect of carbonate alkalinity on flotation behavior of quartz. International Journal of Mineral Processing. 74, 233-238.
  • SIS, H. and CHANDER, S., 2003. Adsorption and contact angle of single and binary mixtures of surfactants on apatite. Minerals Engineering. 16, 839-848.
  • TASKER, P.W., 1980. The structure and properties of fluorite crystal surfaces. Le Journal de Physique Colloques. 41, C6- 488-C6-491.
  • TIAN, J., XU, L., SUN, W., HAN, H., ZENG, X., FANG, S., HONG, K. and HU, Y., 2019. The selective flotation separation of celestite from fluorite and calcite using a novel depressant EDTA. Powder Technology. 352, 62-71.
  • TIAN, J., XU, L., SUN, W., ZENG, X., FANG, S., HAN, H., HONG, K. and HU, Y., 2019. Use of Al2(SO4)3 and acidified water glass as mixture depressants in flotation separation of fluorite from calcite and celestite. Minerals Engineering. 137, 160-170.
  • VINCENT, B.V, 1999. Handbook of Monochromatic XPS Spectra: The Elements of Native Oxides, BE Lookup Table for Signals from Elements and Common Chemical Species. XPS International, Inc: Kawasaki, Japan.
  • WANG, J., LI, W., ZHOU, Z., GAO, Z., HU, Y. and SUN, W., 2020. 1-Hydroxyethylidene-1,1-diphosphonic acid used as pH-dependent switch to depress and activate fluorite flotation I: Depressing behavior and mechanism. Chemical Engineering Science. 214,
  • WANG and HU, 1998. Flotation solution chemistry. Hunan Science and Technology Publishing House. (in Chinese)
  • WANG, Z., WU, H., XU, Y., SHU, K., YANG, J., LUO, L. and XU, L., 2020. Effect of dissolved fluorite and barite species on the flotation and adsorption behavior of bastnaesite. Separation and Purification Technology. 237,
  • XU, Y., XU, L., WU, H., TIAN, J., WANG, Z. and GU, X., 2020. The effect of citric acid in the flotation separation of bastnaesite from fluorite and calcite using mixed collectors. Applied Surface Science. 529,
  • YANG, S., XU, Y., LIU, C., HUANG, L., HUANG, Z. and LI, H., 2020. The anionic flotation of fluorite from barite using gelatinized starch as the depressant. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 597,
  • ZHANG, Z.G., CAO, Y.J., LIAO, Y.F. and MA, Z.L., 2019. Study on comparison adsorption of calcium and sulfate on scheelite and fluorite surfaces. Separation Science and Technology. 54, 1247-1256.
  • ZHENG, R., REN, Z., GAO, H., CHEN, Z., QIAN, Y. and LI, Y., 2018. Effects of crystal chemistry on sodium oleate adsorption on fluorite surface investigated by molecular dynamics simulation. Minerals Engineering. 124, 77-85.
  • ZHOU, H., ZHANG, Y., TANG, X., CAO, Y. and LUO, X., 2020. Flotation separation of fluorite from calcite by using psyllium seed gum as depressant. Minerals Engineering. 159,
  • ZHU, H., QIN, W., CHEN, C., CHAI, L., JIAO, F. and JIA, W., 2018. Flotation separation of fluorite from calcite using polyaspartate as depressant. Minerals Engineering. 120, 80-86
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-15765dc4-dad4-46d0-a396-8a8fefb1e123
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.