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Dynamical and technological consequences of multiple isolas of steady states in a catalytic fluidised-bed reactor

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Steady-state characteristics of a catalytic fluidised bed reactor and its dynamical consequences are analyzed. The occurrence of an untypical steady-state structure manifesting in a form of multiple isolas is described. A two-phase bubbling bed model is used for a quantitative description of the bed of catalyst. The influence of heat exchange intensity and a fluidisation ratio onto the generation of isolated solution branches is presented for two kinetic schemes. Dynamical consequences of the coexistence of such untypical branches of steady states are presented. The impact of linear growth of the fluidisation ratio and step change of the cooling medium temperature onto the desired product yield is analyzed. The results presented in this study confirm that the identification of a region of the occurrence of multiple isolas is important due to their strong impact both on the process start-up and its control.
Rocznik
Strony
411--422
Opis fizyczny
Bibliogr. 13 poz., tab., wykr.
Twórcy
autor
  • Cracow University of Technology, Department of Chemical and Process Engineering, 30-155 Kraków, ul. Warszawska 24, Poland
Bibliografia
  • 1. Abba I.A., Grace J.R., Bi H.T., 2002. Variable-gas-density fluidized bed reactor model for catalytic processes. Chem. Eng. Sci., 57, 4797-4807. DOI: 10.1016/S0009-2509(02)00289-0.
  • 2. Ajbar A., Alhumazi K., Elnashaie, S.S.E.H., 2001. Classification of static and dynamic behaviour in a fluidizedbed catalytic reactor. Chem. Eng. J., 84, 503-516. DOI: 10.1016/S1385-8947(00)00373-9.
  • 3. Balakotaiah V., West D.H., 2014. Thermal effects and bifurcations in catalytic partial oxidations. Curr. Opin, Chem, Eng., 5, 68-77. DOI: 10.1016/j.coche.2014.05.002.
  • 4. Berezowski M., 2000. Method of determination of steady-state diagrams of chemical reactors. Chem. Eng. Sci., 55, 4291-4295. DOI: 10.1016/S0009-2509(00)00058-0.
  • 5. Berezowski M., 2002. Złożona struktura stanów stacjonarnych układu równolegle połączonych reaktorów zbiornikowych. Inż. Chem. Proc., 23, 415-423.
  • 6. Berezowski M., 2010. The application of the parametric continuation method for determining steady state diagrams in chemical engineering. Chem. Eng. Sci. , 65, 5411-5414. DOI: 10.1016/j.ces.2010.07.003.
  • 7. Bizon K., 2016. Autothermicity, multiplicity, yield and selectivity of catalytic processes in a polytropic fluidized bed reactor. Chem. Eng. J., 288, 834-844. DOI: 10.1016/j.cej.2015.12.061.
  • 8. Pinto J.C., Ray W.H., 1995. The dynamic behavior of continuous solution polymerization reactors – VIII. A full bifurcation analysis of a lab-scale copolymerization reactor. Chem. Eng. Sci., 50, 1041-1056. DOI: 10.1016/j.cej.2015.12.061.
  • 9. Seydel R., 1994. Practical bifurcation and stability analysis. From equilibrium to chaos. Springer-Verlag, New York.
  • 10. Tabiś B., 2001. Methanol synthesis in a fluidized-bed reactor coupled with an external heat exchanger. The effect of feedback deformation. Chem. Eng. J., 83, 191-200. DOI: 10.1016/S1385-8947(00)00254-0.
  • 11. Uppal A., Ray W.H., Poore A.B., 1976. The classification of the dynamic behavior of continuous stirred tank reactors - Influence of reactor residence time. Chem. Eng. Sci., 31, 205-214. DOI: 10.1016/0009- 2509(76)85058-0.
  • 12. Westerink E.J., Westerterp K.R., 1990. Stable design and operation of catalytic fluidized-bed reactors for multiple reactions: Uniqueness and multiplicity. Chem. Eng. J., 45, 317-332. DOI: 10.1016/0009-2509(90)87103-Y.
  • 13. Zahn V.M, 2012. Adiabatic simulated moving bed reactor – principle, nonlinear analysis and experimental demonstration. Shaker Verlag GmbH, Herzogenrath.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-05aec757-069e-4422-85e6-43aadb0da018
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