Reduction and Biosorption of Cr(VI) from Aqueous Solutions by Acid- -Modifi ed Guava Seeds: Kinetic and Equilibrium Studies

• Autorzy: Ortíz-Gutiérrez Marel , Alfaro-Cuevas-Villanueva Ruth , Martínez-Miranda Verónica , Hernández-Cristóbal Orlando , Cortés-Martínez Raúl

Identyfikatory

DOI

10.2478/pjct-2020-0037

• Języki publikacji: EN

Abstrakty

EN

The use of guava seeds (GS) and acid-modified guava seeds (MGS) for the removal of Cr(VI) from aqueous solutions was investigated. Batch-type experiments were performed with Cr(VI) aqueous solutions and biosorbents to determine the kinetic and equilibrium sorption parameters. Results indicated that GS and MGS were capable of reducing and remove Cr(VI) from solutions, but the reduction was only observed at some experimental conditions. Infrared analysis showed that several functional groups were involved in the reduction, and biosorption of Cr(VI), particularly alcohol, phenolic, carboxylic, and methoxymethyl structures. The mechanisms of reduction and biosorption depended upon the type of biosorbent, pH, and temperature of the system. The pseudo-second-order kinetic model describes the kinetic sorption data, and the Langmuir-Freundlich (L-F) model describes the isotherm data in most cases. Significantly high total chromium biosorption capacities were obtained. Acid modification of guava seeds improves chromium biosorption performance.

Słowa kluczowe

EN

Guava seeds; chromium reduction; biosorption; isotherms

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2020
• Tom: Vol. 22, nr 4
• Strony: 36--47
• Opis fizyczny: Bibliogr. 54 poz., rys., tab., wykr., wz.

Twórcy

autor

Ortíz-Gutiérrez Marel

• Master of Science Program in Environmental Engineering, Faculty of Biology, Michoacan University of Saint Nicholas of Hidalgo. C.U., C.P. 58060 Morelia, México

autor

Alfaro-Cuevas-Villanueva Ruth

• Earth Sciences Research Institute, Michoacan University of Saint Nicholas of Hidalgo, Edif. U, C.U., C.P. 58060, Morelia, Michoacán, México

autor

Martínez-Miranda Verónica

• Inter-American Institute of Water Technology and Sciences, Autonomous University of the State of Mexico. Carretera Toluca-Atlacomulco km 14.5, Unidad San Cayetano, C.P. 50200, Toluca, Estado de México, México

autor

Hernández-Cristóbal Orlando

• National School of Higher Studies (ENES), Morelia Unit, National Autonomous University of Mexico. Antigua Carretera a Pátzcuaro 8701, col. Ex Hacienda San José de la Huerta, Morelia, México.

autor

Cortés-Martínez Raúl

• Faculty of Chemistry Pharmacobiology, Michoacan University of Saint Nicholas of Hidalgo. Tzintzuntzan 173 Col. Matamoros, C.P. 58240, Morelia, Michoacán. México

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Uwagi

This work was funded by Coordinación de la Investigación Científica-UMSNH (grant CIC-UMSNH-2019).

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).