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Warianty tytułu
Języki publikacji
Abstrakty
This study aims to leach copper from chalcopyrite and optimizing the leaching process, using the response surface methodology (RSM). The RSM, a D-optimal design with four factors in three levels was employed to evaluate the effect of particle size, temperature, silver-coated pyrite to chalcopyrite ratio and redox potential parameters on the copper extraction efficiency. A quadratic model was then proposed by the RSM to correlate leaching variables. The tests results indicated that the model was significant with the experimental data at a correlation coefficient (R2) of 0.96. The most important parameters of copper extraction efficiency were particle size and silver-coated pyrite-to-chalcopyrite ratio, and also the squared term of particle size (A2), temperature (B2) and redox potential (D2). In addition, the interaction between redox potential and silver-coated pyrite-to-chalcopyrite ratio (CD) was significant. It was shown that the finer the particle size the faster the leaching rate of copper. It was also indicated that by increasing silver-coated pyrite to chalcopyrite ratio of 6:1 copper recovery increased. The maximum recovery of copper (71%) was obtained for the particle size of -38 μm, 70 °C, 420 mV of redox potential, silver-coated pyrite-to-chalcopyrite ratio of 6 and leaching time of 8 hours.
Rocznik
Tom
Strony
1023--1035
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
autor
- Department of Mining Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran
autor
- School of Mining Engineering, College of Engineering, University of Tehran, Iran
autor
- School of Mining Engineering, College of Engineering, University of Tehran, Iran
Bibliografia
- AGHAIE E., PAZOUKI M., HOSSEINI M.R., RANJBAR M., GHAVIPANJEH F., 2009. Response surface methodology (RSM) analysis of organic acid production for Kaolin beneficiation by Aspergillus niger. Chemical Engineering Journal 147, 245–251.
- AHMADI A., RANJBAR M., SCHAFFIE M., 2012. Catalytic effect of pyrite on the leaching of chalcopyrite concentrates in chemical, biological and electrobiochemical systems. Minerals Engineering 34, 11-18.
- ANDRE I., KHURI, MUKHOPADHYAY, S., 2010. Response surface methodology. Sons, Inc, WIREs Comp Stat 2, 128–149.
- BOX E.P, GEORGE, HUNTER, STUART J., HUNTER WILLIAM G., 2005. Statistics for Experiments. New Jersey: John Willey and Sons, Inc.
- CORDOBA E.M., MUNOZ J.A., BLAZQUEZ M.L., GONZALEZ F., BALLESTER A., 2008 (a). Leaching of chalcopyrite with ferric ion. Part I: general aspects. Hydrometallurgy 93, 81–87.
- CORDOBA E.M., MUNOZ J.A., BLAZQUEZ M.L., GONZALEZ F., BALLESTER A., 2008 (b). Leaching of chalcopyrite with ferric ion. Part II: Effect of redox potential. Hydrometallurgy 93, 88–96.
- DIXON D.G., MAYNE D.D., BAXTER K.G., 2008. Galvanox™ – a novel galvanically assisted atmospheric leaching technology for copper concentrate. Canadian Metallurgical Quarterly 47, 327–336.
- DUTRIZAC J.E., MACDONALD R.J.C., INGRAHAM T.R., 1969. The kinetics of dissolution of Synthetic Chalcopyrite in aqueous acidic ferric sulfate solutions. Transactions of the Mettalugical Society of AIME 245, 955– 959.
- HACKEL R.P., DREISINGER D.B., PETERS E., KING J.A., 1995. Passivation of chalcopyrite during the oxidative leaching in sulfate media. Hydrometallurgy 39 (1), 25–48.
- HICHEM HAMZAOUI A., JAMOUSSI B., MNIF, A., 2008. Lithium recovery from highly concentrated solutions: Response surface methodology (RSM) process parameters optimization. Hydrometallurgy 90, 1–7.
- HIROYOSHI N., KUROIWA S., MIKI H., TSUNEKAWA M., HIRAJIMA T., 2004. Synergistic effect of cupric and ferrous ions on active-passive behavior in anodic dissolution of chalcopyrite in sulfuric acid solutions. Hydrometallurgy 74, 103–116.
- KOLEINI S.M.J., AGHAZADEH V., SANDSTROM A., 2011. Acidic sulphate leaching of chalcopyrite concentrates in presence of pyrite. Minerals Engineering. 24, 381–386.
- MIRAZIMI S.M.J., RASHCHI F., 2011. Vanadium recovery from steel converter slag using Pseudomonas. Proceedings of the Second National Conference of Applied Microbiology. 30–31.
- MONTGOMERY, D.C., 2005. Design and Analysis of Experiments. John Wiley and Sons, Inc., New Jersey.
- MUNOZ P.B., MILLER J.D., WADSWORTH M.E., 1979. Reaction mechanism for the acid ferric sulfate leaching of chalcopyrite. Metallurgical Transactions B: Process Metallurgy. 10B, 149–158.
- MYERS R.H., Montgomery D.C., 2002. Response Surface Methodology: Process and product optimization usingdesigned experiments, New York: JohnWiley and Sons, Inc.
- NAZARI G., DIXON D.G., DREISINGER D.B., 2011. Enhancing the kinetics of chalcopyrite leaching in the Galvanox™ process. Hydrometallurgy 105, 251–258.
- NAZARI G., DIXON D.G., DREISINGER D.B., 2012 (a). The mechanism of chalcopyrite leaching in the presence of silver-enhanced pyrite in the Galvanox™ process. Hydrometallurgy 113–114, 122–130.
- NAZARI G., DIXON D.G., DREISINGER D.B., 2012 (b). The role of silver-enhanced pyrite in enhancing the electrical conductivity of sulfur product layer during chalcopyrite leaching in the Galvanox™ process. Hydrometallurgy 113–114, 177–184.
- PADILLA R., PAVEZ P., RUIZ M.C., 2008. Kinetics of copper dissolution from sulfidized chalcopyrite at high pressures in H2SO4–O2. Hydrometallurgy 91 ,113–20.
- STOTT M.B., WATLING H.R., FRANZMANN P.D., SUTTON D., 2000. The role of iron-hydroxy precipitates in the passivation of chalcopyrite during bioleaching. Minerals Engineering 13 (10-1), 1117–1127.
- TSHILOMBO A.F. 2004. Mechanism and kinetics of chalcopyrite passivation and depassivation during ferric and microbial leaching solutions. PhD Thesis, The University of British Columbia, Vancouver, BC, Canada.
- VENKATACHALAM S., 1991. Treatment of chalcopyrite concentrates by hydrometallurgical techniques. Minerals engineering 4, 1115-1126.
- VIEIRA S., HOFFMAN R., 1989. Estatistica Experimental. Editora Atlas, Sao Paulo.
- WANG S., 2005. Copper leaching from chalcopyrite concentrates. The Journal of The Minerals, Metals & Materials Society 57, 48–51.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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