Equilibrium and kinetics studies for the adsorption of Ni2+ and Fe3+ ions from aqueous solution by graphene oxide

Konicki, W.; Aleksandrzak, M.; Mijowska, E.

doi:10.1515/pjct-2017-0058

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Tytuł artykułu

Equilibrium and kinetics studies for the adsorption of Ni2+ and Fe3+ ions from aqueous solution by graphene oxide

Autorzy

Konicki W. , Aleksandrzak M. , Mijowska E.

Treść / Zawartość

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Polish Journal of Chemical Technology_3_2017_Konicki.pdf

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Identyfikatory

DOI

10.1515/pjct-2017-0058

Warianty tytułu

Języki publikacji

Abstrakty

In this study, the adsorption of Ni²⁺ and Fe³⁺ metal ions from aqueous solutions onto graphene oxide (GO) have been explored. The effects of various experimental factors such as pH of the solution, initial metal ion concentration and temperature were evaluated. The kinetic, equilibrium and thermodynamic studies were also investigated. The adsorption rate data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order kinetic model and the intraparticle diffusion model. Kinetic studies indicate that the adsorption of both ions follows the pseudo-second-order kinetics. The isotherms of adsorption data were analyzed by adsorption isotherm models such as Langmuir and Freundlich. Equilibrium data fitted well with the Langmuir model. The maximum adsorption capacities of Ni²⁺ and Fe³⁺ onto GO were 35.6 and 27.3 mg g^-1 , respectively. In addition, various thermodynamic parameters, such as enthalpy (ΔHO), entropy (ΔSO) and Gibbs free energy (ΔGO), were calculated.

Słowa kluczowe

nickel iron graphene oxide adsorption kinetics

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2017

Tom

Vol. 19, nr 3

Strony

120--129

Opis fizyczny

Bibliogr. 69 poz., rys., tab.

Twórcy

autor

Konicki W.

w.konicki@am.szczecin.pl

Maritime University of Szczecin, Department of Integrated Transport Technology and Environmental Protection, Henryka Pobożnego St. 11, 70-507 Szczecin, Poland

autor

Aleksandrzak M.

West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Institute of Chemical and Environment Engineering, Pułaskiego St. 10, 70-322 Szczecin, Poland

autor

Mijowska E.

West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Institute of Chemical and Environment Engineering, Pułaskiego St. 10, 70-322 Szczecin, Poland

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).

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