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Tworzenie się rozpuszczalnego substratu organicznego podczas zasadowego rozpuszczania osadów ściekowych
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Abstrakty
Improving the effects of hydrolysis on waste activated sludge (WAS) prior to anaerobic digestion is of primary importance. Several technologies have been developed and partially implemented in practice. In this paper, perhaps the simplest of these methods, alkaline solubilization, has been investigated and the results of hydrolysis are presented. An increase to only pH 8 can distinctively increase the soluble chemical oxygen demand (SCOD), and produce an anaerobic condition effect favorable to volatile fatty acids (VFA) production. Further increases of pH, up to pH 10, leads to further improvements in hydrolysis effects. It is suggested that an increase to pH 9 is sufficient and feasible for technical operations, given the use of moderate anti-corrosive construction material. This recommendation is also made having taken in consideration the option of using hydrodynamic disintegration after the initial WAS hydrolysis process. This paper presents the effects of following alkaline solubilization with hydrodynamic disintegration on SCOD.
Zastosowanie wstępnej hydrolizy osadu czynnego wpływa w znaczący sposób na poprawę efektów fermentacji beztlenowej. W pracy przedstawiono wyniki wstępnej alkalizacji osadu. Stwierdzono, że w wyniku wzrostu pH do 8 nastąpiło wyraźne zwiększenie ChZT w cieczy nadosadowej i intensyfikacja produkcji LKT, a zmiana odczynu do pH 10 powoduje zwiększenie efektów hydrolizy. Wykazano, że wstępna hydroliza osadu do pH 9 jest możliwa do zastosowania w praktyce, z uwagi na wykorzystanie materiałów konstrukcyjnych o umiarkowanej odporności na korozję. Po wstępnej alkalizacji możliwe jest stosowanie innych metod dezintegracji osadu. W pracy przedstawiono wyniki kondycjonowania osadu poprzez alkalizacje w połączeniu z dezintegracją hydrodynamiczną.
Czasopismo
Rocznik
Tom
Strony
29--38
Opis fizyczny
Bibliogr. 19 poz., tab., wykr.
Twórcy
autor
- Polish Academy of Sciences, Poland Institute of Environmental Engineering
autor
- Polish Academy of Sciences, Poland Institute of Environmental Engineering
autor
- Polish Academy of Sciences, Poland Institute of Environmental Engineering
- University of Bielsko-Biała, Poland Institute of Environmental Protection and Engineering
autor
- University of Bielsko-Biała, Poland Institute of Environmental Protection and Engineering
Bibliografia
- [1] Athanasoulia, E., Melidis, P. & Aivasidis, A. (2007). Characterization of enhanced anaerobic degradation of digested sludge mixture after thermo-chemical and enzymatic treatment, Proceedings 10th International Conferences Environmental Sciences and Technology, CEST-2007, pp. A-101-108, Greece 2007.
- [2] Chen, Y.G., Jiang, S., Yuan, H.Y., Zhou, Q. & Gu, G.W. (2007). Hydrolysis and acidifi cation of waste activated sludge at different pH, Water Research, 41, pp. 683-689.
- [3] Gogate, P.R. & Pandit, A.B. (2005). A review and assessment of hydrodynamic cavitation as technology for the future, Ultrasonics Sonochemistry, 12, pp. 21-27.
- [4] Grübel, K. (2007). Process and conditions of microorganisms lysis during the hydrodynamic cavitation (PhD dissertation), Technical University, Częstochowa 2007. (in Polish)
- [5] Grübel, K. & Machnicka, A. (2009). Use of hydrodynamic disintegration to accelerate anaerobic digestion of surplus activated sludge, Water Environment Research, 81(12), pp. 2420-2426.
- [6] Grübel, K., Machnicka, A. & Wacławek, S. (2013). Impact of alkalization of surplus activated sludge on biogas production. Ecological Chemistry and Engineering S, 20, pp. 343-351.
- [7] Kalumuck, K.M. & Chahine, G.L. (2000). The use of cavitating jets to oxidize organic compounds in water. Journal of Fluids Engineering, 122, pp. 465-470.
- [8] Kim, J.S., Park, C.H. & Kim, T.H. (2003). Effects of various pretreatment for enhanced anaerobic digestion with waste activated sludge, Journal of Bioscience and Bioengineering, 95, pp. 271-275.
- [9] Li, H., Jn, Y., Mahar, R.B., Wang, Z. & Nie, Y. (2008). Effects and model of alkaline waste activated sludge treatment, Bioresources Technology, 99, pp. 5140-5144.
- [10] Lin, Y. (2003). Chemically reduced excess sludge production in the activated sludge process, Chemosphere, 50, 1-7.
- [11] Neyens, E., Baeyens, J. & Creemers, C. (2003). Alkaline thermal sludge hydrolysis, Journal of Hazardous Materials, 106, pp. 83-92.
- [12] Ramakrishna, D.M. & Virarghavan, V. (2005). Strategies for sludge minimization in activated sludge process - a review, Fresenius Environmental Bulletin, 14, pp. 1-11
- [13] Rice, E.W., Baird, R.B., Eaton, A.D. & Clesceri, L.S. (EDS.) (2012). Standard methods for the examination of water and wastewater (22nd edition) Washington: American Public Health Association; Washington 2012.
- [14] Rocher, M., Roux, G., Goma, G., Begue, A. P., Louvel, L. & Rois, J.L. (2001). Excess sludge reduction in activated sludge process by integrating biomass alkaline heat treatment, Water Science and Technology, 44, pp. 437-444.
- [15] Suschka, J., Machnicka, A. & Grübel, K. (2007a) Surplus activated sludge disintegration for additional nutrients removal, Archives of Environmental Protection, 33, pp. 55-65.
- [16] Suschka, J., Grübel, K. & Machnicka, A. (2007b). The prospect of intensification of sewage sludge anaerobic fermentation through activated sludge disintegration in the mechanical cavitation process, Gaz, Woda i Technika Sanitarna, 3, pp. 26-28. (in Polish)
- [17] Tae-Hun, K., Tak-Hyun, K., Seungho, Yu., Youn, K.N., Dong-Kyu, Ch., Sang, R.L. & Myun-Joo, L. (2007). Solubilisation of waste activated sludge with alkaline treatment and gamma ray irradiation, Journal of Industrial and Engineering Chemistry, 13, pp. 1149-1153.
- [18] Weemaes, M.P., Verstraete, J. (1998). Evaluation of current wet sludge disintegration techniques, Journal of Chemical Technology and Biotechnology, 73, pp. 83-92.
- [19] Zielewicz-Madej, E. (2000). Application of ultrasonic field for the intensification of biochemical degradation of organic compounds in sludge, Molecular and Quantum Acoustics, 21, pp. 319-326
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-118422ac-625a-44b2-9468-040ed6fd3868