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Application of Thermal Analysis and Trough Test for Determination of the Fire Safety of Some Fertilizers Containing Nitrates

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The studies on how a fire on board accidents may be prevented have been actively carried out at both the national and international levels. This paper provides an outlook on fire safety assessment concerning nitrates fertilizers in sea transport. The investigation was aimed at comparison two methods of classification and assignment to a packing group of solid fertilizers of class 5.1 of International Maritime Danger Goods Code. First research was conducted in accordance with the test method described in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Test and Criteria, Part III, 34.4.1 “Test for oxidizing solids”. The second method was the differential thermal analysis (DTA) where the basis was the determination the temperature change rate during thermal reaction. According to two used tests, the investigated fertilizers belong to 5.1 class and require to packaging group III of the International Maritime Danger Goods Code. The DTA method gives more quantitative information about fire risk on the ship than method recommended in International Maritime Danger Goods Code.
Twórcy
  • Department of Chemistry and Industrial Commodity Science, Poland
autor
  • Department of Chemistry and Industrial Commodity Science, Poland
Bibliografia
  • 1. Appendix A in the BC Code 2001: London, Printed by International Maritime Organization.
  • 2. Appendix B in the BC Code 2001: London, Printed by International Maritime Organization
  • 3. Bruke R.., Hazardous Materials Chemistry for Emergency Re-sponders. 2003, Bocca Ratton-London-New York-Washington. :Lewis Publishers CRC Press Company,
  • 4 Ciesielski W., Tomasik P. Starch radicals. Part III: Semiartifi-cal complexes. 1998. Z. Lebensm. Untes. Forsch. A. 207:pp. 292-298.
  • 5 Ciesielski W., Tomasik P. Baczkowicz M. Starch radicals. Part IV: Thermoanalitical studies. 1998. Z. Lebensm. Untes. Forsch. A. 207:pp. 299-303.
  • 6 Code of Safe Practice for Solid Bulk Cargoes (BC Code), 2004: London, Printed by International Maritime Organiza-tion.
  • 7 International Maritime Dangerous Goods Code (IMDG Code) 2004:London, Printed by International Maritime Organiza-tion.
  • 8. Kwiatkowska-Sienkiewicz K., Barcewicz K., Rojewski L., 2006; Application of thermal analyze in studies on sea transport safety of oxidizers (3). Proc.The 15 th Symposium of IGWT, Kyiv, Ukraine , pp. 1182-1186.
  • 9. Kwiatkowska-Sienkiewicz K., 2008; Application of thermal analyze in studies on levels of separation of oxidizers from ammonium chlorate(VII).Proc.The 16 th Symposium of IGWT, Suwon, Korea, pp. 737-739.
  • 10. Kwiatkowska-Sienkiewicz K., Barcewicz K.: 2001;The new criteria of separation of oxiedizers from ammonium salts. Proc. European Safety & Reliability Conference, ESREL, Turyn, Italy, Ed. Technical University in Turyn, pp.959-963.
  • 11. Manual of Tests and Criteria Part III, 34.4.1.: 2001: London, United Nations Recommendations on the Transport of Dangerous Goods.
  • 12. Michałowski Z., Barcewicz K., 1997. A new proposal for as-signment criteria fo the oxidizers into 5.1 class and packag-ing categories of IMDG Code. Polish Maritime Research, , 3 (13) 4-25.
  • 13. Michałowski Z., Barcewicz K. 1998. Derywatograficzne bada-nia przebiegu reakcji niektórych utleniaczy zaliczanych do do klasy 5.1 z solami amonowymi. Proc. „Problemy ła-dunkoznawcze w obrocie morskim”, Gdynia, Poland. pp. 105-108.
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