Influence of Modified Cationic Starch in a Mixed Poly(Vinyl Alcohol)/Cationic Starch Solution on the Electrospinning Process and Web Structure

• Autorzy: Šateikė Jurgita , Milašius Rimvydas

Identyfikatory

DOI

10.2478/aut-2019-0010

• Języki publikacji: EN

Abstrakty

EN

Nanofibers were electrospun from bicomponent poly(vinyl alcohol) (PVA) and modified cationic starch (CS) mixed solution PVA/CS with different mass ratios (75/25, 50/50 and 35/65) at a total concentration of 12 wt% for all polymer compositions. For comparison, pure PVA solution was used. Electrospinning technique Nanospider (Elmarco, Czech Republic) with a rotating electrode with tines was used to obtain nanofibrous web. The influence of prepared polymer solution compositions on the structure and morphology of nanofibers and webs were investigated. Analyzing the structure and morphology of the formed nanofiber webs, it was noticed that the fineness nanofibers were formed from the PVA/CS solution with a mass ratio of 50/50. This ratio of solution also lets us to obtain the nanofibrous web with less sticked nanofibers on spunbond. The increase in the CS ratio by more than 50/50 had a negative influence on the diameter of nanofibers and the structure of nanofibrous web.

Słowa kluczowe

EN

electrospinning; poly(vinyl alcohol); cationic starch

PL

elektroprzędzenie; alkohol poliwinylowy; skrobia kationowa

• Wydawca: Lodz University of Technology, Faculty of Material Technologies and Textile Design
• Czasopismo: Autex Research Journal
• Rocznik: 2020
• Tom: Vol. 20, no. 1
• Strony: 69--72
• Opis fizyczny: Bibliogr. 14 poz.

Twórcy

autor

Šateikė Jurgita

• Kaunas University of Technology, Faculty of Mechanical Engineering and Design, Studentu 56, LT-51424, Kaunas, Lithuania

autor

Milašius Rimvydas

• Kaunas University of Technology, Faculty of Mechanical Engineering and Design, Studentu 56, LT-51424, Kaunas, Lithuania

Bibliografia

• [1] Bhardwaj, N., Kundu, S. C. (2010). Electrospinning: a fascinating fiber fabrication technique. Biotechnology Advances, 28, 325-347.
• [2] Huang, Z. M., Zhang, Y. Z., Kotaki, M., Ramakrishna, S. (2003). A review on polymer nanofibres by electrospinning and their applications in nanocomposites. Composites Science and Technology, 63(15), 2223-2253.
• [3] Kleivaite, V., Milašius, R. (2018). Electrospinning - 100 Years of investigations and still open questions of web structure estimation. AUTEX Research Journal, 4(18), 398-404.
• [4] Stijnman, A. C., Bodnar, I., Tromp, R. H. (2011). Electrospinning of food-grade polysaccharides. Food Hydrocolloids, 25, 1393-1398.
• [5] Hualin, W., Wenjuan, W., Suwei, J., Shoatong, J., Linfeng, Z., Qin, Z. (2011). Poly(vinyl alcohol)/oxidized starch fibres via electrospinning technique: fabrication and characterization. Iranian Polymer Journal, 20(7), 551-558.
• [6] Sutka, A., Kukle, S., Gravitis, J., Milašius, R., Malašauskiene J. (2013). Nanofibre electrospinning poly(vinyl alcohol) and cellulose composite mats obtained by use of a cylindrical electrode. Advances in Materials Science and Engineering. 2013 (2013), DOI:10.1155/2013/932636.
• [7] Goktepe, F., Mulayim, B. B. (2018). Long path towards to success in electrospun nanofiber yarn production since 1930’s: a critical review. Autex Research Journal, 2(18), 87-109.
• [8] Lee, K. Y., Jeong, L., kang, Y. O., Lee, S. J., Park, W. H. (2009). Electrospinning of polysaccharides for regenerative medicine. Advanced Drug Delivery Reviews, 51, 1020-1032.
• [9] Adomavičiūtė, E., Milašius, R., Žemaitaitis, A., Bendoraitienė, J., Leskovšek, M., Demšar, A. (2009). Methods of forming nanofibres from bicomponent PVA/cationic starch solution. Fibres & Textiles in Eastern Europe, 3(74), 29-33.
• [10] Šukytė, J., Adomavičiūtė, E., Milašius, R., Bendoraitienė, J., Danilovas, P. P. (2012). Formation of Poly(Vinyl Alcohol)/cationic starch blend nanofibres via the electrospining technique: the influence of different factors. Fibres & Textiles in Eastern Europe, 3(92), 16-20.
• [11] Thillaipandian, H., Vankateshwarapurum, R. G. D. (2017). Comprehensive review on electrospinning of starch for biomedical applications, International Journal of Biological Macromolecules, 106, 712-718.
• [12] Kong, L., Zeigler, G. R. (2014). Fabrication of pure starch fibers by electrospinning, Food Hydrocolloids, 36, 20-25.
• [13] Cardenas, W., Gomez-Pachon, E. Y. G., Munaz-Graziano, R. (2016). Preparation of potato starch microfibres obtained by electro wet spinning, Materials Science and Engineering, 138.
• [14] Talmoudi, H., Khenoussi, N., Adolphe, D., Said, A. H., Schacher, L. (2018). An in situ crystal growth of metal organic frameworks-5 on electrospun PVA nanofibers. AUTEX Research Journal, 3(18), 308-313.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).