Assessment of mechanical and thermomechanical properties of epoxy-basalt composites modified with halogen-free intumescent flame retardants

• Autorzy: Barczewski Mateusz , Matykiewicz Danuta , Andrzejewski Jacek , Sałasińska Kamila , Paszkiewicz Sandra , Piasecki Adam , Aniśko Joanna , Hejna Aleksander , Przestacki Damian
• Języki publikacji: EN

Abstrakty

EN

This study aims to examine the effect of flame retardants (FRs) on the mechanical and thermomechanical properties of epoxy composites reinforced with basalt fibers. To effectively modify fire behavior, it is usually necessary to introduce significant amounts of FRs, which raises many concerns due to the potential deterioration of other functional properties, including mechanical performance. In this work, 30 wt.% halogen-free FRs, including a two-component FR (ammonium polyphosphate with pentaerythritol) and melamine cyanurate, were introduced into the polymer matrix. The unmodified and intumescent FR-modified epoxy resin composites reinforced with basalt fibers were subjected to static flexural test and thermomechanical properties assessment. The research results were correlated with the analysis of changes in the chemical composition assessed using Fourier transform infrared spectroscopy. As a result, the saturation of the reinforcing fabrics by the modified epoxy resin was limited, which caused a different failure mechanism under static bending and impact test conditions. Both FR systems reduced the flammability of the modified epoxy laminates along with also acceptable deterioration of the mechanical properties. The most beneficial effects considering the combination of all the analyzed features were noted for the two-component FR system containing ammonium polyphosphate and pentaerythritol.

Słowa kluczowe

EN

epoxy; basalt; composite; intumescent flame retardants; mechanical properties

PL

epoksyd; bazalt; kompozyty; środki zmniejszające palność

• Wydawca: Polskie Towarzystwo Materiałów Kompozytowych
• Czasopismo: Composites Theory and Practice
• Rocznik: 2023
• Tom: R. 23, nr 4
• Strony: 239--246
• Opis fizyczny: Bibliogr. 39 poz., rys., tab.

Twórcy

autor

Barczewski Mateusz

• Poznan University of Technology, Faculty of Mechanical Engineering and Management, Institute of Materials Technology, Polymer Processing Division, ul. Piotrowo 3, 61-138 Poznan, Poland

autor

Matykiewicz Danuta

• Poznan University of Technology, Faculty of Mechanical Engineering and Management, Institute of Materials Technology, Polymer Processing Division, ul. Piotrowo 3, 61-138 Poznan, Poland

autor

Andrzejewski Jacek

• Poznan University of Technology, Faculty of Mechanical Engineering and Management, Institute of Materials Technology, Polymer Processing Division, ul. Piotrowo 3, 61-138 Poznan, Poland

autor

Sałasińska Kamila

• Warsaw University of Technology, Faculty of Materials Science and Engineering, ul. Wołoska 141, 02-507 Warsaw, Poland

autor

Paszkiewicz Sandra

• West Pomeranian University of Technology, Faculty of Mechanical Engineering and Mechatronics, al. Piastów 19, 70-310 Szczecin, Poland

autor

Piasecki Adam

• Poznan University of Technology, Institute of Materials Engineering, ul. Jana Pawła II 24, 60-965 Poznan, Poland

autor

Aniśko Joanna

• Poznan University of Technology, Faculty of Mechanical Engineering and Management, Institute of Materials Technology, Polymer Processing Division, ul. Piotrowo 3, 61-138 Poznan, Poland

autor

Hejna Aleksander

• Poznan University of Technology, Faculty of Mechanical Engineering and Management, Institute of Materials Technology, Polymer Processing Division, ul. Piotrowo 3, 61-138 Poznan, Poland

autor

Przestacki Damian

• Poznan University of Technology, Institute of Mechanical Technology, ul. Piotrowo 3, 61-138 Poznan, Poland

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).