Fabrication of fluoride nanocrystals and their spectroscopic properties

• Autorzy: Pawlik N. , Szpikowska-Sroka B. , Goryczka T. , Pisarski W. A.

Identyfikatory

DOI

10.5277/oa190304

• Języki publikacji: EN

Abstrakty

EN

In this work, the fabrication of glass-ceramic materials containing MF₃:Eu³⁺+ (M = La, Gd) nanocrystals dispersed in silica sol-gel hosts has been presented. The transformation from liquid sols towards bulk samples was also examined based on IR measurements. The crystallization temperatures and formation of MF₃ phases were verified based on TG/DSC analysis and XRD measurements. The optical properties of prepared Eu³⁺5D₀5D₀ → ⁷F_J (J = 1–4) emission bands, which were recorded within the reddish-orange spectral area under near-UV illumination (λ_exc = 393 nm). Recorded luminescence spectra and double-exponential character of decay curves for prepared glass-ceramic samples indicated the successful migration of Eu³⁺ dopant ions from amorphous silica framework to low-phonon energy MF₃ nanocrystal phases.

Słowa kluczowe

EN

sol-gel method; glass-ceramics; fluoride nanocrystals; europium ions

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2019
• Tom: Vol. 49, nr 3
• Strony: 415--426
• Opis fizyczny: Bibliogr. 29 poz., rys.

Twórcy

autor

Pawlik N.

• University of Silesia, Institute of Chemistry, Szkolna 9 Street, 40-007 Katowice, Poland

autor

Szpikowska-Sroka B.

• University of Silesia, Institute of Chemistry, Szkolna 9 Street, 40-007 Katowice, Poland

autor

Goryczka T.

• Univeristy of Silesia, Institute of Materials Science, 75 Pułku Piechoty 1A Street, 41-500 Chorzów, Poland

autor

Pisarski W. A.

• University of Silesia, Institute of Chemistry, Szkolna 9 Street, 40-007 Katowice, Poland

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).