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Nanocrystalline copper based microcomposites

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The aim of this work was to investigate microstructure, mechanical properties and deformation behavior of copper microcomposites: Cu- Y2O3, Cu- ZrO2 and Cu-WC produced by powder metallurgy techniques. Design/methodology/approach: Tests were made with Cu-Y2O3, Cu-ZrO2 and Cu-WC microcomposites containing up to 2% of a strengthening phase. The materials were fabricated by powder metallurgy techniques, including milling of powders, followed by their compacting and sintering. The main mechanical properties of the materials were determined from the compression test and, additionally, measurements of HV hardness and electrical conductivity were made. Analysis of the initial nanocrystalline structure of these materials was made and its evolution during sintering and cold deformation was investigated. Findings: It was found out that addition of up to 2 wt.% of a strengthening phase significantly improves mechanical properties of the material and increases its softening point. The obtained strengthening effect have been discussed based on the existing theories related to strengthening of nanocrystalline materials. The studies have shown importance of “flows” existing in the consolidated materials and sintered materials in pores or regions of poor powder particle connection which significantly deteriorate the mechanical properties of micro-composites produced by powder metallurgy. Research limitations/implications: The powder metallurgy techniques make it possible to obtain copper-based bulk materials by means of input powder milling in a planetary ball mill, followed by compacting and sintering. Additional operations of hot extrusion are also often used. There is some danger, however, that during high-temperature processing or application of these materials at elevated or high temperatures this nanometric structure may become unstable. Practical implications: A growing trend to use new copper based microcomposites is observed recently world-wide. Within this group of materials particular attention is put to those with nanometric grain size of a copper matrix, which show higher mechanical properties than microcrystalline copper. Originality/value: The paper contributes to the knowledge of mechanical properties and the nanostructure stability of Cu-Y2O3, Cu-ZrO2 and Cu-WC microcomposites. A controlled process of milling, compacting, sintering and cold deformation provides possibility to obtain nanocrystalline copper based materials with improved functional properties.
Rocznik
Strony
49--57
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
  • Non-Ferrous Metals Institute, ul. Sowińskiego 5, 44-100 Gliwice, Poland
  • Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
  • Non-Ferrous Metals Institute, ul. Sowińskiego 5, 44-100 Gliwice, Poland
  • Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
  • Non-Ferrous Metals Institute, ul. Sowińskiego 5, 44-100 Gliwice, Poland
  • Non-Ferrous Metals Institute, ul. Sowińskiego 5, 44-100 Gliwice, Poland
Bibliografia
  • [1] A. Czyrska-Filemonowicz, B. Dubiel, Mechanically alloyed, ferritic oxide disperssion strengthened alloys: structure and properties, Journal of Materials Processing Technology 64 (1997)53-64.
  • [2] Z. Rdzawski, High - temperature structural stability of new platinum alloys used in the glass industry, Proceedings AMT’2001, Materials Engineering 5 (2001) 765-767 (in Polish).
  • [3] D.Y. Ying, D.L. Zhang, Processing of Cu-Al2O3 metal matrix nanocomposite materials by using high energy ball milling, Materials Science and Engineering A 286/1 (2000) 152-156.
  • [4] J. Cadek, K. Kucharowa, Novel interpretation of High temperature creep in an ODS Cu-ZrO2 Alloy, Kovove Materials 40 (2002) 133-145.
  • [5] U. Lagerpusch, V. Mohles, D. Baither, B. Anczukowski, E. Membach, Double strengthening of copper by dissolved gold-atoms and by incoherent SiO2- particles: how do the two strengthening contributions superimpose?, Acta Materialia 48 (2000) 3647-3656.
  • [6] A. Zuniga, R. Palma, A. Sepulveda, T. Lobel and L. Nunez, Microstructure and mechanical behavior of Cu-based composites reinforced with WC and TiC particles, prepared by spray forming, Proceedings of the 2nd International Latin American conference on Powder Technology, Iguacu, 1999.
  • [7] Y.V. Baikalova, O.I. Lomovsky, Solid state of synthesis of tungsten carbide in an inert copper matrix, Journal of Alloys and Compounds 297/1-2 (2000) 87-91.
  • [8] Y. Zhan, G. Zhang, Friction and wear behavior of copper matrix composites reinforced with SiC and graphite particles, Tribology Letters 17/1 (2007) 91-98.
  • [9] K.M. Shu, G.C. Tu, The microstructure and the thermal expansion characteristics of Cu/SiCp composities, Materials Science and Engineering 349/1-2 (2003) 236-247.
  • [10] M. Lopez, J.A. Jimenez, D. Corredor, Precipitation strengthened high strength-conductivity copper alloys containing ZrC ceramics, Composites A 38 (2007) 272-279.
  • [11] B.R. Juan, G.C. Jorge, M.Z.V. DePaul, Fabrication and hot extrusion of mechanically alloying Cu-15wt%Cr alloy, Advanced Powder Technology 293-3 (1999) 470-477.
  • [12] K. L. Lee, Effect of oxidation on the creep behavior of copper-chromium in situ composite, Composites Part A: Applied Science and Manufacturing 34/12 (2003) 1135-1271.
  • [13] R. Subramanian, S. Ramakrishnan, P. Shankar, Role of disclination and nanocrystalline state in the formation of quasicrystalline phases on mechanical alloying of Cu-Fe powders, Journal of Materials Science and Technology 16/5 (2000) 499-503.
  • [14] L.K. Tan, Y. Li, S.C. Ng, L. Lu, Structures, properties and responses to heat treatment of Cu-Y alloys prepared by mechanical alloying, Journal of Alloys and Compounds 278/1-2 (1998) 201-208.
  • [15] J.P. Tu, N.Y. Wang, Y.Z. Yang, W.X. Qi, F. Liu, X.B. Zhang, H.M. Lu, M.S. Liu, Preparation and properties of TiB2 nanoparticle reinforced copper matrix composites by in situ processing, Materials Letters 52 (2002) 448-452.
  • [16] C.C. Koch, Top-down synthesis of nanostructured materials: mechanical and thermal processing methods, Reviews On Advanced Materials Science 5 (2003) 91-99.
  • [17] J.P. Stobrawa, Z.M. Rdzawski, Characterisation of nano-structured copper - WC materials, Journal of Achievements in Materials and Manufacturing Engineering 32/2 (2009) 171-178.
  • [18] J.P. Stobrawa, Z.M. Rdzawski, Dispersion - strengthened nanocrystalline copper, Journal of Achievements in Materials and Manufacturing Engineering 24/2 (2007) 35-42.
  • [19] J.P. Stobrawa, Z.M. Rdzawski, W.J. Głuchowski, Micro-structure and properties of nanocrystalline copper - yttria microcomposites, Journal of Achievements in Materials and Manufacturing Engineering 24/2 (2007) 83-86.
  • [20] J.P. Stobrawa, Z.M. Rdzawski, W. Głuchowski, W. Malec, Microstructure evolution in CRCS processed strips of CuCr0,6 alloy, Journal of Achievements in Materials and Manufacturing Engineering 38/2 (2010) 195-202.
  • [21] J. Stobrawa, Z. Rdzawski, W. Głuchowski, W. Malec, Ultrafine grained strips of CuCr0.6 alloy prepared by CRCS method, Journal of Achievements in Materials and Manufacturing Engineering 33/2 (2009) 166-172.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-05bd4c21-d8eb-4b04-a1b3-3042ac2850a4
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