PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Synthesis and Characterization of Novel Biochar Developed from Peganum Harmala Seeds to Adsorb Heavy Metals from Aqueous Solution

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Referring to the oil and industrial development, contamination of water streams and soil by heavy metals becomes severe issue. Biochar has consider as cheap and ecofriendly adsorbent for heavy metal ions removal. As well as, the development and modification of biochar has been a center point of many researches. In this study it has been suggested to develop novel biochar from Peganum harmala seed precursor and evaluate the heavy metal ions adsorption performance. Chemical activation process was adopted to prepare biochar with different concentrations (20%, 30%, and 40%) of phosphoric acid followed by pyrolysis in a laboratory horizontally tube furnace underneath an N2 blanket at 600°C for 3 hours. The physical and chemical properties of biochar have been assessed using Energy Dispersive X-ray Spectroscopy, X-ray diffraction, Scanning Electron Microscopy, pore structure, and Fouriertransform analysis. The prepared biochar was investigated to absorb three different heavy metal ions Fe(III), Ni(II) and Pb(II) from an aqueous solution under varied conditions. Heavy metal concentration (20–100 ppm), adsorbent dosage (0.25–0.75) g/L, contact duration (0–560 min), and solution pH (2–9) were examined. The results show that the largest BET surface area (691.58 m2/g) was achieved with activation conversation of 40% H3PO4 and 600°C for 3 hours, compared to other samples. The maximum adsorption capacities were 113.4096, 112.3355, 180.3478 mg/g for Fe(III), Ni(II) and Pb(II) respectively. Finally, Freundlich isotherm model shows better describe the adsorption equilibrium data, while adsorption kinetic data shows the pseudo-first-order model fits more with Fe(III) ions which shows that chemisorption was controlled in the adsorption process, additionally the pseudo-first-order model fits more with Pb(II) and Ni(II) ions this mean the physisorption has been controlled in the adsorption process.
Rocznik
Strony
99--118
Opis fizyczny
Bibliogr. 52 poz, rys., tab.
Twórcy
  • Department of Chemical Engineering, Al Nahrain University, Baghdad, Iraq
  • Department of Chemical Engineering, Al Nahrain University, Baghdad, Iraq
Bibliografia
  • 1. Abdulmajeed, Y.R., Al-Huda, N. and Mahmood, J. 2018. Production of high surface area activated carbon from grass (Imperata). Iraqi Journal of Chemical and Petroleum Engineering, 19(2), 33–37. Available at: www.iasj.net
  • 2. Afroze, S. and Sen, T.K. 2018. A Review on heavy metal ions and dye adsorption from water by agricultural solid waste adsorbents. Water, Air, and Soil Pollution, 229(7). Available at: https://doi.org/10.1007/s11270-018-3869-z
  • 3. Ajmani, A., Patra, C., Subbiah, S., Narayanasamy, S. 2020. Packed bed column studies of hexavalent chromium adsorption by zinc chloride activated carbon synthesized from Phanera vahlii fruit biomass. Journal of Environmental Chemical Engineering, 8(4), 103825. https://doi.org/10.1016/j.jece.2020.103825
  • 4. Alias, N., Zuki, N.M., Alias, S.H., Kamal, M. 2012. Removal of iron (Fe) by Adsorption using activated carbon Moringa oleifera (ACMO) in Aqueous Solution. Jurnal Intelek, 7(2), 22–29.
  • 5. Aljumaili, M.M.N. and Abdul-Aziz, Y.I. 2023. High surface area peat moss biochar and its potential for Chromium metal adsorption from aqueous solutions. South African Journal of Chemical Engineering, 46, 22–34. Available at: https://doi.org/10.1016/j.sajce.2023.06.006
  • 6. Alslaibi, T.M., Abustan, I., Ahmad, M.A., Foul, A.A. 2013. Comparison of activated carbon prepared from olive stones by microwave and conventional heating for iron (II), lead (II), and copper (II) removal from synthetic wastewater. Environmental Progress & Sustainable Energy, 33(4), 1074–1085. https://doi.org/10.1002/ep.11877
  • 7. Ammar, S.H. and Jaafar, S.A. 2017. Adsorption kinetic and isotherms studies of thiophene removal from model fuel on activated carbon supported copper oxide. Iraqi Journal of Chemical and Petroleum Engineering, 18(2), 83–93. Available at: https://doi.org/10.31699/IJCPE.2017.2.7
  • 8. Awwad, N., El-Zahhar, A., Fouda, A., Ibrahium, H. 2013. Removal of heavy metal ions from ground and surface water samples using carbons derived from date pits. Journal of Environmental Chemical Engineering, 1(3), 416–423. https://doi.org/10.1016/j.jece.2013.06.006
  • 9. Brishti, R.S., Kundu, R., Habib, M.A., Ara, M.H. 2023. Adsorption of iron(III) from aqueous solution onto activated carbon of a natural source: Bombax ceiba fruit shell. Results in Chemistry, 5, 100727. https://doi.org/10.1016/j.rechem.2022.100727
  • 10. Cardell, C., Yebra, A., Van Grieken, R.E. 2002. Applying digital image processing to SEM-EDX and BSE images to determine and quantify porosity and salts with depth in porous media. Mikrochimica Acta, 140(1–2), 9–14. https://doi.org/10.1007/s006040200063
  • 11. Chandra, T.C., Mirna, M.M., Sunarso, J., Sudaryanto, Y., Ismadji, S. 2009. Activated carbon from durian shell: Preparation and characterization. Journal of the Taiwan Institute of Chemical Engineers, 40(4), 457–462. https://doi.org/10.1016/j.jtice.2008.10.002
  • 12. Chen, X. 2015 Modeling of experimental adsorption isotherm data’, Information (Switzerland), 6(1), 14–22. Available at: https://doi.org/10.3390/info6010014
  • 13. Chiu, Y.H. and Lin, L.Y. 2019. Effect of activating agents for producing activated carbon using a facile one-step synthesis with waste coffee grounds for symmetric supercapacitors. Journal of the Taiwan Institute of Chemical Engineers, 101, 177–185. Available at: https://doi.org/10.1016/j.jtice.2019.04.050
  • 14. El-Bendary, N., El-Etriby, H.K. and Mahanna, H. 2021. High-performance removal of iron from aqueous solution using modified activated carbon prepared from corn cobs and luffa sponge. Desalination and Water Treatment, 213, 348–357. Available at: https://doi.org/10.5004/dwt.2021.26721
  • 15. Elewa, A., Amer, A., Attalah, M., Gad, H. 2021. Removal of some heavy metals contaminants from aqueous solutions by applying biomass-based modif ied activated carbon. Egyptian Journal of Chemistry. 64(10), 5929–5944 https://doi.org/10.21608/ ejchem.2021.72070.3600Elmaguana Elhadiri, N., Bouchdoug, M., Jaouad, A. 2018. Moroccan Journal of Chemistry Optimization of preparation conditions of activated carbon from walnut cake. Mor. J. Chem. 6(1), 92–105.
  • 16. El-Sadaawy, M. and Abdelwahab, O. 2014. Adsorptive removal of nickel from aqueous solutions by activated carbons from doum seed (Hyphaenethebaica) coat Alexandria Engineering Journal, 53(2), 399–408. Available at: https://doi.org/10.1016/j.aej.2014.03.014
  • 17. Girgis, B.S., Yunis, S.S. and Soliman, A.M. 2002. Characteristics of activated carbon from peanut hulls in relation to conditions of preparation. Materials Letters, 57, 164–172. Available at: www.elsevier.com/locate/matlet
  • 18. Kannan, D., Mani, N. 2014. Removal of Hardness (Ca2+, Mg2+) and Alkalinity from Ground Water by Low Cost Adsorbent using Phyllanthus emblica Wood. International Journal of Chemical and Pharmaceutical Analysis, 1, 208–212. Available at: http://www.ijcpa.in
  • 19. Karagoz, S., Tay, T., Ucar, S., Erdem, M. 2008. Activated carbons from waste biomass by sulfuric acid activation and their use on methylene blue adsorption. Bioresource Technology, 99(14), 6214–6222. https://doi.org/10.1016/j.biortech.2007.12.019
  • 20. Khadiran, T., Hussein, M.Z., Zainal, Z., Rusli, R. 2014. Textural and chemical properties of activated carbon prepared from tropical peat soil by chemical activation method. Bioresources, 10(1). https://doi.org/10.15376/biores.10.1.986-1007
  • 21. Kumar, G., Tonu, N.T., Dhar, P.K., Mahiuddin. 2021. Removal of Fe3+ ions from wastewater by activated borassus flabellifer male flower charcoal. Pollution, 7(3), 693–707. https://doi.org/10.22059/poll.2021.320575.1033
  • 22. Lee, Y., Jo, J., Kim, I., Yoo, Y. 2017. Chemical characteristics and NaCl component behavior of biochar derived from the salty food waste by water flushing. Energies, 10(10), 1555. https://doi.org/10.3390/en10101555
  • 23. Li, Y., Du, Q., Wang, X., Zhang, P., Wang, D., Wang, Z., Xia, Y. 2010. Removal of lead from aqueous solution by activated carbon prepared from Enteromorpha prolifera by zinc chloride activation. Journal of Hazardous Materials, 183(1–3), 583–589. https://doi.org/10.1016/j.jhazmat.2010.07.063
  • 24. Lozano-Castelló, D., Lillo-Ródenas, M., CazorlaAmorós, D., Linares-Solano, A. 2001. Preparation of activated carbons from Spanish anthracite. Carbon, 39(5), 741–749. https://doi.org/10.1016/s0008-6223(00)00185-8
  • 25. Mao, T., Su, Q. and Cheng, Y. 2022. Statistical method of pore size distribution of disordered mesoporous materials based on electron microscope imaging. Journal of Physics: Conference Series. Institute of Physics. Available at: https://doi.org/10.1088/1742-6596/2321/1/012008
  • 26. Mopoung, S., Moonsri, P., Palas, W., Khumpai, S. 2015b. Characterization and properties of activated carbon prepared from tamarind seeds by KOH activation for Fe(III) adsorption from aqueous solution. ˜the œScientific World Journal/The Scientific World journal, 2015, 1–9. https://doi.org/10.1155/2015/415961
  • 27. Mousa, K.M. and Hadi, H.J. 2016 Coagulation/ Flocculation Process for Produced Water Treatment. International Journal of Current Engineering and Technology, 6(2), 551–554. Available at: http:// inpressco.com/category/ijcet
  • 28. Mungray, A.A., Kulkarni, S.V. and Mungray, A.K. 2012. Removal of heavy metals from wastewater using micellar enhanced ultrafiltration technique: A review. Central European Journal of Chemistry, 27–46. Available at: https://doi.org/10.2478/s11532-011-0134-3
  • 29. Nandiyanto, A.B.D., Oktiani, R. and Ragadhita, R. 2019. How to read and interpret ftir spectroscope of organic material. Indonesian Journal of Science and Technology, 4(1), 97–118. Available at: https://doi.org/10.17509/ijost.v4i1.15806
  • 30. Prahas, D., Kartika, Y., Indraswati, N., Ismadji, S. 2008. Activated carbon from jackfruit peel waste by H3PO4 chemical activation: Pore structure and surface chemistry characterization. Chemical Engineering Journal, 140(1–3), 32–42. https://doi.org/10.1016/j.cej.2007.08.032
  • 31. Qu Deyang, and S.H. 2002. Studies of the activated carbons used in double-layer supercapacitors, Journal of Power Sources, 109(2), 403–411. Available at: https://doi.org/10.1016/S0378-7753(02)00108-8
  • 32. Radhy, E.D. and Najim, S.T. 2022. Toxicity remediation of petroleum refinery wastewater by electrooxidation techniques using graphite electrode, in IOP conference series: Earth and Environmental Science. Institute of Physics. Available at: https://doi.org/10.1088/1755-1315/1029/1/012031
  • 33. Razi, M.M., Hishammudin, M.N.M., Hamdan, R. 2017. Factor affecting textile dye removal using adsorbent from activated carbon: a review. MATEC Web of Conferences, 103, 06015. https://doi.org/10.1051/matecconf/201710306015
  • 34. Shrestha, D. and Nyachhyon, A.R. 2021. The effects of different activating agents on the physical and electrochemical properties of activated carbon electrodes fabricated from wood-dust of Shorea robusta, Heliyon, 7(9). Available at: https://doi.org/10.1016/j.heliyon.2021.e07917
  • 35. Shrestha, R.M., Varga, I., Bajtai, J., Varga, M. 2013. Design of surface functionalization of waste material originated charcoals by an optimized chemical carbonization for the purpose of heavy metal removal from industrial waste waters. Microchemical Journal, 108, 224–232. https://doi.org/10.1016/j.microc.2012.11.002
  • 36. Slaiman, Q.J.M., Haweel, C.K. and Abdulmajeed, Y.R. 2010. Removal of heavy metal ions from aqueous solutions using bioconversion on bamboo, Iraqi Journal of Chemical and Petroleum Engineering, 11(3), 23–32.
  • 37. Songrit, J., Ruamsanith, D., Sagnuansakbaramee, N., Wongchuphan, R. 2017. Metal Ion Adsorption using Durian-Peel Activated Carbon, Suratthani Rajabhat Universitry.
  • 38. Swelam, A.A., Sherif, S.S. and Ibrahim, A. 2018. Synthesis and modeling of lead(II) removal from homogeneous and real wastewater by Moringa oleifera seeds. Al Azhar Bulletin of Science, 29(2-A), 105–124.
  • 39. Taseidifar, M., Makavipour, F., Pashley, R.M., Rahman, A.M. 2017. Removal of heavy metal ions from water using ion flotation. Environmental Technology & Innovation, 8, 182–190. https://doi.org/10.1016/j.eti.2017.07.002
  • 40. Timur, S., Kantarli, I.C., Onenc, S., Yanik, J. 2010. Characterization and application of activated carbon produced from oak cups pulp. Journal of Analytical and Applied Pyrolysis, 89(1), 129–136. https://doi.org/10.1016/j.jaap.2010.07.002
  • 41. Tounsadi, H., Khalidi, A., Abdennouri, M., Barka, N. 2016. Activated carbon from Diplotaxis Harra biomass: Optimization of preparation conditions and heavy metal removal. Journal of the Taiwan Institute of Chemical Engineers, 59, 348–358. https://doi.org/10.1016/j.jtice.2015.08.014
  • 42. Tounsadi, H., Khalidi, A., Machrouhi, A., Farnane, M., Elmoubarki, R., Elhalil, A., Sadiq, M., Barka, N. 2016. Highly efficient activated carbon from Glebionis coronaria L. biomass: Optimization of preparation conditions and heavy metals removal using experimental design approach. Journal of Environmental Chemical Engineering, 4(4), 45494564. https://doi.org/10.1016/j.jece.2016.10.020
  • 43. Widiatmoko, E., Abdullah, M., Khairurrijal, N., Abdullah, M., Khairurrijal, N. 2010. A method to measure pore size distribution of porous materials using scanning electron microscopy images. AIP Conference Proceedings. https://doi.org/10.1063/1.3515554
  • 44. Xiao, R. and Yang, W. 2013. Influence of temperature on organic structure of biomass pyrolysis products. Renewable Energy, 50, 136–141. Available at: https://doi.org/10.1016/j.renene.2012.06.028
  • 45. Xu, J., Chen, L., Qu, H., Jiao, Y., Xie, J., Xing, G. 2014. Preparation and characterization of activated carbon from reedy grass leaves by chemical activation with H3PO4. Applied Surface Science, 320, 674–680. https://doi.org/10.1016/j.apsusc.2014.08.178
  • 46. Yakout, S.M. and Sharaf El-Deen, G. 2016. Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arabian Journal of Chemistry, 9, S1155–S1162. Available at: https://doi.org/10.1016/j.arabjc.2011.12.002
  • 47. Yang, K., Peng, J., Srinivasakannan, C., Zhang, L., Xia, H., Duan, X. 2010. Preparation of high surface area activated carbon from coconut shells using microwave heating. Bioresource Technology, 101(15), 6163–6169. https://doi.org/10.1016/j.biortech.2010.03.001
  • 48. Yang, K., Peng, J., Srinivasakannan, C., Zhang, L., Xia, H., Duan, X. 2010. Preparation of high surface area activated carbon from coconut shells using microwave heating. Bioresource Technology, 101(15), 6163–6169. https://doi.org/10.1016/j.biortech.2010.03.001
  • 49. Zainab, A.H.A. 2024. Adsorption of dyes from simulated wastewater by activated carbon developed from agricultural materials. [Master’s thesis,AlNahrain University College of Engineering],Iraq.
  • 50. Zakaria, R., Jamalluddin, N.A., Bakar, M.Z.A. 2021. Effect of impregnation ratio and activation temperature on the yield and adsorption performance of mangrove based activated carbon for methylene blue removal. Results in Materials, 10, 100183. https://doi.org/10.1016/j.rinma.2021.100183
  • 51. Zhang, X., Hao, Y., Wang, X., Chen, Z. 2017. Adsorption of iron(III), cobalt(II), and nickel(II) on activated carbon derived from Xanthoceras Sorbifolia Bunge hull: mechanisms, kinetics and influencing parameters. Water Science & Technology, 75(8), 1849–1861. https://doi.org/10.2166/wst.2017.067
  • 52. Zou, G., She, J., Peng, S., Yin, Q., Liu, H., Che, Y. 2020. Two-dimensional SEM image-based analysis of coal porosity and its pore structure. International Journal of Coal Science & Technology/ International Journal of Coal Science & Technology, 7(2), 350–361. https://doi.org/10.1007/s40789-020-00301-8
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-11ee0761-2daf-415a-8cb4-e7e75c4f63a8
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.