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Effect of N-carboxybutyl chitosan on the flotation separation of apatite from dolomite

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
With high-grade apatite resources exhausted and economic development, enhancing the apatite quality from calcium gangue such as dolomite has a great significance for production. However, it is difficult to separate apatite from dolomite effectively due to the similar surface properties. In this study, the N-carboxybutyl chitosan (CBC) was tested as a potential selective depressant to separate apatite from dolomite in the sodium oleate (NaOL). Flotation results of single mineral and artificially mixed mineral confirmed the selective depression effect of CBC. The depression mechanism of CBC was investigated using wettability analysis, Fourier Transform Infrared (FTIR), and X-ray Photoelectron Spectroscopy (XPS) analyses. The results indicated that the CBC adsorption quantity and intensity on the dolomite surface more than that on the apatite surface, which was due to CBC absorbed on apatite surface by hydrogen bonding, while absorbed on dolomite surface mainly through chemical chelating between Ca on the mineral surface and -COO- on the depressant. These adsorption differences led to the flotation separation of the two minerals.
Rocznik
Strony
27--35
Opis fizyczny
Bibliogr. 21 poz., rys. kolor.
Twórcy
autor
  • School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
  • Quanzhou Institute of Equipment Manufacturing, Haixi Institutes, Chinese Academy of Sciences, Quanzhou, Fujian, 362000, PR China
autor
  • Zhanggong District Sixteenth Nursery, Ganzhou, Jiangxi 341000, China
autor
  • School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
  • Quanzhou Institute of Equipment Manufacturing, Haixi Institutes, Chinese Academy of Sciences, Quanzhou, Fujian, 362000, PR China
autor
  • Quanzhou Institute of Equipment Manufacturing, Haixi Institutes, Chinese Academy of Sciences, Quanzhou, Fujian, 362000, PR China
autor
  • Quanzhou Institute of Equipment Manufacturing, Haixi Institutes, Chinese Academy of Sciences, Quanzhou, Fujian, 362000, PR China
autor
  • School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
  • School of Architectural and Surveying & Mapping Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
Bibliografia
  • ASLANI, S., SAMIM, H.R., ARIANPOUR. F., 2010. Beneficiation of Iranian magnesite ores by reverse flotation process and its effects on shaped and unshaped refractories properties. Bull. Mater. Sci. 33, 697–705.
  • BOTERO, A.E.C., TOREM, M.L.L., MESQUITA, M.S., 2007. Fundamental studies of Rhodococcus opacus as a biocollector of calcite and magnesite. Minerals Engineering. 20, 1026–1032.
  • CAO, J., TIAN, X.D., LUO, Y.C., HU, X.Q., XU, P.F., 2017. The effect of graphene oxide on the slime coatings of serpentine in the flotation of pentlandite. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 522, 621–627.
  • CHEN, W., FENG, Q., ZHANG, G., YANG, Q., & ZHANG, C., 2017. The effect of sodium alginate on the flotation separation of scheelite from calcite and fluorite. Miner. Eng. 113, 1-7.
  • DONG, L., JIAO, F., QIN, W., LIU, W., 2019. Selective flotation of scheelite from calcite using xanthan gum as depressant. Minerals Engineering. 138,14-23.
  • FENG, B., ZHONG, C.H., ZHANG, L.Z., GUO, Y.T., WANG, T., HUANG, Z.Q., 2020. Effect of surface oxidation on the depression of sphalerite by locust bean gum. Minerals Engineering. 146, 106142.
  • GENCE, N., Wetting behavior of magnesite and dolomite surfaces. Applied Surface Science. 252, 3744–3750.
  • KATIA, S.C.R., SILVA, S.R.C., FERREIRA, E.I., BRUNS, R.E., 2005. 32 Factorial design and response surface analysis optimization of N-carboxybutyl chitosan synthesis. Carbohydr. Polym., 59.1, 37-42.
  • LIU, C., CHEN, Y.F., SONG, S.S., LI, H.Q., 2018. The effect of aluminum ions on the flotation separation of pentlandite from lizardite. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 555, 708–712.
  • LIU, C., ZHANG, W., LI, H., 2019. Selective flotation of apatite from calcite using 2 phosphonobutane-1,2,4-tricarboxylic acid as depressant, Minerals Engineering. 136, 62-65.
  • LIU, X., RUAN, Y., LI, C., CHENG, R., 2017. Effect and mechanism of phosphoric acid in the apatite/dolomite flotation system. International Journal of Mineral Processing. 167, 95-102.
  • LUO, N., WEI, D.Z., SHEN, Y.B., HAN, C., ZHANG, C.E., 2017. Elimination of the adverse effect of calcium ion on the flotation separation of magnesite from dolomite. Mineral, 7, 150.
  • LUO, X.M., YIN, W.Z., WANG, Y.F., SUN, C.Y., MA, Y.Q., LIU, J., 2016. Effect and mechanism of dolomite with different size fractions on hematite flotation using sodium oleate as collector. Journal of Central South University. 23, 529–534.
  • LV, H.Z., PENG, Z., TONG, X., CHEN, L.Z., CHEN, Y.M., 2017. Pulsating high gradient magnetic separation for purification of quartz. Physicochemical Problems of Mineral Processing. 53, 617-627.
  • MERMA, A.G., TOREM, M.L., MORAN, J.J.V., MOTE, M.B.M., 2013. On the fundamental aspects of apatite and quartz flotation using a Gram-positive strain as a bioreagent. Minerals Engineering. 48, 61–67.
  • MUZZARELLI, R., WECKX, M., FILIPPINI, O., LOUGH C., 1989. Characteristic properties of N-Carboxybutyl chitosan. Carbohydr. Polym. 11(4), 307-320.
  • PAN, Z., WANG, Y., WEI, Q., CHEN, X., JIAO, F & QIN, W., 2020. Effect of sodium pyrophosphate on the flotation separation of calcite from apatite. Separation and Purification Technology, 116408.
  • SIS, H., CHANDER, S., 2003. Reagents used in the flotation of phosphate ores: a critical review. Minerals Engineering.16, 577–585.
  • SOKOLOVIC, J., STANOJLOVIC, R., & MARKOVIC, Z., 2012. Activation of oxidized surface of anthracite waste coal by attrition. Physicochemical Problems of Mineral Processing, 48(1), 5-18.
  • WANG, J.L., SUN, T.C., 2008. Effects of grain size and regulators on separation of quartz from magnesite. Chinese Journal of Nonferrous Metals, 18.11, 2082-2086.
  • YU, J., GE, Y., GUO, X., GUO, W., 2016. The depression effect and mechanism of NSFC on dolomite in the flotation of phosphate ore. Separation & Purification Technology. 161, 88-95.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0b692894-2711-49c8-b50b-3b617575495e
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