Effect of alkali metal promoters on catalytic performance of Co-based catalysts in selective hydrogenation of aniline to cyclohexylamine

• Autorzy: Valeš Roman , Zapletal Martin , Krupka Jiří

Identyfikatory

DOI

10.2478/pjct-2023-0001

• Języki publikacji: EN

Abstrakty

EN

In this study, a series of Co-based catalysts with alkali metal carbonate promoters were prepared to investigate the interrelation between promotion effect of these carbonates and catalytic performance for aniline hydrogenation to cyclohexylamine in vapour phase. The chemical promoters Li₂CO₃ and Na₂CO₃ leading to decrease in catalytic activity of cobalt catalysts for aniline hydrogenation. Catalysts with K₂CO₃ and Cs₂CO₃ loadings have practically no catalytic activity for hydrogenation of aniline. Results of TPD of aniline proved that presence of alkali metals carbonates restricts the adsorption of aniline on the surface of cobalt catalysts. Further, it was found that the addition of Na₂CO₃ greatly enhances the catalytic selectivity towards the cyclohexylamine and inhibits the consecutive reactions of cyclohexylamine leading to formation of by-products such as dicyclohexylamine and N-phenylcyclohexylamine.

Słowa kluczowe

EN

aniline; cyclohexylamine; hydrogenation; cobalt catalyst; alkali metal carbonate

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2023
• Tom: Vol. 25, nr 1
• Strony: 1--7
• Opis fizyczny: Bibliogr. 29 poz., rys., tab., wz.

Twórcy

autor

Valeš Roman

• Department of Organic Technology, Faculty of Chemical Technology, University of Chemistry and Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

autor

Zapletal Martin

• Department of Organic Technology, Faculty of Chemical Technology, University of Chemistry and Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

autor

Krupka Jiří

• Department of Organic Technology, Faculty of Chemical Technology, University of Chemistry and Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).