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The current state of the hydrosphere is largely determined by human anthropogenic activities. Discharge of polluted waste waters into surface water bodies significantly worsens their quality and limits the possibility of safe consumption. One of the biggest sources of increasing surface waters mineralization and hardness is the discharge of spent regeneration solutions of natural waters ion-exchange softening processes, which creates a closed circulation cycle of sodium, calcium and magnesium chlorides. The necessity to reduce the intensity of this cycle and decrease environmental pollution is very actually today. The research of traditional soda-sodium softening technology has shown its low suitability for low and medium capacity systems due to necessity of water heating and subsequently pH adjusting. More acceptable solution was found in using phosphate anions as a precipitant, which ensures high efficiency in removing calcium and magnesium ions at a wide range of temperatures and pH levels. It was found that the solid phase formed during such treatment was difficult to separate from the liquid phase. Using of anionic flocculants was proposed as one of the solutions of this problem, which ensure high efficiency in separating the formed solid particles from water. Proposed technological scheme was designed for implementation as a pre-treatment stage in reverse osmosis systems of low and medium capacity.
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Rocznik
Tom
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194--202
Opis fizyczny
Bibliogr. 22 poz., rys.
Twórcy
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Beresteiskyi Av. 37/4, 03056 Kyiv, Ukraine
Bibliografia
- 1. Alipov A.N., Myahkyy D.D., Yankovska Y.V. 2007. Water supply for the population, industry, and agriculture of Donbass. Use of own resources. Water and Water Treatment Technologies, 4, 17–22. (in Ukrainian)
- 2. Ayrapetyan T.S. 2010. Water management of industrial enterprises: Textbook, Kharkiv: KhNAMG, 280. (in Ukrainian)
- 3. Ciganok L.P., Bybel T.O., Vyshnikin A.B., Vashkevich T.U. 2014. Analytical Chemistry. DNU O. Gonchar, 252. (in Ukrainian)
- 4. Dolinsky A.A., Obodovych O.M., Sydorenko V.V., Lymar A.Yu. 2021. Features of water treatment for boiler systems. Thermophysics and Thermal Energy, 4, 17–24. (in Ukrainian)
- 5. DSanPiN 2.2.4-171-10 “Hygienic requirements for drinking water intended for human consumption”. Order of the Ministry of Health of Ukraine, May 12, 2010, No. 400. (in Ukrainian)
- 6. Fischer L., Hartmann S.S., Maljusch A., D¨aschlein C., Prymak O., Ulbricht M. 2023. The influence of anion-exchange membrane nanostructure on ion transport: Adjusting membrane performance through fabrication conditions. Journal of Membrane Science, 669.
- 7. Goncharuk V.V., Kucheruk D.D., Skubenko V.F., Badekha V.P., Kochkodan V.M. 2001. Prospect of baromembrane desalination of brackish waters in the south of Ukraine. Desalination, 139, 327–331.
- 8. Hasson D., Cornel A. 2017. Effect of residence time on the degree of CaCO₃ precipitation in the presence of an anti-scalant. Desalination, 401, 64–67.
- 9. Homelia I.M., Omelchuk Y.A., Radovenchyk V.M. 2008. Evaluation of the efficiency of KU–2–8 and AqualiteK–100FC cation exchangers for water softening in the presence of iron ions. Ecotechnology and Resource Saving, 3, 62–65. (in Ukrainian)
- 10. Hordiienko K.Yu., Radovenchyk I.V., Krysenko T.V., Radovenchyk V.M. 2022. Efficiency of calcium ion precipitation from diluted aqueous solutions in the form of phosphates. Bulletin of Khmelnytskyi National University. Series: Technical Sciences, 5 (313), 134–140. DOI: 10.31891/2307-5732-2022- 313-5-134-140 (in Ukrainian).
- 11. Hordiienko K.Y., Radovenchyk I.V. 2023. Use of flocculants in water softening processes. Bulletin of NTUU “Igor Sikorsky Kyiv Polytechnic Institute”. Series: Chemical Engineering, Ecology and Resource Saving, 3, 94–100. DOI: 10.20535/2617- 9741.3.2023.288254 (in Ukrainian)
- 12. Li N., Hefferren J.J., Li K. 2013. Quantitative Chemical Analysis. World Scientific Pub Co Inc., 238.
- 13. Nazarenko O.S. 2015. Study of the regeneration process of spent cation exchange resin from a water softening unit in benzene production at the “Zorya” Chemical Plant. Bulletin of the East Ukrainian National University named Volodymyr Dall, 7(224), 32–36. (in Ukrainian)
- 14. Orlov V.O. 2014. Industrial Enterprise Water Supply: Textbook, Kyiv: Znannia, 278. (in Ukrainian).
- 15. Patent No. 154768, Ukraine, CO2F 5/00, CO2F 5/05. Water Softening Method. Radovenchyk I.V., Hordiienko K.Y. Published on December 13, 2023, Bulletin No. 50. (in Ukrainian).
- 16. Radovenchyk I.V., Hordiienko K.Y., Radovenchyk V.M., Krysenko T.V. 2022. Features of chemical precipitation of calcium ions from diluted aqueous solutions. Bulletin of NTUU “Igor Sikorsky Kyiv Polytechnic Institute”. Series: Chemical Engineering, Ecology and Resource Saving, 2, 72–78. DOI: 10.20535/2617-9741.2.2022.260353 (in Ukrainian).
- 17. Radovenchyk I.V., Hordiienko K.Y., Krysenko T.V., Radovenchyk V.M. 2022. Efficiency of magnesium ion removal from water in softening processes. Bulletin of National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Series “Chemical Engineering, Ecology and Resource Saving, 4(21), 33–49. DOI: 10.20535/2617- 9741.4.2022.269815 (in Ukrainian).
- 18. Radovenchyk V.M., Hordiienko K.Y., Radovenchyk I.V., Krysenko T.V. 2022. Use of surfactants for efficient removal of calcium phosphate particles from water. Bulletin of NTUU “Igor Sikorsky Kyiv Polytechnic Institute”. Series: Chemical Engineering, Ecology and Resource Saving, 3, 94–102. DOI: 10.20535/2617-9741.3.2022.265365 (in Ukrainian).
- 19. Shablii T.O., Radovenchyk V.M., Homelia M.D. 2014. Application of New Reagents in Industrial Water Consumption, Kyiv: InfoDruk, 302. (in Ukrainian).
- 20. Trus I.M., Homelia M.D., Krysenko T.V., Vorobyova V.I. 2016. Ion-exchange water purification from nitrates in the development of energy-efficient water demineralization technologies. Strategies for Sustainable Development: Towards a Stronger Community: Proceedings of the Scientific and Practical Conference, October 21, 2016, Severodonetsk, 272–274. (in Ukrainian).
- 21. Tykhonova I., Matsiievska O. 2004. The problem of using ion-exchange materials in the water treatment shop of industrial enterprises. Installation Market, 9, 22–23. (in Ukrainian).
- 22. Zapolskyi A.K. 2005. Water Supply, Wastewater Disposal and Water Quality, Kyiv: Vyscha Shkola, 612. (in Ukrainian).
Typ dokumentu
Bibliografia
Identyfikator YADDA
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