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Hydrometallurgical recovery of cobalt(ii) from acidic chloride solutions by transport through polymer inclusion membranes

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Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this work a selective transport of Co(II) and Li(I) ions from acidic chloride solutions through polymer inclusion membranes (PIMs) with Cyanex 301 has been studied. The effect of composition of the polymer membrane has been investigated. The obtained results show that around 98% of Co(II) was transported from the source phase containing 0.01 M Co(II) and 0.01 M Li(I) at pH 4.0 through PIM after 12 h into 3.0 M HCl. The membrane containing 18 wt.% cellulose triacetate (CTA), 32 wt.% Cyanex 301 and 50 wt.% o-nitrophenyl octyl ether (ONPOE) showed very good stability, suggesting that there is a possibility of application of the membrane for Co(II) recovery from acidic leach liquor solutions of spent lithium ion batteries (LIBs).
Rocznik
Strony
641--649
Opis fizyczny
Bibliogr. 19 poz., rys., tab.
Twórcy
autor
  • Department of Chemistry, Czestochowa University of Technology, Armii Krajowej 19, 42-200 Czestochowa, Poland
Bibliografia
  • 1. ALGUACIL F.J., ALONSO M., LOPEZ F.A., LOPEZ-DELGADO A., 2011, Active transport of cobalt(II) through a supported liquid membrane using the mixture DP8R and Acorga M5640 as extractant, Desalination 281, 221–225.
  • 2. ALGUACIL F.J., ALONSO M., 2005, Separation of zinc(II) from cobalt(II) solutions using supported liquid membrane with DP-8R (di(2-ethylhexyl) phosphoric acid) as a carrier, J. Membr. Sci. 41, 179–186.
  • 3. AROUS O., KERDUOUDUJ H., SETA P., 2004, Comparison of carrier-facilitated silver(I) and copper(II) ions transport mechanisms in a supported liquid membrane and in a plasticized cellulose triacetate membrane, J. Membr. Sci. 241, 177–185.
  • 4. AROUS O., AMARA M., TRARI M., BOUGUELIA A., KERDUOUDUJ, H., 2010, Cadmium (II) and lead transport in a polymer inclusion membrane using tributyl phosphate as mobile carrier and CuFeO2 as a polarized photo electrode, J. Hazard. Mater.180, 493–498.
  • 5. DANESI P.R., 1984, Separation of metal species by supported liquid membranes, Sep. Sci. Technol. 19, 857–894.
  • 6. INES M., ALMEIDA G.S., CATRALL R.W., KOLEV S.D., 2012, Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs), J. Membr. Sci. 415–416 (2012) 9–23.
  • 7. JAKOVLIJEC B., BOURGET C., NUCCIARONE D., 2004, Cyanex 301 binary extractant systems in cobalt/nickel recovery from acidic chloride solutions, Hydrometallurgy 75, 25–36.
  • 8. KAGAYA S., CATTRALL R.W., KOLEV S.D., 2011, Solid-phase extraction of cobalt(II) from lithium chloride solutions using a poly(vinyl chloride)-based polymer inclusion membrane with Aliquat 336 as the carrier, Anal. Sci. 27, 653–657.
  • 9. KEBICHE-SENHADJI O., TINGRY S., SETA P., BENAMOR M., 2010, Selective extraction of Cr(VI) over metallic species by polymer inclusion membrane (PIM) using anion (Aliquat 336) as carrier, Desalination 258, 59–65.
  • 10. KOZLOWSKI C.A., WALKOWIAK W., 2007, Competitive transport of cobalt-60, strontium-90, and cesium-137 radioisotopes across polymer inclusion membranes with DNNS, J. Membr. Sci. 297, 181–189.
  • 11. KOZLOWSKI A.C., KOZLOWSKA J., PELLOWSKI WALKOWIAK W., 2006, Separation of cobalt-60, strontium-90, and cesium-137 radioisotopes by competitive transport across polymer inclusion membranes with organophosphorous acids, Desalination 198, 141–148.
  • 12. POSPIECH B., WALKOWIAK W., WOZNIAK M., 2005, Application of TBP in selective removal of iron(III) in solvent extraction and transport through polymer inclusion membranes, Physicochem. Probl. Miner. Process. 39, 89–98.
  • 13. POSPIECH B., 2012, Separation of silver(I) and copper(II) from aqueous solutions by transport through polymer inclusion membranes with Cyanex 471X, Sep. Sci. Technol. 47:9, 1413–1419
  • 14. RICKELTON W.A., BOYLE R.J., 1988, Solvent extraction with organophosphines – commercial & potential applications, Sep. Sci. Technol. 23, 1227–1250.
  • 15. SURUCU A., EYUPOGLU V., TUTKUN O., 2010, Selective separation of cobalt and nickel by supported liquid membranes, Desalination 250, 1155–1156.
  • 16. SWAIN B., JEONG J., LEE J., LEE G., 2007, Extraction of Co(II) by supported liquid membrane and solvent extraction using Cyanex 272 as an extractant: A comparison study, J. Membr. Sci. 288, 139–148.
  • 17. SWAIN B., JEONG, J. LEE, J., LEE G., SOHN J., 2007, Hydrometallurgical process for recovery of cobalt from waste cathodic active material generated during manufacturing of lithium ion batteries, J. Power Sources 167, 536–544.
  • 18. SWAIN B., JEONG J., YOO K., LEE J., 2010, Synergistic separation of Co(II)/Li(I) for the recycling of LIB industry wastes by supported liquid membrane using Cyanex 272 and DP-8R, Hydrometallurgy 101, 20–27.
  • 19. TAIT B. K., 1992, The extraction of base metal ions by Cyanex 301, Cyanex 302 and their binary extractants mixtures with Aliquat 336, Solv. Extr. Ion Exch. 10, 799–809.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-05e795de-cd74-4166-b98d-1cb4427ca389
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