Functional Nanocomposite Poly(phenylene sulphide) Fibres - Preliminary Studies

• Autorzy: Kulpinski P. , Czarnecki P. , Niekraszewicz B. , Jeszka J. K.

Identyfikatory

DOI

10.5604/12303666.1201129

Warianty tytułu

PL

Funkcjonalne włókna nanokompozytowe z poli(siarczku fenylenu) – wyniki wstępne

• Języki publikacji: EN

Abstrakty

EN

Composite poly(phenylene sulphide) (PPS) fibres and nonwovens were obtained by the melt blowing method. A specially designed twin screw extruder was used which allowed to perform several mixing cycles prior to final extrusion. Multiwall carbon nanotubes (CNTs) and carbonyl iron microparticles were used as the additives. To obtain possibly good dispersion of the modifiers in the polymer melt, the CNTs were first dispersed in N-methyl-2-pyrrolidone and Fe microparticles were dispersed in polyethylene wax. Rheological characteristics of the melts and bulk composites, such as viscosity, loss and storage moduli, are similar to those reported by other groups; however, the contents of additives must be lower than in the case of bulk materials to assure satisfactory melt spinability. The fibres obtained show satisfactory mechanical characteristics and electromagnetic screening efficiency in the GHz region.

PL

W artykule zaprezentowano kompozytowe włókna oraz włókniny z poli(siarczku fenylenu) wytwarzane metodą melt-blown. Do formowania włókien zastosowano laboratoryjną wytłaczarkę dwuślimakową, której konstrukcja pozwala na wykonanie kilku cykli mieszania polimeru przed procesem formowania włókien. Jako modyfikatory zastosowano wielościenne nanorurki węglowe (CNTs) oraz cząstki żelaza o rozdrobnieniu mikrometrycznym. W celu otrzymania możliwe dobrej dyspersji modyfikatorów w polimerze, nanorurki węglowe zostały wstępnie rozprowadzone w N-metylo pirolidonie (NMP), natomiast mikrocząstki żelaza były zdyspergowane w niskocząsteczkowym wosku polietylenowym. Wykonano charakterystykę reologiczną stopów polimerowych zawierających modyfikatory. Określono również parametry mechaniczne włókien oraz oszacowano właściwości barierowe otrzymanych włóknin. Na podstawie uzyskanych wyników można stwierdzić, iż otrzymane włókna charakteryzują się stosunkowo dobrymi parametrami mechanicznymi oraz mają właściwości ekranujące w zakresie fal elektromagnetycznych o częstotliwości rzędu GHz.

Słowa kluczowe

EN

poly(phenylene sulphide); nonwoven; carbon nanotube; carbonyl iron

PL

poli(siarczek fenylu); włókniny; nanorurki węglowe; mikrocząstki żelaza

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2016
• Tom: Vol. 24, no. 4 (118)
• Strony: 20--26
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Kulpinski P.

• Department of Man-Made Fibres, Faculty of Material Technologies and Textile Design, Lodz University of Technology, Łódź, Poland

autor

Czarnecki P.

• Department of Man-Made Fibres, Faculty of Material Technologies and Textile Design, Lodz University of Technology, Łódź, Poland

autor

Niekraszewicz B.

• Department of Man-Made Fibres, Faculty of Material Technologies and Textile Design, Lodz University of Technology, Łódź, Poland

autor

Jeszka J. K.

• Department of Man-Made Fibres, Faculty of Material Technologies and Textile Design, Lodz University of Technology, Łódź, Poland

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.