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Ecotoxicity of ionic liquids as lubricants

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EN
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EN
In this article there is discussed the influence of ionic liquids on natural environment on the basis of detailed analysis of the literature information and the results of the Authors' researches carried out within the framework of the development and research project no. PBR/15-249/2007/WAT-OR00002904 financed by Ministry of Science and Higher Education during 2007-2011. The literature information about toxic features of ionic liquids is very skimpy, but the detailed analysis of it and the results of our own researches allow us to say that not all ionic liquids should be treated as fully environmentally friendly substances. Among these substances, there are non-toxic and moderately toxic but there are very toxic liquids, too. Therefore, uncritical rating all ionic liquids among Green Chemistry is inappropriate. The test results of ionic liquids ecotoxicity were compared with the results obtained for standard oils used at lubrication technologies, particularly at motorization. All reference oils, according to EU classification, were non-toxic. The tests were carried out in accordance with OECD 202 European normative document, which recommends carrying out the tests for Daphnia Magna crustaceans. There were carried out: acute immobilization tests to Daphnia Magna, calculation of the effective concentrations EC50-t and evaluation of ionic and reference liquids toxicity with regard to used bioindicators
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Twórcy
  • Military University of Technology, Faculty of Mechanical Engineering Gen. S. Kaliskiego Street 2, 00-908 Warsaw, Poland tel. +48 261 837384, 261 839565
  • Military University of Technology, Faculty of Mechanical Engineering Gen. S. Kaliskiego Street 2, 00-908 Warsaw, Poland tel. +48 261 837384, 261 839565
  • Warsaw University of Technology, Faculty of Environmental Engineering Pl. Politechniki 1, 00-661 Warsaw, Poland
autor
  • Tribochemistry Consulting, Salt Lake City, Utah 84117, USA
Bibliografia
  • [1] Kałdoński, T. (Ed.), Porowate łożyska ślizgowe nowej generacji – badania i prognozy (New generation porous sliding bearings – research and prognosis). Military University of Technology, Warsaw, 2013.
  • [2] Wassercheid, P., Welton, T. (Eds.), Ionic Liquid in Synthesis. Second, Completely Revised and Enlarged Edition, Wiley – WCH Verlag GmbH&Co. KgaA, Weinhein, 2008.
  • [3] Swatlosky, R. P., Holbrey, J. D., Rogers, R. D., Ionic liquids are not always green hydrolysis of 1-
  • butyl-3-methylimidazolium hexafluorophosphate. Green Chemistry, 5 (4), pp. 361-363, 2003. [4] Keskin, S., Kayrak-Talay, D., Akman, U., Hortaęsu, O., A review of ionic liquids toward superficial fluids application. Journal of Superficial Fluids, Vol. 43, pp. 150-180, 2007.
  • [5] Magin, E. J., Research. Ionic Liquids, www.nd.edu/red/Research/IL_toxicology.html.
  • [6] Wells, A. S., Coombe, V. T., On the freshwater ecotoxicity and biodegradation properties of some common ionic liquids. Org. Process Res. Dex., 10, pp. 794-798, 2006.
  • [7] Swatlosky, R. P., Holbrey, J. D., Memon, S. B., Caldwell, G. A., Caldwell, K. A., Rogers, R. D., Using Caenorhabditis Elegans to probe toxicity of 1-alkyl-3-methylimidazolium chloride based ionic liquids. Chem. Commun., pp. 668-669, 2004.
  • [8] Bernott, R. J., Kennedy, E. E., Lamberti, G. A.: Effects of ionic liquids on the survival movement and feeding behavior of the freshwater snail. Physa Acuta Environ. Toxicol. Chem., 24, pp. 1759-1765, 2005.
  • [9] Landry, T. D., Brooks, K., Poche, D., Wollhiser, M., Acute toxicity profile of 1-butyl-3-methylimidazolium chloride. Bull. Enviran. Contam. Toxical., 74, pp. 559-565, 2005.
  • [10] Pretti, C., Chiappe, C., Piraccini, D., Gregori, M., Aramo, F., Monnia, G., Intorre, L., Acute toxicity of ionic liquids to the Zebra Fish (Danio Rerio). Green Chem., 8, pp. 238-240, 2006.
  • [11] Maase, M. (Basf), Oral presentation COIL meeting, 19-22 Juli 2005, Salzburg; BASF Material Safety Data Sheets, www.basionics.com.
  • [12] Patent specification no. PL203064, 31.08.2009 WUP 08/09: Imidazolowe ciecze jonowe i sposób wytwarzania imidazolowych cieczy jonowych (Imidazole ionic liquids and the way of producing imidazole ionic liquids), 2009.
  • [13] Chemical Reagents J.S.C. Product information POCH S.A., Gliwice-Poland.
  • [14] Sigma-Aldrich Product information: ChemFiles-Enbling Technologies-Ionic Liquids, Vol. 5, № 6, 2005.
  • [15] Solvay Solexis – Fomblin PFPE Lubrications Product information.
  • [16] Oecd 2002. Daphnia Sp., Acute Immobilisation Test and Reproduction Test – part I, 2004.
  • [17] Łebkowska, M., Załęska-Radziwiłł, M., Słomczyńska, B., Toksykologia środowiska – ćwiczenia laboratoryjne (Environmental toxicology – laboratory exercises). Outhouse Publishing of Warsaw University of Technology, Warsaw, 2004.
  • [18] Weber, E., Grundniss der biologischen statistic für naturwissen schaftler land wirte und medizine. VEB Fischer Verlag, Jena, 1972.
  • [19] Załęska-Radziwiłł, M.: Badania ekotoksykologiczne w procesie ekologicznej oceny ryzyka w środowisku wodnym (Ecotoxicological researches in the process of ecological risk assessment in water environment). Inżynieria Środowiska (Environmental Engineering), 52, p. 1-198, 2007.
  • [20] USEPA Directive. Technical support document for water quality – based toxic control EPA/505/2-90-001. Washington D.C. Office of Water, US Environmental Procetion Agency, 1999.
  • [21] EU Directive. Commission of the European Communities. Technical guidance document in support of Commission Directive 93/67/EEC on risk assessment for existing substances. Part II-Environmental Risk Assessment, Brussels, Belgium, 1996.
  • [22] Kałdoński, T. J., Badania i ocena alkoksymetyloimidazolowych cieczy jonowych jako nowych smarów dla stalowych węzłów tribologicznych (Testing and evaluation of alkoxymethylimidazolium ionic liquids as new lubricants for the steel tribological nodes) – Doctor's thesis, Military University of Technology, Warsaw, 2012.
  • [23] Kałdoński, T. J., Ciecze jonowe – perspektywiczne oleje smarujące. (Ionic liquids – perspective lubricating oils). Military University of Technology, Warsaw, 2014.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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