Optimization and evaluation of alkali-pretreated Paeonia ostii seed coats as adsorbent for the removal of MB from aqueous solution

• Autorzy: Liu Q. , Li T. , Zhang S. , Qu L. , Ren B.

Identyfikatory

DOI

10.2478/pjct-2018-0035

• Języki publikacji: EN

Abstrakty

EN

A novel efficient adsorbent, alkali-pretreated Paeonia ostii seed coats (AP-PSC), was investigated for the removal of methylene blue (MB) dye from solution. Orthogonal array design was applied to optimize the process parameters viz. alkali concentration, liquid-solid ratio (LSR) and pretreatment time. The results revealed that the optimal pretreatment conditions were at 0.8% (w/w) NaOH with LSR of 0.35 L g^–1  treating for 50 min. Equilibrium and kinetic studies indicated that Langmuir isotherm and Pseudo-second-order models described the experimental data well. The maximum adsorption capability was of 368.2 mg g^–1  for MB at 25°C. Thermodynamic parameters suggested that the AP-PSC adsorption process was physical, endothermic and spontaneous. Furthermore, the adsorption process was influenced by several interactive mechanisms, including ion-exchange, as well as Van der Waals forces and hydrogen bonds that occur concomitantly. It was concluded that AP-PSC may be potential as an efficient adsorbent to remove MB from solution.

Słowa kluczowe

EN

Alkali-pretreated Paeonia ostii seed coats; Adsorption; Methylene blue; Mechanism

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2018
• Tom: Vol. 20, nr 3
• Strony: 29--36
• Opis fizyczny: Bibliogr. 35 poz., rys., tab.

Twórcy

autor

Liu Q.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China
• School of Environmental Engineering and Chemistry, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, P. R. China

autor

Li T.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China

autor

Zhang S.

• School of Environmental Engineering and Chemistry, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, P. R. China

autor

Qu L.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China

autor

Ren B.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).