PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

A comparative study of advanced oxidative processes. Degradation of chlorinated organic compounds in ultrafiltration fractions of kraft pulp bleaching effluent

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Oxidative pretreatment methods such as the Fenton oxidation, ozonation, and photocatalytic treatment have been compared in reducing adsorbable organic halogens (AOX) and chlorophenolic compounds in untreated kraft pulp bleaching effluent. Their efficiency was also studied on effluent ultrafiltration fractions. The Fenton treatment removed all analyzed chlorophenolic compounds from the effluent. Ozonation and photocatalysis appeared to be much less effective methods. The efficiency of the Fenton oxidation appeared to be more pronounced in higher molecular weight effluent fractions. This suggests a novel design, where the filtration stage can be placed after the oxidation, and the high-molecular weight fraction is returned to the Fenton treatment.
Słowa kluczowe
Rocznik
Strony
151--159
Opis fizyczny
Bibliogr. 17 poz., tab., rys.
Twórcy
autor
  • Laboratory of Organic Chemistry, Department of Chemistry, University of Helsinki, A.I. Virtasen Aukio 1, FIN-00560 Helsinki, Finland
autor
  • Laboratory of Applied Chemistry, Department of Chemistry. University of Jyväskylä, Survontie 9, FIN-40500 Jyväskylä, Finland.
autor
  • Laboratory of Applied Chemistry, Department of Chemistry. University of Jyväskylä, Survontie 9, FIN-40500 Jyväskylä, Finland.
autor
  • Laboratory of Applied Chemistry, Department of Chemistry. University of Jyväskylä, Survontie 9, FIN-40500 Jyväskylä, Finland.
Bibliografia
  • [1] HYNNINEN P., Effluent loadings from the forest industry, [in:] P. Hynninen (Ed.), Environmental Control, Fapet Oy, Jyväskylä, Finland, 1998, 30.
  • [2] FISKARI J., On minimum effluent pulp mill concept: water use reduction in the bleach plant, Doctoral Thesis, Åbo Akademi University, Åbo, Finland, 2002.
  • [3] KNUUTINEN J., ALÉN R., Overview of analytical methods in wet-end chemistry, [in:] R. Alén (Ed.), Papermaking Chemistry, Fapet Oy, Jyväskylä, Finland, 2007, 199.
  • [4] ALI M., SREEKRISHNAN T.R., Aquatic toxicity from pulp and paper mill effluents. A review, Adv. Environ. Res., 2001, 5 (2), 175.
  • [5] PÉREZ M., TORRADES F., DOMÈNECH X., PERAL J., Treatment of bleaching kraft mill effluents and poly-chlorinated phenolic compounds with ozonation, J. Chem. Technol. Biotechnol., 2002, 77 (5), 891.
  • [6] MANTZAVINOS D., PSILLAKIS E., Enhancement of biodegrability of industrial wastewaters by chemical oxidation pre-treatment, J. Chem. Technol. Biotechnol., 2002, 79 (5), 431.
  • [7] CATALKAYA E.C., KARGI F., Color, TOC and AOX removals from pulp mill effluent by advanced oxidation processes. A comparative study, J. Hazard. Mater., 2007, 139 (2), 244.
  • [8] CAJAL-MARIÑOSA P., MONONEN T., FISKARI J., TUHKANEN T., A novel concept for monitoring AOX and DOC removal during Fenton treatment of bleached kraft pulp mill effluents, Tappsa J., 2012, (3), 23.
  • [9] ISOAHO J.P., TARKKANEN S., ALÉN R., FISKARI J., Oxidative degradation of AOX in softwood-based kraft mill effluents from ECF bleaching, Nord. Pulp Pap. Res. J., 2012, 27 (4), 707.
  • [10] MARCO A., ESPLUGAS S., SAUM G., How and why combine chemical and biological processes for wastewater treatments, Water Sci. Technol., 1997, 35 (4), 321.
  • [11] CHAMARRO E., MARCO A., ESPLUGAS S., Use of Fenton reagent to improve organic chemical biodegrability, Water Res., 2001, 35 (4), 1047.
  • [12] MÄNTYKOSKI K., PCBs in Processes, Products and Environment of Paper Mills Using Wastepaper as Their Raw Material, Doctoral Thesis, University of Jyväskylä, Jyväskylä, Finland, 2006.
  • [13] RODRÍGUEZ J., CONTRERAS D., PARRA C., FREER J., BAEZA J., DURÁN N., Pulp mill effluent treatment by Fen-ton-type reactions catalyzed by iron complexes, Water Sci. Technol., 1999, 40 (11–12), 351.
  • [14] YEBER M.C., RODRÍGUEZ J., FREER J., ZAROR C., DURÁN N., MANSILLA H.D., Photocatalytic degradation of cellulose bleaching effluent by supported TiO2 and ZnO, Chemosphere, 2000, 41 (8), 1193.
  • [15] KANSAL S.K., SINGH M., SUD D., Studies on TiO2/ZnO photocatalysed degradation of lignin, J. Hazard. Mater., 2008, 153 (1–2), 412.
  • [16] RISTOLAINEN M., ALÉN R., KNUUTINEN J., Characterization of TCF effluents from kraft pulp bleaching. I. Fractionation of hardwood lignin-derived material by GPC and UF, Holzforschung, 1996, 50 (1), 91.
  • [17] KOPRIVANAC N., KUSIC H., AOP as an effective tool for the minimization of hazardous organic pollutants in colored wastewater; Chemical and photochemical processes, [in:] A. Lewinsky (Ed.), Hazardous Materials and Wastewater: Treatment, Removal and Analysis, Nova Science Publishers, Inc., New York 2007, 149.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0b35efe6-081b-4ee2-beb4-d18b5140360e
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.