Synthetic Textile Wastewater Treatment using Potassium Ferrate(VI) – Application of Taguchi Method for Optimisation of Experiment

• Autorzy: Thomas M. , Barbusiński K. , Kliś S. , Szpyrka E. , Chyc M.

Identyfikatory

DOI

10.5604/01.3001.0011.7313

Warianty tytułu

PL

Oczyszczanie syntetycznych ścieków farbiarskich przy wykorzystaniu żelazianu(VI) potasu – zastosowanie metody Taguchi do optymalizacji eksperymentu

• Języki publikacji: EN

Abstrakty

EN

The article attempts to assess the usefulness of the Taguchi method to optimise the purification process of synthetic textile wastewater (pH 6.7 - 7.2, Conductivity = 6.71 - 6.84 mS/cm, Salinity = 3581 - 3648 mg NaCl/l, Colour = 560 - 4710 mg Pt/l, COD = 2220 - 2290 mg O₂/l, TOC = 394 - 551 mg/l) using K₂FeO₄. The research was conducted using 3 types of wastewater containing anionic detergent (sodium lauryl sulfate, 100 mg/l) and differing only in the concentration of azo dye Acid Green 16 (AG 16). Technical K₂FeO₄ was used as an oxidiser, which was subjected to physico-chemical analysis (purity, UV-VIS spectrum, surface characteristics and chemical composition using SEM and EDX methods). For planning and optimising the wastewater treatment process, the Taguchi method was used for four input parameters: pH (2, 7, 12), reaction time (10, 30, 50 min), AG 16 concentrations (20, 120, 220 mg/l) and K₂FeO₄ concentrations (25, 125, 225 mg/l), for which 9 experiments were performed in accordance with the plan adopted. Test result analysis allowed to indicate the optimal values for individual input parameters (pH 2, time = 50 min, AG 16 = 20 mg/l, K₂FeO₄ = 125 mg/l). Under these conditions, visual discoloration of wastewater was obtained (AG 16 = 0.4 mg/l, ↓98% ), colour removal (66 mg Pt/l, ↓88%) and DOC (249 mg/l, ↓37%).

PL

W artykule podjęto próbę oceny przydatności metody Taguchi do optymalizacji procesu oczyszczania syntetycznych ścieków farbiarskich (pH = 6.7-7.2, Conductivity = 6.71-6.84 mS/cm, Salinity = 3581-3648 mg NaCl/dm3, Colour = 560-4710 mg Pt/dm3, COD = 2220-2290 mg O₂/dm3, TOC = 394-551 mg/dm3) z zastosowaniem K₂FeO₄. Badania prowadzono z wykorzystaniem 3 rodzajów ścieków zawierających detergent anionowy (laurylosiarczan sodu, 100 mg/dm3) i różniących się jedynie stężeniem barwnika Acid Green 16 (AG 16). Jako utleniacz zastosowano techniczny K₂FeO₄, który poddano analizie fizykochemicznej (czystość, widmo UV-VIS, charakterystyka powierzchni i skład chemiczny z zastosowaniem metod SEM i EDX). Do planowania i optymalizacji procesu oczyszczania ścieków zastosowano metodę Taguchi dla czterech parametrów wejściowych: pH (2, 7, 12), czasu reakcji (10, 30, 50 min.), stężenia AG 16 (20, 120, 220 mg/dm3) oraz stężenia K₂FeO₄ (25, 125, 225 mg/dm3), dla których wykonano 9 eksperymentów zgodnie z przyjętym planem. Analiza wyników badań pozwoliła na wskazanie optymalnych wartości dla poszczególnych parametrów wejściowych (pH 2, czas 50 min., AG 16=20 mg/dm3, K₂FeO₄ = 125 mg/dm3). W tych warunkach uzyskano wizualne odbarwienie ścieków (AG 16 = 0.4 mg/dm3, ↓98% ), zmniejszenie barwy (66 mg Pt/dm3, ↓88% ) oraz DOC (249 mg/dm3, ↓37%).

Słowa kluczowe

EN

textile wastewater; potassium ferrate(VI); Acid Green 16; Taguchi method

PL

ścieki tekstylne; nadsiarczan potasu; metoda Taguchi

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2018
• Tom: Vol. 26, no. 3 (129)
• Strony: 104--109
• Opis fizyczny: Bibliogr. 37 poz., rys., tab.

Twórcy

autor

Thomas M.

• Chemiqua Company, Skawińska Str. 25/1, 31-066 Kraków, Poland

autor

Barbusiński K.

• Silesian University of Technology, Institute of Water and Wastewater Engineering, ul. Konarskiego 18, 44-100 Gliwice, Poland

autor

Kliś S.

• The Central Mining Institute, Katowice, Poland

autor

Szpyrka E.

• University of Rzeszów, Faculty of Biotechnology, ul. Pigonia 1, 35-310 Rzeszów, Poland

autor

Chyc M.

• State Higher Vocational School in Tarnów, Institute of Mathematical and Natural Science, ul. Mickiewicza 8, 33-100 Tarnów, Poland

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).