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Leaching kinetics of iron from coal-series kaolin by oxalic acid solutions

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Removal of iron from coal-series kaolinite and its kinetics by chemical leaching were investigated in this paper. The optimal removal rate of iron reaches 29.09% (the content of Fe2O3 decreased from 0.55 to 0.39%) under the conditions of 100 °C, 0.4 M C2H2O4, and liquid-to-solid ratio of 4 cm3/g for 120 min. The leaching process was successfully described by the Avrami model and mainly controlled by internal diffusion control of shrinking core model, the apparent activation energy is 18.46 kJ/mol. The experimental results were consistent with the internal diffusion control of shrinking core model, improving acid concentration and leaching temperature could promotes the removal of iron from coal-series kaolin.
Rocznik
Strony
134--146
Opis fizyczny
Bibliogr. 13 poz., rys., tab.
Twórcy
autor
  • School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • Hainan Branch, China Triumph International Engineering Co, Ltd, Haikou 570125, China
autor
  • Hainan Branch, China Triumph International Engineering Co, Ltd, Haikou 570125, China
autor
  • School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
Bibliografia
  • AMBIKADEVI, V.R., LALITHAMBIKA, M., 2000. Effect of organic acids on ferric iron removal from iron-stained kaolinite. Appl. Clay Sci. 16(3), 133-145.
  • GUO, M.R., LIN, Y.M., XU, X.P., CHEN, Z.L., 2010. Bioleaching of iron from kaolin using Fe(III)-reducing bacteria with various carbon nitrogen sources. Appl. Clay Sci. 48(3), 379-383.
  • HUANG, T., LEI, S.M., LIU, Y.Y., LI, B., 2019. Optimization for the COD reduction and thermodynamics research of coalseries kaolin. Environ Earth Sci. 78(12), 363.
  • LEVENSPIEL, O., 1972. Chemical Reaction Engineering. Wiley, New York, 361-371.
  • LIN M., LIU Y. Y., LEI S.M., YE Z., PEI Z.Y., LI B., 2018. High-efficiency extraction of Al from coal-series kaolinite and its kinetics by calcination and pressure acid leaching. Appl. Clay Sci, 161, 215-224.
  • MARTINEZ-LUEVANOS, A., RODRIGUEZ-DELGADO, M.G., URIBE-SALAS, A., CARRILLO-PEDROZA, E.R., OSUNA-ALARCON, J.G., 2011 Leaching kinetics of iron from low grade kaolin by oxalic acid solutions. Appl. Clay Sci. 51(4), 473-477.
  • SOKIĆ M.D., MARKOVIC B., ZIVKOVIC D., 2009. Kinetics of chalcopyrite leaching by sodium nitrate in sulphuric acid. Hydrometallurgy. 95(3–4), 273-279.
  • TUNÇ, M., KOCAKERIM, M.M., ÖZKAN, K., 2007. Dissolution of colemanite in (NH4)2SO4 solutions. Korean J. Chem. Eng. 24(1), 55-59.
  • QUEROL, X., IZQUIERDO, M., MONFORT, E., ALVAREZ, E., FONT, O., MORENO, T., ALASTUEY, A., ZHUANG, X., LU, W., WANG, Y., 2008. Environmental characterization of burnt coal gangue banks at Yangquan, Shanxi Province, China. Int. J. Coal Geol. 75(2), 93-104.
  • VEGLIO, F., PAGLIARINI, A., TORO, L., 1993. Factorial experiments for the development of a kaolin bleaching process. Int. J. Miner. Process. 39(39), 87-99.
  • XIA, G.H., LU, M., SU, X.L., ZHAO, X.D.,2012. Iron removal from kaolin using thiourea assisted by ultrasonic wave. Ultrason. Sonochem. 19(1), 38-42.
  • YU, M.M., JIANG, X.Q., MEI, G.J., CHEN, X.D., 2017. Leaching kinetic study of Y and Eu from waste phosphors using hydrochloric acid solution containing hydrogen peroxide. Physicochem. Probl. Mineral Proc. 54(2), 238-248.
  • ZHU, P.W., ZENG, W.Q., XU, X. L., CHENG, L.M., JIANG, X., SHI, Z.L., 2014. Influence of acid leaching and calcination on iron removal of coal kaolin. Int. J. Min. Met. Mater. 21(4), 317-325.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1187b3ae-2ebf-4780-98a4-c14fdb51f670
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