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Corrosion behavior of lead-free SAC-type solder alloys in liquid media

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
New lead-free solders are developed for electronic assemblies as a replacement for traditional Pb-containing alloys. The main goal of this study was to investigate the corrosion resistance of ternary Sn–Ag–Cu (SAC) alloys in the air-saturated aqueous solutions of NaCl (including sea water) and containing NO3−, SO42−, Cl− ions of concentration equivalent to those in acid rains. The Atomic Absorption Spectrometry (AAS) was used to determine Ag, Cu and Sn concentrations in the corrosive media. The corrosion potential and current were obtained using the potentiodynamic polarization technique. Corrosion resistance experiments of Sn–Ag–Cu alloys with the potentiodynamic method revealed that the solders were considerably resistant to corrosion in the liquid media used. The eutectic composition alloy was characterized by a higher resistance than the near eutectic one despite very small differences in the chemical composition. Corrosion rate during spontaneous dissolution was considerably lower than that derived from the potentiodynamic experiments because of blocking the reaction surface with corrosion products.
Rocznik
Strony
206--213
Opis fizyczny
Bibliogr. 18 poz., rys., tab., wykr.
Twórcy
  • Institute of Metallurgy and Materials Science, Polish Academy of Sciences, Poland
autor
  • Institute of Metallurgy and Materials Science, Polish Academy of Sciences, Poland
autor
  • Institute of Metallurgy and Materials Science, Polish Academy of Sciences, Poland
Bibliografia
  • [1] Directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment, Directive 2002/95/EC, Official Journal of the European Union (2003), 13 February 2003.
  • [2] K. Zeng, K.N. Tu, Six cases of reliability of Pb-free solder joints in electronic packaging technology, Materials Science and Engineering R 38 (2002) 55–105.
  • [3] C. Schmetterer, H. Ipser, J. Peaece, Handbook of properties of SAC Solders and Joints, ELFNET COST 531 Lead Free Solders, COST Office 2 (2008).
  • [4] Directive on the protection of groundwater against pollution caused by certain dangerous substances, Directive 80/68/EEC, Official Journal of the European Union L 020 (1980) 0043–0048, 26/01/1980.
  • [5] A. Kroupa, A.T. Dinsdale, A. Watson, J. Vrestal, J. Vizdal, A. Zemanova, The development of the COST 531 lead-free solders thermodynamic database, Journal of the Minerals 59 (7) (2007) 20–25.
  • [6] H. Westphal, et al., Environmental Impacts of Adhesives and Solders, Danish Toxicology Centre, 1998, ISBN: 87-7398- 123-0.
  • [7] Creep and Failure of Lead-free Solder Alloys, J.G.A. Theeven report number MT02.03, Eindhoven University of Technology Faculty of Mechanical Engineering Materials Technology Group (2002).
  • [8] B. Walna, J. Siepak, Research on the variability of physical-chemical parameters characterizing acidic atmospheric precipitation at the Jeziory Ecological Station in the Wielkopolski National Park (Poland), Science of the Total Environment 239 (1999) 173–187.
  • [9] A.P. Yadav, A. Nishikata, T. Tsuru, Oxygen reduction mechanism on corroded zinc, Journal of Electroanalytical Chemistry 585 (2005) 142–149.
  • [10] C.I. House, G.H. Kelsall, Potential—pH diagrams for the Sn/ H2O–Cl system, Electrochimica Acta 29 (1984) 1459–1464.
  • [11] S.D. Kapusta, N. Hackerman, Anodic passivation of tin in slightly alkaline solutions, Electrochimica Acta 25 (1980) 1625–1639.
  • [12] M.C. Zhao, M. Liu, G.-L. Song, A. Atrens, Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41, Corrosion Science 50 (2008) 3168–3178.
  • [13] F. Rosalbino, E. Angelini, G. Zanicchi, Corrosion behaviour assessment of lead-free Sn–Ag–M (M = In, Bi, Cu) solder alloys, Materials Chemistry and Physics 109 (2008) 386–391.
  • [14] V.G. Levich, Physicochemical Hydrodynamics, Prentice Hall, New Jersey, 1962.
  • [15] Z. Zembura, A. Fuliński, Rotating-disk investigations of kinetics of metal dissolution: case of two independent dissolution reactions, Electrochimica Acta 10 (1965) 859–865.
  • [16] K.V. Rybalka, L.A. Beketaeva, A.D. Davydov, Electrochemical behavior of stainless steel in aerated NaCl solutions by electrochemical impedance and rotating disk electrode methods, Russian Journal of Electrochemistry 42 (4) (2006) 370–374.
  • [17] F.-T. Heakal, A.M. Fekry, A.A. Ghoneim, Corrosion characterization of new tin-silver binary alloys in nitric acid solutions, Corrosion Science 50 (2008) 1618–1626.
  • [18] U.S. Mohanty, K.L. Lin, The effect of alloying element gallium on the polarization characteristics of Pb-free Sn–Zn–Ag–Al– XGa solders in NaCl solution, Corrosion Science 48 (3) (2006) 662–678.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0fefaad3-b426-4562-8e5c-2939fb7414c8
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