Removal of lead ions from acid aqueous solutions and acid mine drainage using zeolite bearing tuff

• Autorzy: Zendelska A. , Golomeova M. , Golomeov B. , Krstev B.

Identyfikatory

DOI

10.24425/118185

• Języki publikacji: EN

Abstrakty

EN

The adsorption of lead ions onto a zeolite bearing tuff (stilbite) from synthetic acid aqueous solution and acid mine drainage taken from Sasa mine, Macedonia, is elaborated in this paper. The results present that adsorption occurs efficiently in both of cases. The physical and chemical properties of the used natural material, zeolite bearing tuff, are characterized by X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy. The concentration of metal ions in solution before and after treatment is obtained by AES-ICP. The effectivity of zeolite bearing tuff is determined through a series of experiments under batch conditions from single ion solutions, whereby the main parameters are the effects of initial pH of solution, mass of adsorbent, initial metal concentration in solution, contacting time and competing cations. The maximum capacity of zeolite bearing tuff for removal of lead ions from solution is determined by equilibrium studies. The experimental obtained data are fitted with Freundlich and Langmuir adsorption models. The experimental data are better fitted with Langmuir adsorption isotherm. Zeolite bearing tuff is effective adsorbent for treating acid mine drainage. The results showed that 99% of lead ions are removed from acid mine drainage, i.e. the concentration of lead ions from 0.329 mg/dm3 decrease to 0.002 mg/dm3. The pH value of acid mine drainage from 3.90 after treatment with zeolite bearing tuff increases to 5.36.

Słowa kluczowe

EN

adsorption; acid mine drainage; zeolite bearing tuff; lead ions; equilibrium studies; Sasa mine

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2018
• Tom: Vol. 44, no. 1
• Strony: 87--96
• Opis fizyczny: Bibliogr.26 poz., tab., wykr.

Twórcy

autor

Zendelska A.

• Goce Delcev University, Faculty of Natural and Technical Sciences

autor

Golomeova M.

• Goce Delcev University, Faculty of Natural and Technical Sciences

autor

Golomeov B.

• Goce Delcev University, Faculty of Natural and Technical Sciences

autor

Krstev B.

• Goce Delcev University, Faculty of Natural and Technical Sciences

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).