Secondary sulphate minerals from Bhanine Valley coals (South Lebanon) : a crystallochemical and geochemical study

Kruszewski, Łukasz

doi:10.7306/gq.1450

Artykuł - szczegóły

Tytuł artykułu

Secondary sulphate minerals from Bhanine Valley coals (South Lebanon) : a crystallochemical and geochemical study

Autorzy

Kruszewski Łukasz

Treść / Zawartość

Pełne teksty:

Kruszewski_L_Secondary_GQ_Vol.63_No.1_2019.pdf

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Identyfikatory

DOI

10.7306/gq.1450

Warianty tytułu

Języki publikacji

Abstrakty

Rich efflorescences of various Fe and Al sulphate mineral mixtures on coal seams of Bhanine, South Lebanon, were examined using (1) Powder X-Ray Diffraction (with the Rietveld method and unit cell parameters calculation), (2) Scanning Electron Microscopy with standardized Electron-Dispersive Spectroscopy system, and (3) Inductively-Coupled Plasma Mass Spectroscopy. The sulphates most likely originated from coal-contained pyrite to form Fe(II) sulphates (melanterite, rozenite, and the most common szomolnokite), followed by Fe³⁺-rich sulphates (coquimbite group, copiapite group) and Al sulphates (alunogen, tamarugite). The halotrichite group and minor voltaite, metavoltine, and possibly secondary rozenite and szomolnokite were the last species to be formed. Strong enrichment in Al in copiapites and coquimbites, common occurrence of aluminocoquimbite, and Al likely entering the structure of Fe(II) sulphates makefurther phenomena, during which the initial ferrous copiapites were oxidized in the presence of Al-rich solutions, not out of the question. The obtained unit cell parameters sometimes stand for threshold values in the literature-based ranges drawn, but the values are usually below the 2% discrepancy. The Bhanine sulphates bear relatively large amounts of Tl, Hg, and Co when compared to Coal Clarke and mean crustal abundancies, being also moderately enriched in Ni and As.

Słowa kluczowe

iron sulphates aluminium sulphates coquimbite coal unit cell parameters standardized Energy Dispersive Spectroscopic analysis

Wydawca

Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy

Czasopismo

Geological Quarterly

Rocznik

2019

Tom

Vol. 63, No. 1

Strony

65--87

Opis fizyczny

Bibliogr. 97 poz., fot., rys., tab., wykr.

Twórcy

autor

Kruszewski Łukasz

lkruszewski@twarda.pan.pl

Polish Academy of Sciences, Institute of Geological Sciences, Twarda 51/55, 00-818 Warsaw, Poland

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-04e6726b-ee4e-42ec-9f5d-a3a104e3d13c