Synthesis, Structure and Energetic Properties of a Catenated N6, Polynitro Compound: 1,1’-Azobis(3,5-dinitropyrazole)

• Autorzy: Li Y.-N. , Shu Y.-J. , Wang Y.-L. , Wang B.-Z. , Zhang S.-Y. , Bi F.-Q.

Identyfikatory

DOI

10.22211/cejem/70373

• Języki publikacji: EN

Abstrakty

EN

A nitrogen-rich, polynitro energetic compound with an N,N-azo linkage, 1,1’-azobis(3,5-dinitropyrazole) (ABDNP), has been synthesized by an oxidative coupling reaction of 1-amino-3,5-dinitropyrazole with different oxidizing agents. The target compound was characterized by IR spectroscopy, 1H and 13C nuclear magnetic resonance spectroscopy, elemental analysis, mass spectra, X-ray diffraction and differential scanning calorimetry (DSC). The DSC results show that 1,1’-azobis(3,5-dinitropyrazole) decomposes at a relatively high onset temperature (202.9 °C), which indicates that 1,1’-azobis(3,5-dinitropyrazole) has acceptable thermal stability. The energetic properties were obtained, with a measured density and heat of formation matched by theoretically computed values based on the B3LYP method.

Słowa kluczowe

EN

energetic compound; 1,1’-azobis(3,5-dinitropyrazole); synthesis; energetic properties

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2017
• Tom: Vol. 14, no. 2
• Strony: 321--335
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Li Y.-N.

• State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Shu Y.-J.

• State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Wang Y.-L.

• State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Wang B.-Z.

• State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China

autor

Zhang S.-Y.

• State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China
• Department of Chemistry, School of Pharmacy, Fourth Military Medical University, Xi’an 710032, China

autor

Bi F.-Q.

• State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi’an Modern Chemistry Research Institute, Xi’an 710065, China

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