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Modification of PVC compounds with butadiene-acrylonitrile elastomers

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Wybrane pełne teksty z tego czasopisma
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Języki publikacji
EN
Abstrakty
EN
Purpose: The purpose of the paper is to present the research programme on influence of acrylonitrile-butadiene copolymers on properties of plasticized polyvinylchloride as window gaskets material. Design/methodology/approach: Short literature review concerning application of modified PVC as gasket material was presented. In experimental part two types of acrylonitrile-butadiene copolymers were used as elastomeric plasticizers. Compounds with fifteen different levels of modifiers content (up to 25% by weight) were prepared and tested. Additionally three commercial compounds were tested as reference formulations. The following test were performed: Shore hardness, short-term and long-term elastic recovery, tensile strength, elongation at break and migration of plasticizers from gasket material to unplasticized PVC. Findings: Application of acrylonitrile-butadiene copolymers as PVC modifier enhanced many properties essential for window gasket materials such as long-term and short term elastic recovery, tensile strength and elongation at break. At the same time addition of these elastomers did not change migration of other plasticizers contained in gasket material. Obtained results indicated that among tested compounds best properties as gasket material exhibited plasticized PVC with 23% of acrylonitrile-butadiene copolymer Chemigum P83. Reference commercial compounds exhibited worse performance properties than compounds with this acrylonitrile-butadiene copolymer. Practical implications: Research programme allowed to elaborate plasticized PVC compounds modified with acrylonitrile-butadiene copolymer that can be industrially applied for PVC window gaskets. Originality/value: Obtained results are of scientific and practical value. Research programme allowed to investigate the influence of elastomeric modifiers on plasticized PVC properties. Research results are also of practical importance.
Rocznik
Strony
141--144
Opis fizyczny
Bibliogr. 15 poz., wykr.
Twórcy
autor
  • Division of Metal and Polymer Materials Processing, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Division of Metal and Polymer Materials Processing, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
Bibliografia
  • [1] K. Flaga, Advances in materials applied in civil engineering, J. Mater. Proc. Technol. 106 (2000) 173-183.
  • [2] F. Kamisli, C. Turan, A study on usability of magnesium oxide with titanium dioxide in PVC door and window profiles, J. Mater. Proc. Technol. 159 (2005) 40-47.
  • [3] S. Ramakrishna, Z. Ming Huang, H.M. Yew, Development of a novel flexible composite material, J. Mater. Proc. Technol. 89-90 (1999) 473-477.
  • [4] J.R. Pena, M. Hidalgo, C. Mijangos, Plastification of poly(vinyl chloride) by polymer blending, J. Appl. Polym. Sci. 75 (2000) 1303-1312.
  • [5] D. Dickmann, Plasticizers, Modern Plastics Encyclopedia’91 p. 202-208, McGraw Hill, New York 1990.
  • [6] G. Wypych, Handbook of Plasticizers, ChemTec Publishing, 2004.
  • [7] G. Wu, J. Zhao, H. Shi, H. Zhang, The influence of core-shell structured modifiers on the toughness of poly(vinyl chloride) grafted copolymer of polybutadiene and polymethyl methacrylate, European Polymer J., 40 (2004) 2451-2456.
  • [8] M. Rahman, C.S. Brazel, The plasticizer market an assessment of traditional plasticizers and research trends to meet new challenges, Progress in Polym. Sci., 29 (2004) 1223-1248.
  • [9] A. Hassan, B. Hawotrh, Impast properties of acrylate rubber – modified PVC: Influence of temperature, J. Mater. Proc. Technol. 172 (2006) 341-345.
  • [10] M. Obłój-Muzaj, B. Świerz-Motysia, B. Szabłowska,Polyvinyl chloride, WNT, Warszawa 1997 (in Polish).
  • [11] S.H. Zhu, C.M. Chan, S.C. Wong, Y.W. Mai, Mechanical properties of PVC/SBR blends compatibilized by acrylonitrile-butadiene rubber and covulcanization, Polym. Eng. Sci., 39 (1999) 1998-2006.
  • [12] L. Zhou, X. Wang, Y. Lin, J. Yang, Q. Wu, Comparison of the toughening mechanisms of poly(vinyl chloride)/ chlorinated polyethylene and poly(vinyl chloride)/ acrylonitrile-butadiene-styrene copolymer blends, J. Appl. Polymer Sci. 90 (2003) 916-924.
  • [13] A. de Zarraga, S. Villanueva, M.E. Muñoz, R. Obeso, J.J. Peña, B. Pascual, A. Santamaría, Ternary Blends to Improve Heat Distortion Temperature and Rheological Properties of PVC, Macromolecular Mat. and Eng. 289 (2004) 648-652.
  • [14] B. Jurkowski, B. Jurkowska, Preparing of polymeric compounds WNT Warszawa 1995 (in Polish).
  • [15] N.R. Manoj, P.P. De An investigation of the chemical interactions in blends of poly(vinyl chloride) and nitrile rubber during processing, Polymer 39 (1998) 733-741.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0c966f0b-8af1-440e-a49c-894a5445d6e4
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