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Halloysite was intercalated by the mechanochemical technique from dry components. The process efficiency of 50% was achieved. The obtained intercalate differed from the material acquired using an aqueous solution of potassium acetate. The material was analyzed employing electron microscopy, thermogravimetry, X-ray powder diffraction, and dielectric spectroscopy. It was found that the molecules and/or ions present in the interlayer spaces retain some possibility of movement. This property of the material is promising for potential application as low expensive absorbers of electromagnetic radiation.
Rocznik
Tom
Strony
235--243
Opis fizyczny
Bibliogr. 28 poz., rys., wykr., wz.
Twórcy
autor
- Faculty of Chemistry, University of Wrocław, Joliot-Curie 14. 50-383 Wrocław, Poland
autor
- Faculty of Chemistry, University of Wrocław, Joliot-Curie 14. 50-383 Wrocław, Poland
autor
- Faculty of Chemistry, University of Wrocław, Joliot-Curie 14. 50-383 Wrocław, Poland
autor
- Faculty of Chemistry, University of Wrocław, Joliot-Curie 14. 50-383 Wrocław, Poland
autor
- Faculty of Chemistry, University of Wrocław, Joliot-Curie 14. 50-383 Wrocław, Poland
Bibliografia
- ADAMCZYK, M., 2014. Dielektryczne właściwości haloizytu i jego interkalowanych pochodnych. University of Wrocław.
- ADAMCZYK, M., ROK, M., WOLNY, A., ORZECHOWSKI, K., 2014. Dielectric properties of halloysite and halloysiteformamide intercalate. Journal of Applied Physics 115, 024101.
- CHEN, B., LIU, J., CHEN, H., WU, J., 2004. Synthesis of Disordered and Highly Exfoliated Epoxy/Clay Nanocomposites Using Organoclay with Catalytic Function via Acetone−Clay Slurry Method. Chemistry of Materials 16, 4864–4866.
- CHENG, H., LIU, Q., YANG, J., MA, S., FROST, R.L., 2012. The thermal behavior of kaolinite intercalation complexes - A review. Thermochimica Acta 545, 1–13.
- CHENG, H., LIU, Q., YANG, J., ZHANG, J., FROST, R.L., DU, X., 2011. Infrared spectroscopic study of halloysitepotassium acetate intercalation complex. Journal of Molecular Structure 990, 21–25.
- COSTA, F.R., WAGENKNECHT, U., HEINRICH, G., 2007. LDPE/Mg-Al layered double hydroxide nanocomposite: Thermal and flammability properties. Polymer Degradation and Stability 92, 1813–1823.
- FRANCO, F., CRUZ, M.D.R., 2004. Factors influencing the intercalation degree ('reactivity’) of kaolin minerals with potassium acetate, formamide, dimethylsulphoxide and hydrazine. Clay Min. 39, 193–205.
- FROST, R.L., 1997. Intercalation of Halloysite: A Raman Spectroscopic Study. Clays and Clay Minerals 45, 551–563.
- FROST, R. L., KRISTOF, J., HORVATH, E., KLOPROGGE, J.T., 2000a. Rehydration and Phase Changes of Potassium Acetate-Intercalated Halloysite at 298 K. Journal of Colloid and Interface Science 226, 318–327.
- FROST, R.L., KRISTOF, J., HORVATH, E., KLOPROGGE, J.T., 1999. Deintercalation of dimethylsulphoxide intercalated kaolinites – a DTA/TGA and Raman spectroscopic study. Thermochimica Acta 327, 155–166.
- FROST, R. L., KRISTOF, J., MAKO, E., KLOPROGGE, J.T., 2000b. Modification of the hydroxyl surface of potassium acetate intercalated halloysite between 25 and 300 degrees C. Am. Miner. 85, 1735–1743.
- FROST, R. L., KRISTOF, J., MAKO, E., KLOPROGGE, J.T., 2000. Modification of the Hydroxyl Surface in PotassiumAcetate-Intercalated Kaolinite between 25 and 300 °C. Langmuir 16, 7421–7428.
- FROST, R.L., KRISTOF, J., PAROZ, G.N., TRAN, T.H., KLOPROGGE, J.T., 1998. The role of water in the intercalation of kaolinite with potassium acetate. Journal of Colloid and Interface Science 204, 227–236.
- FROST, R.L., LOCOS, O.B., KRISTOF, J., KLOPROGGE, J.T., 2001. Infrared spectroscopic study of potassium and cesium acetate-intercalated kaolinites. Vibrational Spectroscopy 26, 33–42.
- GARRIDO-RAMIREZ, E.G., THENG, B.K.G., KORA, M.L., 2010. Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions — A review. Applied Clay Science 47, 182–192.
- HOFMANN, U., ENDELL, K., WILM, D., 1934. Radiographic and colloid-chemical investigations of clay. Angewandte Chemie 47, 0539–0547.
- JOSHI, G.V., KEVADIYA, B.D., PATEL, H.A., BAJAJ, H.C., JASRA, R.V., 2009. Montmorillonite as a drug delivery system: Intercalation and in vitro release of timolol maleate. International Journal of Pharmaceutics 374, 53–57.
- JOUSSEIN, E., PETIT, S., CHURCHMAN, J., THENG, B., RIGHI, D., DELVAUX, B., 2005. Halloysite clay minerals — a review. Clay Minerals 40, 383–426.
- KIŁACZ, K., ORZECHOWSKI, K., 2019. Nontronite and intercalated nontronite as effective and cheap absorbers of electromagnetic radiation. Dalton Trans. 48, 3874–3882.
- LEGOCKA, I., WIERZBICKA, E., AL-ZAHARI, T.M.J., OSAWARU, O., 2013. Influence of halloysite on the structure, thermal and mechanical properties of polyamide 6. Polimery 58, 24–32.
- LIN, F.H., LEE, Y.H., JIAN, C.H., WONG, J.M., SHEIH, M.J., WANG, C.Y., 2002. A study of purified montmorillonite intercalated with 5-fluorouracil as drug carrier. Biomaterials 23, 1981–1987.
- MITRA, G.B., BHATTACHERJEE, S., 1975. The structure of halloysite. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 31, 2851–2857.
- PEREIRA, C.M.C., HERRERO, M., LABAJOS, F.M., MARQUES, A.T., RIVES, V., 2009. Preparation and properties of new flame retardant unsaturated polyester nanocomposites based on layered double hydroxides. Polymer Degradation and Stability 94, 939–946.
- ROBINSON, D.A., 2004. Measurement of the solid dielectric permittivity of clay minerals and granular samples using a time domain reflectometry immersion method. Vadose Zone Journal 3, 705–713.
- SONG, S., SONG, L., ZHANG, Y., CHEN, S., LI, Q., GUO, Y., DENG, S., SI, S., XIONG, C., 2014. Lauric acid/intercalated kaolinite as form-stable phase change material for thermal energy storage. Energy 76, 385–389.
- STOCH, L., 1974. Minerały ilaste. Wydawnictwa Geologiczne, Warszawa.
- TARI, G., BOBOS, I., GOMES, C.S.F., FERREIRA, J.M.F., 1999. Modification of Surface Charge Properties during Kaolinite to Halloysite-7Å Transformation. Journal of Colloid and Interface Science 210, 360–366.
- YUAN, P., TAN, D., AANNABI-BERGAYA, F., YAN, W., FAN, M., LIU, D., HE, H., 2012. Changes in Structure, Morphology, Porosity, and Surface Activity Of Mesoporous Halloysite Nanotubes Under Heating. Clays Clay Miner. 60, 561–573.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0fa01f9f-982e-440a-b1ec-ded0f55f8496