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In this study, Ag-impregnated silica aerogel composites were fabricated via wet impregnation. In this approach, silver salt was reduced with ethylene glycol in the presence of polyvinylpyrrolidone (PVP) at reaction temperature 80°C. PVP was used as a capping agent to protect the Ag nanoparticles (NPs) from agglomeration. Wet impregnation was used to synthesize the Ag/SiO2 composite by combining the reduction of AgNO3 with a silica aerogel slurry. Experimental results showed that the AgNO3 concentration and PVP: AgNO3 ratio had an active influence on the growth of Ag NPs on silica surfaces. The X-ray diffraction (XRD) patterns of the composite material showed no imprints of impurities or parasitic materials except for Ag and SiO2. Scanning electron microscopy (SEM) images revealed that the Ag NPs were well impregnated into the porous silica aerogel structure. It was found that SiO2 aerogel surfaces were homogeneously surrounded by the Ag NPs.
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Czasopismo
Rocznik
Tom
Strony
77--80
Opis fizyczny
Bibliogr. 9 poz., fot., rys.
Twórcy
autor
- Inha University, Department of Materials Science and Engineering, Incheon 22212, Republic of Korea
autor
- Inha University, Department of Materials Science and Engineering, Incheon 22212, Republic of Korea
autor
- Yonsei University, Department of Materials Science and Engineering, Seoul 03722, Republic of Korea
autor
- Inha University, Department of Materials Science and Engineering, Incheon 22212, Republic of Korea
Bibliografia
- [1] M. Park, A. Choi, S. Kim, Study of SiO2 coating and carboxylic surface-modification on Mg-based inorganic fiber by one-step reflux reaction. J. Korean Ceram. Soc. 59, 869-875 (2022). DOI: Https://doi.org/10.1007/s43207-022-00227-8
- [2] M. Park, W. Shim, Y. Kim, A Study of Various SiO2 Coating Control on White TiO2 Pigment for Cosmetic Applications. Powder Mater. 29 (3), 207-212 (2022). DOI: https://doi.org/10.4150
- [3] S. Kim, M.S. Nam, Y.S. Oh, S. Nahm, J. Shin, H. Kim, B.S. Oh, Fabrication of Light Weight Ceramic Insulation Materials by Using Oxide Ceramic Fibers for Reusable Thermal Protection Systems. Powder Mater. 9 (6), 477-484(2022). DOI: https://doi.org/10.4150/KPMI.2022.29.6.477
- [4] Ersoz, O.A. Yildirim, Green Synthesis and Characterization of Ag-doped ZnO nanofibers for photodegradation of MB, RhB and MO dye molecules. J. Korean Ceram. Soc. 59, 655-670 (2022). DOI: https://doi.org/10.1007/s43207-022-00202-3
- [5] Z. Deng, M. Chen, L. Wu, Novel Method to Fabricate SiO2/Ag Composite Spheres and Their Catalytic, Surface-Enhanced Raman Scattering Properties. J. Phys. Chem. C. 111 (31), 11692-11698 (2007). doi: https://doi.org/10.1021/jp073632h
- [6] C. Burda, X. Chen, R. Narayanan, M.A. El-Sayed, Chemistry and Properties of Nanocrystals of Different Shapes. Chem. Rev. 105 (4), 1025-1102 (2005). DOI: https://doi.org/10.1021/cr030063a
- [7] Q.Y. Han, G.A. Li., D.X. Wang, E.J. He, J. Dong, W. Gao, J.N. Li, T.Z. Liu, Z.Y. Zhang, H.R. Zheng, Synthesis of Ag-SiO2 Composite Nanospheres and Their Catalytic Activity. Sci. China Chem. 57, 881-887 (2014). DOI: https://doi.org/10.1007/s11426-014-5068-0
- [8] K.J. Lee, J.M. Lee, K.S. Nam, H. Hwang, Thermal Gelation for Synthesis of Surface-Modified Silica Aerogel Powders. Gels. 7(4), 242 (2021). DOI: https://doi.org/10.3390/gels7040242
- [9] T. Ung, L.M. Liz-Marzán, P. Mulvaney, Redox Catalysis using Ag@ SiO2 Colloids. J. Phys. Chem. B. 103 (32), 6770-6773 (1999). DOI: https://doi.org/10.1021/jp991111r
Uwagi
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2020R1A5A1019131). This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2022M3H4A1A04085322).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0b39850a-0c66-4795-9665-3ca4b45e15b4
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