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Study on organic radicals giving rise to multicomponent EMR spectra in dried fruits expose to ionizing radiation II. D-Glucose

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Electron Magnetic Resonance Forum EMR-PL (2; 16-18.05.2013; Częstochowa-Hucisko, Poland )
Języki publikacji
EN
Abstrakty
EN
Crystalline D-glucose extracted from dried resins was irradiated with 60Co gamma rays. The multicomponent EMR spectra of the samples kept at ambient temperature were compared with those heated at 105°C – the temperature close to the melting point of glucose. Normalized EMR spectra recorded with both samples were subtracted, resulting in a differential EMR spectrum. Spectral analysis of all three spectra has been done resulting in the identification of isotropic doublet of doublets assigned to less stable radical derived from parent glucose molecule.
Czasopismo
Rocznik
Strony
425--428
Opis fizyczny
Bibliogr. 14 poz., rys.
Twórcy
autor
  • Laboratory for Detection of Irradiated Food, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str. 03-195 Warsaw, Poland, Tel.: +48 22 504 1066, Fax: +48 22 811 1532
  • Laboratory for Detection of Irradiated Food, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str. 03-195 Warsaw, Poland, Tel.: +48 22 504 1066, Fax: +48 22 811 1532
Bibliografia
  • 1. Codex General Standard for Irradiated Foods. Codex Alimentarius STAN 106-1983; Vol. XV, Rev. 1-2003
  • 2. De Cooman H, Vanhaelewyn G, Pauwels E, Sangstuen E, Waroquier M, Callens F (2008) Radiation-induced radicals in glucose-1-phosphate. I. Electron paramagnetic resonance and electron nuclear double resonance analysis of in situ X-irradiated single crystals at 77 K. J Phys Chem B 112;15045–15053
  • 3. European Committee for Standardisation (2003) PN-EN 13708:2003 Foodstuffs – Detection of irradiated food containing crystalline sugar by ESR spectroscopy. CEN, Brussels
  • 4. Guzik GP, Stachowicz W, Michalik J (2008) Study on stable radicals produced by ionizing radiation in dried fruits and related sugars by electron paramagnetic resonance spectrometry and photostimulated luminescence method – I. D-Fructose. Nukleonika 53;Suppl 2:S89–S94
  • 5. Guzik GP, Stachowicz W, Michalik J (2010) Study on organic radicals giving rise to multicomponent EMR spectra in dried fruits exposed to ionizing radiation. Curr Top Biophys 33;Suppl A:81–85
  • 6. Handbook of physical chemistry (1974) WNT, Warsaw (in Polish)
  • 7. Karakirova Y, Yordanov ND, De Cooman H, Vrielinck H, Callens F (2010) Dosimetric characteristics of different types of saccharides: An EPR and UV spectrometric study. Radiat Phys Chem 79:654–659
  • 8. Mischke J, Helle N, Linke B, Schreiber GA (1994) Elektronen-Spin-Resonanz-Messung an Trockenfruchten. Zeitschrift Ernaehrungswissenschaft 33:258–266
  • 9. Pauwels E, Cooman H, Vanhaelewyn G, Sangstuen E, Callens F, Waroquier M (2008) Radiation-induced radicals in glucose-1-phosphate. II. DFT analysis of structures and possible formation mechanisms. J Phys Chem B 112:15054–15063
  • 10. Raffi J, Angel JP (1989) Electron spin resonance identification of irradiated fruits. Radiat Phys Chem 34;6:891–894
  • 11. Raffi J, Angel JP, Ahmend SH (1991) Electron spin resonance identification of irradiated dates. Food Technol 3/4:26–30
  • 12. Stachowicz W, Burlińska G, Michalik J, Dziedzic-Goclawska, A, Ostrowski K (1996) EPR spectroscopy for the detection of foods treated with ionising radiation. In: McMurray CH, Stewart EM, Gray R, Pearce J (eds) Detection methods for irradiated foods. Current status. The Royal Society of Chemistry, Cambridge, pp 23–32
  • 13. Stachowicz W, Strzelczak G, Michalik J, Wojtowicz A, Dziedzic-Gocławska A, Ostrowski K (1992) Application of EPR spectroscopy for control of irradiated food. J Sci Food Agric 58:407–415
  • 14. Tarpan M, Sangstuen E, Pauwels E, Vrielinck H, Waroquier M, Callens F (2008) Combined electron magnetic resonance and density functional theory study of 10 K X-irradiated β-D-Fructose single crystals. J Phys Chem A 112:3898–3905
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-13c6e85f-1979-4661-ae77-14c781bac0b9
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