Uptake of phosphates from water solutions on metallurgical sludge

• Autorzy: Kostura Bruno , Huczala Radim , Klika Zdeněk , Ritz Michal , Bartoňová Lucie , Matýsek Dalibor

Identyfikatory

DOI

10.37190/epe210304

• Języki publikacji: EN

Abstrakty

EN

Steel-making dust slurry (SS) and convertor dust slurry (CS) were tested for uptake of phosphates from aqueous solutions. The adsorption of phosphates on SS and CS corresponded well with both Langmuir and Freundlich adsorption isotherms, which indicated the combination of physical and chemical processes. The maximum adsorbed amount of phosphates on both dust slurry samples was ca. 11 mg P/g. The study evaluates also the effect of acidic leaching on the retention characteristics of both dust slurry samples. From the slurry samples prepared by acidic leaching, the leached convertor dust slurry (CSL) was the only sample capable to retain phosphates. To reveal the retention mechanisms of phosphates, the original and leached dust slurry samples were analyzed by IR and Raman spectroscopy. Co-precipitation of Ca and Fe phosphates, or surface complexation of phosphates were evaluated as the retention mechanisms of CS and CSL while the retention of phosphates by zincite in the case of SS is probably based on their adsorption.

Słowa kluczowe

EN

phosphates; heavy metals; Langmuir isotherm; Freundlich isotherm

PL

fosforany; metale ciężkie; izoterma Langmuira; izoterma Freundlicha

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2021
• Tom: Vol. 47, nr 3
• Strony: 37--51
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Kostura Bruno

• Department of Chemistry, VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava, Czech Republic

• https://orcid.org/0000-0002-8019-4524

autor

Huczala Radim

• Department of Chemistry, VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava, Czech Republic

• https://orcid.org/0000-0002-6264-9986

autor

Klika Zdeněk

• Department of Chemistry, VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava, Czech Republic

• https://orcid.org/0000-0002-5261-3648

autor

Ritz Michal

• Department of Chemistry, VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava, Czech Republic

• https://orcid.org/0000-0002-1679-3055

autor

Bartoňová Lucie

• Department of Chemistry, VSB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava, Czech Republic

• https://orcid.org/0000-0003-3387-4057

autor

Matýsek Dalibor

• Institute of Geological Engineering, VŠB – Technical University of Ostrava, 17. listopadu 15/2172, 708 33 Ostrava, Czech Republic

• https://orcid.org/0000-0002-1412-1079

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