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The investigation of lithium extraction by roasting with sulfating agent and water leaching from nepheline syenite rocks

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this study, the extraction of lithium from zinnwaldite concentrate containing 0.25% Li was investigated. The run-of-mine ore originated from nepheline syenite rocks in Kırşehir, Turkey, and contained 216.3 ppm Li. Firstly, the ore was beneficiated by a flotation process to increase the lithium content. Then, it was subjected to roasting and water leaching processes, respectively. In the roasting process, calcite and gypsum were used as additives to form dissoluble lithium sulfate for the next process. Additionally, the effect of roasting temperatures (750, 850, 950, and 1000°C) and times (30, 60, 90, 120, and 240 min) was examined along with different ratios of additives to concentrate to find the optimal conditions. Accordingly, the calcined product from the roasting process was dissolved in water by determining the optimal leaching temperature, time, and water/solid ratio. Consequently, a lithium product was obtained from the concentrate with 93.3% extraction efficiency. Finally, the mother liquor contained 30 mg/dm3 Li, the production of Li2CO3 from mother liquor will be investigated in case of production of the sample at the optimal conditions of roasting and leaching in further studies.
Słowa kluczowe
Rocznik
Strony
art. no. 146154
Opis fizyczny
Bibliogr. 37 poz., rys., tab., wykr.
Twórcy
  • Istanbul Technical University, Faculty of Mines, Mineral Processing Engineering Department, Istanbul, Turkey, 34469
autor
  • Istanbul Technical University, Faculty of Mines, Mineral Processing Engineering Department, Istanbul, Turkey, 34469
Bibliografia
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  • BARBOSA, L.I., GONZÁLEZ, J.A., DEL CARMEN RUIZ, M., 2015. Extraction of lithium from β-spodumene Rusing chlorination roasting with calcium chloride. Thermochim. Acta. 605, 63–67.
  • BOTULA, J., RUCKÝ, P., ŘEPKA, V., 2005. Extraction of zinnwaldite from mining and processing wastes. Collection of Scientifical Works of Technical University of Ostrava, Mining–Geological Group 51(2), 9–16.
  • CHEN, Y., TIAN, Q., CHEN, B., SHI, X., LIAO, T., 2011. Preparation of lithium carbonate from spodumene by a sodium carbonate autoclave process. Hydrometallurgy. 109(1–2), 43–46.
  • CHOI, J., KIM, W., CHAE, W., KIM, S.B., KIM, H., 2012. Electrostatically controlled enrichment of lepidolite via flotation. Mater. Trans. 53, 2191–2194.
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  • HE, G. C., FENG, J.N., MAO, M.X., WU, Y.P., 2013. Application of combined collectors in flotation of lepidolite. Adv. Mater. Res. 734, 921–924.
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  • JANDOVÁ, J., DVOŘÁK, P., VU, H.N., 2010. Processing of zinnwaldite waste to obtain Li2CO3. Hydrometallurgy. 103(1–4), 12–18.
  • JANDOVÁ, J., VU, H.N., BELKOVA, T., DVORÁK, P., KONDÁS, J., 2009. Obtaining Li2CO3 from zinnwaldite wastes. Ceram-Silik. 53(2), 108–112.
  • JANDOVÁ, J., VU, H., DVOŘÁK, P., 2007. Využití sádrové a vápencové metody pro separaci Li a Rb z cinvalditových odpadů (in Czech), in: Fečko, P. (Ed.), Proceedings of XI. Conference on Wastes Recycling, Košice, Slovak Republic, December 6.
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  • LUONG, V.T., KANG, D.J., AN, J.W., DAO, D.A., KIM, M.J., TRAN, T., 2014. Iron sulphate roasting for extraction of lithium from lepidolite. Hydrometallurgy. 141, 8–16.
  • LUONG, V.T., KANG, D.J., AN, J.W., KIM, M.J., TRAN, T., 2013. Factors affecting the extraction of lithium from lepidolite. Hydrometallurgy. 134, 54–61.
  • MARTIN, G., SCHNEIDER, A., VOIGT, W., BERTAU, M., 2017. Lithium extraction from the mineral zinnwaldite: Part II: Lithium carbonate recovery by direct carbonation of sintered zinnwaldite concentrate. Miner. Eng. 110, 75–81.
  • MCVAY, T.L., BROWNING, J.S., 1962. Flotation of spodumene from pegmatites of Cleveland county, N.C. US Department of the Interior, Bureau of Mines Report, pp. 1–6.
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  • YAN, Q., LI, X., WANG, Z., WU, X., WANG, J., GUO, H., HU, Q., PENG, W., 2012a. Extraction of lithium from lepidolite by sulfation roasting and water leaching. Int. J. Miner. Process. 110, 1–5.
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  • YAN, Q.X., LI, X.H., WANG, Z.X., WANG, J.X., GUO, H.J., HU, Q.Y., PENG, W., WU, X.F., 2012c. Extraction of lithium from lepidolite using chlorination roasting–water leaching process. Trans. Nonferrous Met. Soc. China 22(7), 1753–1759.
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Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-0acd7a09-ea3c-47ac-8f5e-fdb8ac2b4bb1
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