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Application of Emulsion Liquid Membrane Using Green Surfactant for Removing Phenol from Aqueous Solution: Extraction, Stability and Breakage Studies

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Emulsion Liquid Membrane (ELM) has garnered much attention, for its simple operation and high selectivity for the target solute. For an ELM process to be successful, emulsion stability and formulation of liquid membrane are the two main criteria. This study investigated an ELM formulation to identify a suitable green surfactant over the ordinary ones to reduce the utilization of chemicals. The stability of water-in-oil-in-water (w/o/w) was assessed in the following ways, by altering the concentrations of the egg yolk and NaOH, homogenizer speed, and emulsification time. To ascertain the favorable conditions for phenol extraction, several experiments were performed, adopting the batch process, which included many parameters, like the influence exerted by the pH of the external feed, concentration of surfactant, concentration of the internal phase, time of emulsification, homogenization speed and mixing time. Lower breakage and greater extraction efficiency (0.83% and 82.06%, respectively) were attained at 3.5 pH of the external feed, 4% (v/v) of the surfactant, 0.1 M of NaOH, 7 min of emulsification time, 5800 rpm of homogenizer speed and 3 minutes of mixing time. From the results of this study, egg yolk emerged as a good green surfactant. Thus, the ELM process holds promise as an effective technology for stripping phenol from aqueous solutions.
Rocznik
Strony
305--314
Opis fizyczny
Bibliogr. 38 poz., rys., tab.
Twórcy
  • Environmental Engineering Department, College of Engineering University of Baghdad, Baghdad, Iraq
  • Environmental Engineering Department, College of Engineering University of Baghdad, Baghdad, Iraq
  • Physics Science Department, College of Science, University of Baghdad, Baghdad, Iraq
Bibliografia
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  • 2. Ahmad, A., et al. 2012. Emulsion liquid membranę for cadmium removal: Studies on emulsion diameter and stability. Desalination, 287, 30–34.
  • 3. Ahmed A. 2008. Electrocoagulation of phenol for wastewater treatment. Iraqi Journal of Chemical Petroleum Engineering, 9(3), 45–49.
  • 4. Arutchelvan V., et al. 2006. Kinetics of high strength phenol degradation using Bacillus brevis. Journal of hazardous materials, 129(1–3), 216–222.
  • 5. Bazrafshan E., et al. 2019. Photocatalytic degradation of catechol using ZnO nanoparticles as catalyst: Optimizing the experimental parameters using the Box-Behnken statistical methodology and kinetic studies. Microchemical Journal, 147, 643–653.
  • 6. Chiha M., et al. 2010. Study on ultrasonically assisted emulsification and recovery of copper (II) from wastewater using an emulsion liquid membrane process. Ultrasonics sonochemistry, 17(2), 318–325.
  • 7. Dâas A., Hamdaoui O.J.J.O.M.S. 2010. Extraction of bisphenol A from aqueous solutions by emulsion liquid membrane. Arabian Journal of Chemistry, 348(1–2), 360–368.
  • 8. Dehmani Y., et al. 2020. Removal of phenol from aqueous solution by adsorption onto hematite (α-Fe2O3): mechanism exploration from both experimental and theoretical studies. Arabian Journal of Chemistry, 13(5), 5474–5486.
  • 9. Devulapalli R., Jones F. 1999. Separation of aniline from aqueous solutions using emulsion liquid membranes. Journal of Hazardous Materials, 70(3), 157–170.
  • 10. Gürel L., et al. 2005. Removal of lead from wastewater using emulsion liquid membrane technique. Environmental Engineering Science, 22(4), 411–420.
  • 11. Hernández-Francisco E., et al. 2017. Removal of phenolic compounds from oil refinery wastewater by electrocoagulation and Fenton/photo-Fenton processes. Journal of Water Process Engineering, 19, 96–100.
  • 12. Hussein M.A., et al. 2019. Application of emulsion and Pickering emulsion liquid membrane technique for wastewater treatment: an overview. Environmental Science Pollution Research, 26(36), 36184–36204.
  • 13. Jiang L., Mao X. 2012. Degradation of phenol-containing wastewater using an improved Electro-Fenton process. Int J Electrochem Sci, 7, 4078–4088.
  • 14. Jiang Y., et al. 2010. Biodegradation of phenol and m-cresol by mutated Candida tropicalis. Journal of Environmental Sciences, 22(4), 621–626.
  • 15. Jiao H., et al. 2013. Extraction performance of bisphenol A from aqueous solutions by emulsion liquid membrane using response surface methodology. Desalination, 313, 36–43.
  • 16. Karcher V., et al. 2015. Interfacial energy during the emulsification of water-in-heavy crude oil emulsions. Brazilian Journal of Chemical Engineering, 32(1), 127–137.
  • 17. Kasaini H., et al. 1998. Application of emulsion liquid membranes to recover cobalt ions from a dualcomponent sulphate solution containing nickel ions. Journal of Membrane Science, 146(2), 159–168.
  • 18. Kohli H.P., et al. 2019. Stability and performance study of emulsion nanofluid membrane: A combined approach of adsorption and extraction of Ethylparaben. Colloids Surfaces A: Physicochemical Engineering Aspects, 579, 123675.
  • 19. Kumbasar R.A. 2008. Selective separation of chromium (VI) from acidic solutions containing various metal ions through emulsion liquid membrane using trioctylamine as extractant. Separation purification technology, 64(1), 56–62.
  • 20. Kusumastuti, A., et al. 2018. Emulsion liquid membrane for textile dyes removal: Extraction process. Journal of Physical Science, 29, 175–184.
  • 21. Mahakal P.A., Deshpande R.S. 2018. Removal of heavy metal from aqueous wastewater by emulsion liquid membrane. International Journal of Advanced Research, 6(1), 455–463.
  • 22. Mahvi A.H., et al. 2007. Photo-oxidation of phenol in aqueous solution: toxicity of intermediates. Korean Journal of Chemical Engineering, 24(1), 79–82.
  • 23. Mohammed A.A., et al. 2020. Studies on membranę stability and extraction of ciprofloxacin from aqueous solution using pickering emulsion liquid membranę stabilized by magnetic nano-Fe2O3. Colloids Surfaces A: Physicochemical Engineering Aspects, 585, 124044.
  • 24. Mohammed A.A., et al. 2020. Simultaneous studies of emulsion stability and extraction capacity for the removal of tetracycline from aqueous solution by liquid surfactant membrane. Chemical Engineering Research Design, 159, 225–235.
  • 25. Mohammed A.A., Selman H.M. 2018. Liquid surfactant membrane for lead separation from aqueous solution: Studies on emulsion stability and extraction efficiency. Journal of environmental chemical engineering, 6(6), 6923–6930.
  • 26. Moussavi G., et al. 2009. The investigation of catalytic ozonation and integrated catalytic ozonation/biological processes for the removal of phenol from saline wastewaters. Journal of Hazardous Materials, 171(1–3), 175–181.
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  • 29. Raji M., et al. 2018. Response Surface Optimization of Dysprosium Extraction Using an Emulsion Liquid Membrane Integrated with Multi‐Walled Carbon Nanotubes. Chemical Engineering Technology, 41(9), 1857–1870.
  • 30. Raji M., et al. 2017. Nanofluid-based emulsion liquid membrane for selective extraction and separation of dysprosium. International Journal of Chemical Molecular Engineering, 11(12), 787–792.
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  • 32. Sabry R., et al. 2007. Removal of lead by an emulsion liquid membrane: Part I. Desalination, 212(1–3), 165–175.
  • 33. Seifollahi Z., et al. 2019. Amoxicillin extraction from aqueous solution by emulsion liquid membranes using response surface methodology. Chemical Engineering Technology, 42(1), 156–166.
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  • 37. Wilberg K.D.Q., et al. 2000. Removal of phenol by enzymatic oxidation and flotation. Brazilian Journal of Chemical Engineering, 17, 907–914.
  • 38. Zhao X., Wang Y., Ye Z., Borthwick A.G.L., Ni J. 2006. Oil field wastewater treatment in Biological Aerated Filter by immobilized microorganisms. Process Biochemistry, 41(7), 1475–1483.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-092e6557-3575-4fbb-8ca0-4ec41c71e8a6
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