Bismuth and lead based metal organic frameworks: morphological, luminescence and Brunauer-Emmett-Teller (BET) studies

• Autorzy: Iram Shamaila , Imran Muhammad , Kanwal Farah , Latif Shoomaila , Iqbal Zafar

Identyfikatory

DOI

10.2478/msp-2020-0021

• Języki publikacji: EN

Abstrakty

EN

Biphenyl-4,4′-dicarboxylic acid (H₂BDA) was used as an organic linker to synthesize bismuth and lead based organic frameworks (1 and 2). The structural/morphological studies of these metal organic frameworks (MOFs) were done using UV-Vis, Fourier transform infrared spectroscopy (FT-IR), ¹H NMR, energy dispersive spectroscopy (EDXS), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and powder X-ray diffraction method. Surface area as determined by Brunauer-Emmett-Teller (BET) studies revealed better N₂ gas adsorption for MOF (1) compared to MOF (2). Both these MOFs exhibited good luminescence activity which was attributed to ligand-to-metal charge transfer transitions (LMCT).

Słowa kluczowe

EN

bismuth; lead; metal organic framework; luminescence

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2020
• Tom: Vol. 38, No. 1
• Strony: 132--137
• Opis fizyczny: Bibliogr. 25 poz., rys.

Twórcy

autor

Iram Shamaila

• Institute of Chemistry Punjab University Lahore-Pakistan

autor

Imran Muhammad

• Institute of Chemistry Punjab University Lahore-Pakistan

autor

Kanwal Farah

• Institute of Chemistry Punjab University Lahore-Pakistan

autor

Latif Shoomaila

• Department of Chemistry, University of Lahore, Lahore, 54000, Pakistan

autor

Iqbal Zafar

• Department of Chemistry, Lahore University of Management and Sciences, Lahore, 54000, Pakistan

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).